Difference between revisions of "Sandbox"
(→Table 1A - Bimolecular O1D) |
(→feel free to experiment here) |
||
Line 154: | Line 154: | ||
|3.5e-12*exp(-450/T) | |3.5e-12*exp(-450/T) | ||
|[[File:JPL201510andGCv10_ISOPplNO3_eq_INO2.png|200px|thumb|left|JPL201510andGCv10_ISOPplNO3_eq_INO2.png]] | |[[File:JPL201510andGCv10_ISOPplNO3_eq_INO2.png|200px|thumb|left|JPL201510andGCv10_ISOPplNO3_eq_INO2.png]] | ||
+ | |||
+ | |} | ||
+ | |||
+ | === Table 1F - Bimolecular ClOx === | ||
+ | |||
+ | {| border=1 cellspacing=0 cellpadding=5 | ||
+ | |-valign="top" bgcolor="#CCCCCC" | ||
+ | !width="275px"|GEOS-Chem Reaction | ||
+ | !width="275px"|v10 (JPL 10-6) | ||
+ | !width="275px"|JPL 15-10 | ||
+ | !width="275px"|Comparison | ||
+ | |||
+ | |-valign="top" | ||
+ | |colspan="4"|Non CFC/HCFC ClOx needs review. (volunteer by putting your name here) | ||
+ | |||
+ | |||
+ | |-valign="top" | ||
+ | |OH + HCFC22 = Cl + H2O | ||
+ | |1.05E-12*exp(-1600./T) | ||
+ | |9.2e-13*exp(-1560./T) | ||
+ | |[[File:JPL201510andGCv10_OHplHCFC22_eq_ClplH2O.png|200px|thumb|left|JPL201510andGCv10_OHplHCFC22_eq_ClplH2O.png]] | ||
+ | |||
+ | |-valign="top" | ||
+ | |OH + HCFC123 = Cl + H2O | ||
+ | |6.30E-13*exp(-850./T) | ||
+ | |7.4e-13*exp(-900./T) | ||
+ | |[[File:JPL201510andGCv10_OHplHCFC123_eq_ClplH2O.png|200px|thumb|left|JPL201510andGCv10_OHplHCFC123_eq_ClplH2O.png]] | ||
|} | |} | ||
Line 159: | Line 186: | ||
=== === | === === | ||
− | |||
− | |||
− | |||
− | |||
− | |||
<tr><th colspan=4 bgcolor="#CCFFFF">Table 1G - Bimolecular BrOx </th></tr> | <tr><th colspan=4 bgcolor="#CCFFFF">Table 1G - Bimolecular BrOx </th></tr> | ||
<tr><td colspan=4>Needs review. (volunteer by putting your name here)</td></tr> | <tr><td colspan=4>Needs review. (volunteer by putting your name here)</td></tr> | ||
Line 180: | Line 202: | ||
<tr><td>N2O5 = NO2 + NO3</td><td>GP(A0 = 7.40E-04, B0 = 4.4E+00, C0 = -11000., A1 = 5.18E+14, B1 = 7.0E-01, C1 = -11000.)</td><td>GP(A0 = 2.4e-30/5.8e-27, B0 = 3., C0 = -10840, A1 = 1.6e-12/5.8e-27, B1 = -0.1, C1 = -10840)</td><td width="30%">[[File:JPL201510andGCv10_N2O5_eq_NO2plNO3.png|200px|thumb|left|JPL201510andGCv10_N2O5_eq_NO2plNO3.png]]</td></tr> | <tr><td>N2O5 = NO2 + NO3</td><td>GP(A0 = 7.40E-04, B0 = 4.4E+00, C0 = -11000., A1 = 5.18E+14, B1 = 7.0E-01, C1 = -11000.)</td><td>GP(A0 = 2.4e-30/5.8e-27, B0 = 3., C0 = -10840, A1 = 1.6e-12/5.8e-27, B1 = -0.1, C1 = -10840)</td><td width="30%">[[File:JPL201510andGCv10_N2O5_eq_NO2plNO3.png|200px|thumb|left|JPL201510andGCv10_N2O5_eq_NO2plNO3.png]]</td></tr> | ||
