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| == feel free to experiment here == | | == feel free to experiment here == |
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− | === Table 1A - Bimolecular Ox ===
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
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− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− | |-valign="top"
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− | |No quantitative updates || || ||
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− | |}
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− |
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− | === Table 1A - Bimolecular O1D ===
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
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− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− | |-valign="top"
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− | |CH3Cl + O1D || not active || ||
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− | |-valign="top"
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− | |CH3CCl3 + O1D || not active || ||
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− | |-valign="top"
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− | |O1D + HCFC22 = O + HCFC22 + ClO + Cl
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− | |1e-10
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− | |1.02e-10
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− | |[[File:JPL201510andGCv10_O1DplHCFC22_eq_OplHCFC22plClOplCl.png|200px|thumb|left|JPL201510andGCv10_O1DplHCFC22_eq_OplHCFC22plClOplCl.png]]
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− | |-valign="top"
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− | |O1D + HCFC142b
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− | |2.20E-10
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− | |2.00E-10
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− | |[[File:JPL201510andGCv10_O1DplHCFC142b.png|200px|thumb|left|JPL201510andGCv10_O1DplHCFC142b.png]]
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− | |-valign="top"
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− | |O1D + CFC113
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− | |2.00E-10
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− | |2.32E-10
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− | |[[File:JPL201510andGCv10_O1DplCFC113.png|200px|thumb|left|JPL201510andGCv10_O1DplCFC113.png]]
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− | |-valign="top"
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− | |O1D + CFC114
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− | |1.30E-10
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− | |1.3E-10*exp(-25/T)
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− | |[[File:JPL201510andGCv10_O1DplCFC114.png|200px|thumb|left|JPL201510andGCv10_O1DplCFC114.png]]
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− | |-valign="top"
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− | |O1D + CFC115
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− | |5.0E-11
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− | |5.4E-11*exp(-30/T)
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− | |[[File:JPL201510andGCv10_O1DplCFC115.png|200px|thumb|left|JPL201510andGCv10_O1DplCFC115.png]]
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− | |}
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− |
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− | === Table 1A - Bimolecular Singlet O2 ===
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
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− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− |
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− | |-valign="top"
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− | |No quantitative updates || || ||
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− |
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− | |}
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− |
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− | === Table 1B - Bimolecular HOx ===
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
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− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− |
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− | |-valign="top"
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− | |No quantitative updates || || ||
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− |
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− | |}
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− |
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− | === Table 1C - Bimolecular NOx ===
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
| |
− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− |
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− | |-valign="top"
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− | |No quantitative updates || || ||
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− |
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− | |}
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− |
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− | === Table 1D - Bimolecular Organic ===
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
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− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− | |-valign="top"
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− | |MACR + O3 = OH + HO2 + HCOOH + CO + MGLY + CH2O
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− | |1.40E-15*exp(-2100/T)
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− | |1.5e-15*exp(-2110/T)
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− | |[[File:JPL201510andGCv10_MACRplO3_eq_OHplHO2plHCOOHplCOplMGLYplCH2O.png|200px|thumb|left|JPL201510andGCv10_MACRplO3_eq_OHplHO2plHCOOHplCOplMGLYplCH2O.png]]
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− | |-valign="top"
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− | |MVK + O3 = OH + HO2 + HCOOH + CO + ALD2 + MGLY + CH2O
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− | |8.50E-16*exp(-1520/T)
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− | |8.5e-16*exp(-1520/T)
