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Table 1A - Bimolecular Ox
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
No quantitative updates |
Table 1A - Bimolecular O1D
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
CH3Cl + O1D | not active | ||
CH3CCl3 + O1D | not active | ||
O1D + HCFC22 = O + HCFC22 + ClO + Cl | 1e-10 | 1.02e-10 | |
O1D + HCFC142b | 2.20E-10 | 2.00E-10 | |
O1D + CFC113 | 2.00E-10 | 2.32E-10 | |
O1D + CFC114 | 1.30E-10 | 1.3E-10*exp(-25/T) | |
O1D + CFC115 | 5.0E-11 | 5.4E-11*exp(-30/T) |
Table 1A - Bimolecular Singlet O2
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
No quantitative updates |
Table 1B - Bimolecular HOx
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
No quantitative updates |
Table 1C - Bimolecular NOx
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
No quantitative updates |
Table 1D - Bimolecular Organic
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
MACR + O3 = OH + HO2 + HCOOH + CO + MGLY + CH2O | 1.40E-15*exp(-2100/T) | 1.5e-15*exp(-2110/T) | |
MVK + O3 = OH + HO2 + HCOOH + CO + ALD2 + MGLY + CH2O | 8.50E-16*exp(-1520/T) | 8.5e-16*exp(-1520/T) | |
MACR + OH = MAO3 + MRO2\ | 8.0E-12*exp(380/T) | 9.6e-12*exp(360./T) | |
MVK + OH = VRO2\ | 2.6e-12*exp(610/T) | 2.7e-12*exp(580./T) | |
ISOP + OH = RIO2 | 3.1e-11*exp(350/T) | 3.0e-11*exp(360./T) | |
MACR + NO3 = MAN2 | 2.30e-15 | 3.4e-15 | |
ISOP + NO3 = INO2 | 3.3E-12*exp(-450/T) | 3.5e-12*exp(-450/T) |
Table 1F - Bimolecular ClOx
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
Non CFC/HCFC ClOx needs review. (volunteer by putting your name here)
| |||
OH + HCFC22 = Cl + H2O | 1.05E-12*exp(-1600./T) | 9.2e-13*exp(-1560./T) | |
OH + HCFC123 = Cl + H2O | 6.30E-13*exp(-850./T) | 7.4e-13*exp(-900./T) |
Table 1G - Bimolecular BrOx
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
Needs review. (volunteer by putting your name here) |
Table 1H - Bimolecular IOx
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
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Needs review. (volunteer by putting your name here) |
Table 1I - Bimolecular SOx
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
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Needs review. (volunteer by putting your name here) |
Table 2-1 - Termolecular
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
HO2 + NO2 + M = HNO4 | GP(A0 = 2.e-31, B0 = 3.4, A1 = 2.9e-12, B1 = 1.1) | GP(A0 = 1.9e-31, B0 = 3.4, A1 = 4e-12, B1 = 0.3) | |
NO2 + NO3 + M = N2O5 | GP(A0 = 2.00E-30, B0 = 4.4E+00, A1 = 1.40E-12, B1 = 7.0E-01) | GP(A0 = 2.4e-30, B0 = 3., A1 = 1.6e-12, B1 = -0.1) | |
OH + CO + M = H + CO2 | GY(A0 = 5.9e-33, B0 = 1.4e0, A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = -0.6e0, A3 = 2.1e09, B3 = -6.1e0) | GY(A0 = 5.9e-33, B0 = 1., A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = 0., A3 = 2.1e09, B3 = -6.1e0) | |
OH + PRPE + M = PO2 | GP(A0 = 8.00E-27, B0 = 3.5E+00, A1 = 3.00E-11, B1 = 1.0E+00) | GP(A0 = 4.6e-27, B0 = 4., A1 = 2.6e-11, B1 = 1.3) | |
ClO + ClO + M = Cl2O2 | GP(1.60E-32, 4.5E+00 , 3.00E-12, 2.0E+00) | GP(A0 = 1.9e-32, B0 = 3.6, A1 = 3.7e-12, B1 = 1.6) | |
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Table 3-1
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
---|---|---|---|
N2O5 = NO2 + NO3 | GP(A0 = 7.40E-04, B0 = 4.4E+00, C0 = -11000., A1 = 5.18E+14, B1 = 7.0E-01, C1 = -11000.) | GP(A0 = 2.4e-30/5.8e-27, B0 = 3., C0 = -10840, A1 = 1.6e-12/5.8e-27, B1 = -0.1, C1 = -10840) | |
HNO4 = HO2 + NO2 | GP(A0 = 2.e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 2.9e-12 / 2.1e-27, B1 = 1.1, C1 = -10900.) | GP(A0 = 1.9e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 4e-12 / 2.1e-27, B1 = 0.3, C1 = -10900.) | |
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