<tr><td>HNO4 = HO2 + NO2</td><td>GP(A0 = 2.e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 2.9e-12 / 2.1e-27, B1 = 1.1, C1 = -10900.)</td><td>GP(A0 = 1.9e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 4e-12 / 2.1e-27, B1 = 0.3, C1 = -10900.)</td><td width="30%">[[File:JPL201510andGCv10_HNO4_eq_HO2plNO2.png|200px|thumb|left|JPL201510andGCv10_HNO4_eq_HO2plNO2.png]]</td></tr> | <tr><td>HNO4 = HO2 + NO2</td><td>GP(A0 = 2.e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 2.9e-12 / 2.1e-27, B1 = 1.1, C1 = -10900.)</td><td>GP(A0 = 1.9e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 4e-12 / 2.1e-27, B1 = 0.3, C1 = -10900.)</td><td width="30%">[[File:JPL201510andGCv10_HNO4_eq_HO2plNO2.png|200px|thumb|left|JPL201510andGCv10_HNO4_eq_HO2plNO2.png]]</td></tr> | ||
+ | |||
<tr><td colspan=4>1. Termolecular rates coefficients are evaluated from -0.5km to 11km in the 1976 US Std Atmosphere temperature and pressures</td></tr> | <tr><td colspan=4>1. Termolecular rates coefficients are evaluated from -0.5km to 11km in the 1976 US Std Atmosphere temperature and pressures</td></tr> | ||
<tr><td colspan=4>2. GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1</td></tr> | <tr><td colspan=4>2. GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1</td></tr> |
Revision as of 17:15, 17 May 2016
Contents
feel free to experiment here
Table 1A - Bimolecular Ox
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
No quantitative updates |
Table 1A - Bimolecular O1D
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
CH3Cl + O1D | not active | ||
CH3CCl3 + O1D | not active | ||
O1D + HCFC22 = O + HCFC22 + ClO + Cl | 1e-10 | 1.02e-10 | |
O1D + HCFC142b | 2.20E-10 | 2.00E-10 | |
O1D + CFC113 | 2.00E-10 | 2.32E-10 | |
O1D + CFC114 | 1.30E-10 | 1.3E-10*exp(-25/T) | |
O1D + CFC115 | 5.0E-11 | 5.4E-11*exp(-30/T) |
Table 1A - Bimolecular Singlet O2
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
No quantitative updates |
Table 1B - Bimolecular HOx
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
No quantitative updates |
Table 1C - Bimolecular NOx
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
No quantitative updates |
Table 1D - Bimolecular Organic
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
MACR + O3 = OH + HO2 + HCOOH + CO + MGLY + CH2O | 1.40E-15*exp(-2100/T) | 1.5e-15*exp(-2110/T) | |
MVK + O3 = OH + HO2 + HCOOH + CO + ALD2 + MGLY + CH2O | 8.50E-16*exp(-1520/T) | 8.5e-16*exp(-1520/T) | |
MACR + OH = MAO3 + MRO2\ | 8.0E-12*exp(380/T) | 9.6e-12*exp(360./T) | |
MVK + OH = VRO2\ | 2.6e-12*exp(610/T) | 2.7e-12*exp(580./T) | |
ISOP + OH = RIO2 | 3.1e-11*exp(350/T) | 3.0e-11*exp(360./T) | |
MACR + NO3 = MAN2 | 2.30e-15 | 3.4e-15 | |
ISOP + NO3 = INO2 | 3.3E-12*exp(-450/T) | 3.5e-12*exp(-450/T) |
Table 1F - Bimolecular ClOx
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
Non CFC/HCFC ClOx needs review. (volunteer by putting your name here)
| |||
OH + HCFC22 = Cl + H2O | 1.05E-12*exp(-1600./T) | 9.2e-13*exp(-1560./T) | |