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− | |[[File:JPL201510andGCv10_MVKplO3_eq_OHplHO2plHCOOHplCOplALD2plMGLYplCH2O.png|200px|thumb|left|JPL201510andGCv10_MVKplO3_eq_OHplHO2plHCOOHplCOplALD2plMGLYplCH2O.png]]
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− | |-valign="top"
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− | |MACR + OH = MAO3 + MRO2\
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− | |8.0E-12*exp(380/T)
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− | |9.6e-12*exp(360./T)
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− | |[[File:JPL201510andGCv10_MACRplOH_eq_MAO3plMRO2.png|200px|thumb|left|JPL201510andGCv10_MACRplOH_eq_MAO3plMRO2.png]]
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− | |-valign="top"
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− | |MVK + OH = VRO2\
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− | |2.6e-12*exp(610/T)
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− | |2.7e-12*exp(580./T)
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− | |[[File:JPL201510andGCv10_MVKplOH_eq_VRO2.png|200px|thumb|left|JPL201510andGCv10_MVKplOH_eq_VRO2.png]]
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− | |-valign="top"
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− | |ISOP + OH = RIO2
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− | |3.1e-11*exp(350/T)
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− | |3.0e-11*exp(360./T)
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− | |[[File:JPL201510andGCv10_ISOPplOH_eq_RIO2.png|200px|thumb|left|JPL201510andGCv10_ISOPplOH_eq_RIO2.png]]
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− | |-valign="top"
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− | |MACR + NO3 = MAN2
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− | |2.30e-15
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− | |3.4e-15
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− | |[[File:JPL201510andGCv10_MACRplNO3_eq_MAN2.png|200px|thumb|left|JPL201510andGCv10_MACRplNO3_eq_MAN2.png]]
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− | |-valign="top"
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− | |ISOP + NO3 = INO2
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− | |3.3E-12*exp(-450/T)
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− | |3.5e-12*exp(-450/T)
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− | |[[File:JPL201510andGCv10_ISOPplNO3_eq_INO2.png|200px|thumb|left|JPL201510andGCv10_ISOPplNO3_eq_INO2.png]]
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− |
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− | |}
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− |
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− | === Table 1F - Bimolecular ClOx ===
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− |
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
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− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− |
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− | |-valign="top"
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− | |colspan="4"|Non CFC/HCFC ClOx needs review. (volunteer by putting your name here)
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− | |-valign="top"
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− | |OH + HCFC22 = Cl + H2O
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− | |1.05E-12*exp(-1600./T)
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− | |9.2e-13*exp(-1560./T)
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− | |[[File:JPL201510andGCv10_OHplHCFC22_eq_ClplH2O.png|200px|thumb|left|JPL201510andGCv10_OHplHCFC22_eq_ClplH2O.png]]
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− | |-valign="top"
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− | |OH + HCFC123 = Cl + H2O
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− | |6.30E-13*exp(-850./T)
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− | |7.4e-13*exp(-900./T)
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− | |[[File:JPL201510andGCv10_OHplHCFC123_eq_ClplH2O.png|200px|thumb|left|JPL201510andGCv10_OHplHCFC123_eq_ClplH2O.png]]
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− |
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− | |}
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− |
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− | === Table 1G - Bimolecular BrOx ===
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− |
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
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− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− |
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− | |-valign="top"
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− | |colspan="4"|Needs review. (volunteer by putting your name here)
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− |
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− | |}
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− |
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− | === Table 1H - Bimolecular IOx ===
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
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− | !width="275px"|JPL 15-10
| |
− | !width="275px"|Comparison
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− |
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− | |-valign="top"
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− | |colspan="4"|Needs review. (volunteer by putting your name here)
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− |
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− | |}
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− |
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− | === Table 1I - Bimolecular SOx ===
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− |
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
| |
− | !width="275px"|JPL 15-10
| |
− | !width="275px"|Comparison
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− |
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− | |-valign="top"
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− | |colspan="4"|Needs review. (volunteer by putting your name here)
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− |
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− | |}
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− |
