feel free to experiment here
Table 1A - Bimolecular Ox
GEOS-Chem Reaction
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v10 (JPL 10-6)
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JPL 15-10
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Comparison
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No quantitative updates |
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Table 1A - Bimolecular O1D
GEOS-Chem Reaction
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v10 (JPL 10-6)
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JPL 15-10
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Comparison
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CH3Cl + O1D |
not active |
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CH3CCl3 + O1D |
not active |
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O1D + HCFC22 = O + HCFC22 + ClO + Cl
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1e-10
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1.02e-10
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JPL201510andGCv10_O1DplHCFC22_eq_OplHCFC22plClOplCl.png
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O1D + HCFC142b
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2.20E-10
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2.00E-10
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JPL201510andGCv10_O1DplHCFC142b.png
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O1D + CFC113
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2.00E-10
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2.32E-10
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JPL201510andGCv10_O1DplCFC113.png
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O1D + CFC114
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1.30E-10
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1.3E-10*exp(-25/T)
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JPL201510andGCv10_O1DplCFC114.png
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O1D + CFC115
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5.0E-11
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5.4E-11*exp(-30/T)
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JPL201510andGCv10_O1DplCFC115.png
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Table 1A - Bimolecular Singlet O2
GEOS-Chem Reaction
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v10 (JPL 10-6)
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JPL 15-10
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Comparison
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No quantitative updates |
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Table 1B - Bimolecular HOx
GEOS-Chem Reaction
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v10 (JPL 10-6)
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JPL 15-10
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Comparison
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No quantitative updates |
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Table 1C - Bimolecular NOx
GEOS-Chem Reaction
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v10 (JPL 10-6)
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JPL 15-10
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Comparison
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No quantitative updates |
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Table 1D - Bimolecular Organic
GEOS-Chem Reaction
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v10 (JPL 10-6)
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JPL 15-10
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Comparison
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MACR + O3 = OH + HO2 + HCOOH + CO + MGLY + CH2O
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1.40E-15*exp(-2100/T)
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1.5e-15*exp(-2110/T)
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JPL201510andGCv10_MACRplO3_eq_OHplHO2plHCOOHplCOplMGLYplCH2O.png
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MVK + O3 = OH + HO2 + HCOOH + CO + ALD2 + MGLY + CH2O
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8.50E-16*exp(-1520/T)
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8.5e-16*exp(-1520/T)
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JPL201510andGCv10_MVKplO3_eq_OHplHO2plHCOOHplCOplALD2plMGLYplCH2O.png
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MACR + OH = MAO3 + MRO2\
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8.0E-12*exp(380/T)
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9.6e-12*exp(360./T)
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JPL201510andGCv10_MACRplOH_eq_MAO3plMRO2.png
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MVK + OH = VRO2\
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2.6e-12*exp(610/T)
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2.7e-12*exp(580./T)
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JPL201510andGCv10_MVKplOH_eq_VRO2.png