OH + HCFC123 = Cl + H2O | 6.30E-13*exp(-850./T) | 7.4e-13*exp(-900./T) |
<tr><th colspan=4 bgcolor="#CCFFFF">Table 1G - Bimolecular BrOx </th></tr> <tr><td colspan=4>Needs review. (volunteer by putting your name here)</td></tr> <tr><th colspan=4 bgcolor="#CCFFFF">Table 1H - Bimolecular IOx </th></tr> <tr><td colspan=4>Needs review. (volunteer by putting your name here)</td></tr> <tr><th colspan=4 bgcolor="#CCFFFF">Table 1I - Bimolecular SOx </th></tr> <tr><td colspan=4>Needs review. (volunteer by putting your name here)</td></tr> <tr><th colspan=4 bgcolor="#CCFFFF">Table 2-1 - Termolecular</th></tr> <tr><th width="20%">GEOS-Chem Reaction</th><th>v10 (JPL 10-6)</th><th>JPL 15-10</th><th>Comparison</th></tr>
<tr><td>HO2 + NO2 + M = HNO4</td><td>GP(A0 = 2.e-31, B0 = 3.4, A1 = 2.9e-12, B1 = 1.1)</td><td>GP(A0 = 1.9e-31, B0 = 3.4, A1 = 4e-12, B1 = 0.3)</td><td width="30%"></td></tr> <tr><td>NO2 + NO3 + M = N2O5</td><td>GP(A0 = 2.00E-30, B0 = 4.4E+00, A1 = 1.40E-12, B1 = 7.0E-01)</td><td>GP(A0 = 2.4e-30, B0 = 3., A1 = 1.6e-12, B1 = -0.1)</td><td width="30%"></td></tr> <tr><td>OH + CO + M = H + CO2</td><td>GY(A0 = 5.9e-33, B0 = 1.4e0, A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = -0.6e0, A3 = 2.1e09, B3 = -6.1e0)</td><td>GY(A0 = 5.9e-33, B0 = 1., A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = 0., A3 = 2.1e09, B3 = -6.1e0)</td><td width="30%"></td></tr> <tr><td>OH + PRPE + M = PO2</td><td>GP(A0 = 8.00E-27, B0 = 3.5E+00, A1 = 3.00E-11, B1 = 1.0E+00)</td><td>GP(A0 = 4.6e-27, B0 = 4., A1 = 2.6e-11, B1 = 1.3)</td><td width="30%"></td></tr> <tr><td>ClO + ClO + M = Cl2O2</td><td>GP(1.60E-32, 4.5E+00 , 3.00E-12, 2.0E+00)</td><td>GP(A0 = 1.9e-32, B0 = 3.6, A1 = 3.7e-12, B1 = 1.6)</td><td width="30%"></td></tr><tr><th colspan=4 bgcolor="#CCFFFF">Table 3-1</th></tr>
<tr><td>N2O5 = NO2 + NO3</td><td>GP(A0 = 7.40E-04, B0 = 4.4E+00, C0 = -11000., A1 = 5.18E+14, B1 = 7.0E-01, C1 = -11000.)</td><td>GP(A0 = 2.4e-30/5.8e-27, B0 = 3., C0 = -10840, A1 = 1.6e-12/5.8e-27, B1 = -0.1, C1 = -10840)</td><td width="30%"></td></tr> <tr><td>HNO4 = HO2 + NO2</td><td>GP(A0 = 2.e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 2.9e-12 / 2.1e-27, B1 = 1.1, C1 = -10900.)</td><td>GP(A0 = 1.9e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 4e-12 / 2.1e-27, B1 = 0.3, C1 = -10900.)</td><td width="30%"></td></tr><tr><td colspan=4>1. Termolecular rates coefficients are evaluated from -0.5km to 11km in the 1976 US Std Atmosphere temperature and pressures</td></tr> <tr><td colspan=4>2. GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1</td></tr> <tr><td colspan=4>3. GY is short hand for the GEOS-Chem rate form denoted by Y in globchem.dat and corresponding to the JPL termolecular rate defined as k^{ca}_f([M],T) in Section 2.1</td></tr> </table>