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− | === Table 2-1 - Termolecular ===
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− |
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
| |
− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− | |-valign="top"
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− | |HO2 + NO2 + M = HNO4
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− | |GP(A0 = 2.e-31, B0 = 3.4, A1 = 2.9e-12, B1 = 1.1)
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− | |GP(A0 = 1.9e-31, B0 = 3.4, A1 = 4e-12, B1 = 0.3)
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− | |[[File:JPL201510andGCv10_HO2plNO2plM_eq_HNO4.png|200px|thumb|left|JPL201510andGCv10_HO2plNO2plM_eq_HNO4.png]]
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− | |-valign="top"
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− | |NO2 + NO3 + M = N2O5
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− | |GP(A0 = 2.00E-30, B0 = 4.4E+00, A1 = 1.40E-12, B1 = 7.0E-01)
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− | |GP(A0 = 2.4e-30, B0 = 3., A1 = 1.6e-12, B1 = -0.1)
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− | |[[File:JPL201510andGCv10_NO2plNO3plM_eq_N2O5.png|200px|thumb|left|JPL201510andGCv10_NO2plNO3plM_eq_N2O5.png]]
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− | |-valign="top"
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− | |OH + CO + M = H + CO2
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− | |GY(A0 = 5.9e-33, B0 = 1.4e0, A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = -0.6e0, A3 = 2.1e09, B3 = -6.1e0)
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− | |GY(A0 = 5.9e-33, B0 = 1., A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = 0., A3 = 2.1e09, B3 = -6.1e0)
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− | |[[File:JPL201510andGCv10_OHplCOplM_eq_HplCO2.png|200px|thumb|left|JPL201510andGCv10_OHplCOplM_eq_HplCO2.png]]
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− |
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− | |-valign="top"
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− | |OH + PRPE + M = PO2
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− | |GP(A0 = 8.00E-27, B0 = 3.5E+00, A1 = 3.00E-11, B1 = 1.0E+00)
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− | |GP(A0 = 4.6e-27, B0 = 4., A1 = 2.6e-11, B1 = 1.3)
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− | |[[File:JPL201510andGCv10_OHplPRPEplM_eq_PO2.png|200px|thumb|left|JPL201510andGCv10_OHplPRPEplM_eq_PO2.png]]
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− | |-valign="top"
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− | |ClO + ClO + M = Cl2O2
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− | |GP(1.60E-32, 4.5E+00 , 3.00E-12, 2.0E+00)
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− | |GP(A0 = 1.9e-32, B0 = 3.6, A1 = 3.7e-12, B1 = 1.6)
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− | |[[File:JPL201510andGCv10_ClOplClOplM_eq_Cl2O2.png|200px|thumb|left|JPL201510andGCv10_ClOplClOplM_eq_Cl2O2.png]]
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− | |-valign="top"
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− | |colspan="4"|
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− | #Termolecular rates coefficients are evaluated from -0.5km to 11km in the 1976 US Std Atmosphere temperature and pressures
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− | #GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1
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− | #GY is short hand for the GEOS-Chem rate form denoted by Y in globchem.dat and corresponding to the JPL termolecular rate defined as k^{ca}_f([M],T) in Section 2.1
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− |
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− | |}
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− |
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− | === Table 3-1 ===
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− |
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− | {| border=1 cellspacing=0 cellpadding=5
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− | |-valign="top" bgcolor="#CCCCCC"
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− | !width="275px"|GEOS-Chem Reaction
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− | !width="275px"|v10 (JPL 10-6)
| |
− | !width="275px"|JPL 15-10
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− | !width="275px"|Comparison
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− | |-valign="top"
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− | |N2O5 = NO2 + NO3
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− | |GP(A0 = 7.40E-04, B0 = 4.4E+00, C0 = -11000., A1 = 5.18E+14, B1 = 7.0E-01, C1 = -11000.)
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− | |GP(A0 = 2.4e-30/5.8e-27, B0 = 3., C0 = -10840, A1 = 1.6e-12/5.8e-27, B1 = -0.1, C1 = -10840)
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− | |[[File:JPL201510andGCv10_N2O5_eq_NO2plNO3.png|200px|thumb|left|JPL201510andGCv10_N2O5_eq_NO2plNO3.png]]
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− |
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− | |-valign="top"
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− | |HNO4 = HO2 + NO2
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− | |GP(A0 = 2.e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 2.9e-12 / 2.1e-27, B1 = 1.1, C1 = -10900.)
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− | |GP(A0 = 1.9e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 4e-12 / 2.1e-27, B1 = 0.3, C1 = -10900.)
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− | |[[File:JPL201510andGCv10_HNO4_eq_HO2plNO2.png|200px|thumb|left|JPL201510andGCv10_HNO4_eq_HO2plNO2.png]]
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− |
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− | |-valign="top"
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− | |colspan="4"|
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− | #GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1
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− | #GY is short hand for the GEOS-Chem rate form denoted by Y in globchem.dat and corresponding to the JPL termolecular rate defined as k^{ca}_f([M],T) in Section 2.1
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− |
| |
− | |}
| |