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ISOP + OH = RIO2
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3.1e-11*exp(350/T)
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3.0e-11*exp(360./T)
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JPL201510andGCv10_ISOPplOH_eq_RIO2.png
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MACR + NO3 = MAN2
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2.30e-15
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3.4e-15
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JPL201510andGCv10_MACRplNO3_eq_MAN2.png
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ISOP + NO3 = INO2
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3.3E-12*exp(-450/T)
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3.5e-12*exp(-450/T)
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JPL201510andGCv10_ISOPplNO3_eq_INO2.png
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Table 1F - Bimolecular ClOx
GEOS-Chem Reaction
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v10 (JPL 10-6)
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JPL 15-10
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Comparison
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Non CFC/HCFC ClOx needs review. (volunteer by putting your name here)
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OH + HCFC22 = Cl + H2O
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1.05E-12*exp(-1600./T)
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9.2e-13*exp(-1560./T)
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JPL201510andGCv10_OHplHCFC22_eq_ClplH2O.png
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OH + HCFC123 = Cl + H2O
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6.30E-13*exp(-850./T)
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7.4e-13*exp(-900./T)
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JPL201510andGCv10_OHplHCFC123_eq_ClplH2O.png
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<tr><th colspan=4 bgcolor="#CCFFFF">Table 1G - Bimolecular BrOx </th></tr>
<tr><td colspan=4>Needs review. (volunteer by putting your name here)</td></tr>
<tr><th colspan=4 bgcolor="#CCFFFF">Table 1H - Bimolecular IOx </th></tr>
<tr><td colspan=4>Needs review. (volunteer by putting your name here)</td></tr>
<tr><th colspan=4 bgcolor="#CCFFFF">Table 1I - Bimolecular SOx </th></tr>
<tr><td colspan=4>Needs review. (volunteer by putting your name here)</td></tr>
<tr><th colspan=4 bgcolor="#CCFFFF">Table 2-1 - Termolecular</th></tr>
<tr><th width="20%">GEOS-Chem Reaction</th><th>v10 (JPL 10-6)</th><th>JPL 15-10</th><th>Comparison</th></tr>
<tr><td>HO2 + NO2 + M = HNO4</td><td>GP(A0 = 2.e-31, B0 = 3.4, A1 = 2.9e-12, B1 = 1.1)</td><td>GP(A0 = 1.9e-31, B0 = 3.4, A1 = 4e-12, B1 = 0.3)</td><td width="30%">
JPL201510andGCv10_HO2plNO2plM_eq_HNO4.png
</td></tr>
<tr><td>NO2 + NO3 + M = N2O5</td><td>GP(A0 = 2.00E-30, B0 = 4.4E+00, A1 = 1.40E-12, B1 = 7.0E-01)</td><td>GP(A0 = 2.4e-30, B0 = 3., A1 = 1.6e-12, B1 = -0.1)</td><td width="30%">
JPL201510andGCv10_NO2plNO3plM_eq_N2O5.png
</td></tr>
<tr><td>OH + CO + M = H + CO2</td><td>GY(A0 = 5.9e-33, B0 = 1.4e0, A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = -0.6e0, A3 = 2.1e09, B3 = -6.1e0)</td><td>GY(A0 = 5.9e-33, B0 = 1., A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = 0., A3 = 2.1e09, B3 = -6.1e0)</td><td width="30%">
JPL201510andGCv10_OHplCOplM_eq_HplCO2.png
</td></tr>
<tr><td>OH + PRPE + M = PO2</td><td>GP(A0 = 8.00E-27, B0 = 3.5E+00, A1 = 3.00E-11, B1 = 1.0E+00)</td><td>GP(A0 = 4.6e-27, B0 = 4., A1 = 2.6e-11, B1 = 1.3)</td><td width="30%">
JPL201510andGCv10_OHplPRPEplM_eq_PO2.png
</td></tr>
<tr><td>ClO + ClO + M = Cl2O2</td><td>GP(1.60E-32, 4.5E+00 , 3.00E-12, 2.0E+00)</td><td>GP(A0 = 1.9e-32, B0 = 3.6, A1 = 3.7e-12, B1 = 1.6)</td><td width="30%">
JPL201510andGCv10_ClOplClOplM_eq_Cl2O2.png
</td></tr>
<tr><th colspan=4 bgcolor="#CCFFFF">Table 3-1</th></tr>
<tr><td>N2O5 = NO2 + NO3</td><td>GP(A0 = 7.40E-04, B0 = 4.4E+00, C0 = -11000., A1 = 5.18E+14, B1 = 7.0E-01, C1 = -11000.)</td><td>GP(A0 = 2.4e-30/5.8e-27, B0 = 3., C0 = -10840, A1 = 1.6e-12/5.8e-27, B1 = -0.1, C1 = -10840)</td><td width="30%">
JPL201510andGCv10_N2O5_eq_NO2plNO3.png
</td></tr>
<tr><td>HNO4 = HO2 + NO2</td><td>GP(A0 = 2.e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 2.9e-12 / 2.1e-27, B1 = 1.1, C1 = -10900.)</td><td>GP(A0 = 1.9e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 4e-12 / 2.1e-27, B1 = 0.3, C1 = -10900.)</td><td width="30%">
JPL201510andGCv10_HNO4_eq_HO2plNO2.png
</td></tr>
<tr><td colspan=4>1. Termolecular rates coefficients are evaluated from -0.5km to 11km in the 1976 US Std Atmosphere temperature and pressures</td></tr>
<tr><td colspan=4>2. GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1</td></tr>
<tr><td colspan=4>3. GY is short hand for the GEOS-Chem rate form denoted by Y in globchem.dat and corresponding to the JPL termolecular rate defined as k^{ca}_f([M],T) in Section 2.1</td></tr>
</table>
--Bob Y. (talk) 19:54, 19 May 2015 (UTC)