Table 1F - Bimolecular ClOx |
Non CFC/HCFC ClOx needs review. (volunteer by putting your name here) |
OH + HCFC22 = Cl + H2O | 1.05E-12*exp(-1600./T) | 9.2e-13*exp(-1560./T) | JPL201510andGCv10_OHplHCFC22_eq_ClplH2O.png |
OH + HCFC123 = Cl + H2O | 6.30E-13*exp(-850./T) | 7.4e-13*exp(-900./T) | JPL201510andGCv10_OHplHCFC123_eq_ClplH2O.png |
Table 1G - Bimolecular BrOx |
Needs review. (volunteer by putting your name here) |
Table 1H - Bimolecular IOx |
Needs review. (volunteer by putting your name here) |
Table 1I - Bimolecular SOx |
Needs review. (volunteer by putting your name here) |
Table 2-1 - Termolecular |
GEOS-Chem Reaction | v10 (JPL 10-6) | JPL 15-10 | Comparison |
HO2 + NO2 + M = HNO4 | GP(A0 = 2.e-31, B0 = 3.4, A1 = 2.9e-12, B1 = 1.1) | GP(A0 = 1.9e-31, B0 = 3.4, A1 = 4e-12, B1 = 0.3) | JPL201510andGCv10_HO2plNO2plM_eq_HNO4.png |
NO2 + NO3 + M = N2O5 | GP(A0 = 2.00E-30, B0 = 4.4E+00, A1 = 1.40E-12, B1 = 7.0E-01) | GP(A0 = 2.4e-30, B0 = 3., A1 = 1.6e-12, B1 = -0.1) | JPL201510andGCv10_NO2plNO3plM_eq_N2O5.png |
OH + CO + M = H + CO2 | GY(A0 = 5.9e-33, B0 = 1.4e0, A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = -0.6e0, A3 = 2.1e09, B3 = -6.1e0) | GY(A0 = 5.9e-33, B0 = 1., A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = 0., A3 = 2.1e09, B3 = -6.1e0) | JPL201510andGCv10_OHplCOplM_eq_HplCO2.png |
OH + PRPE + M = PO2 | GP(A0 = 8.00E-27, B0 = 3.5E+00, A1 = 3.00E-11, B1 = 1.0E+00) | GP(A0 = 4.6e-27, B0 = 4., A1 = 2.6e-11, B1 = 1.3) | JPL201510andGCv10_OHplPRPEplM_eq_PO2.png |
ClO + ClO + M = Cl2O2 | GP(1.60E-32, 4.5E+00 , 3.00E-12, 2.0E+00) | GP(A0 = 1.9e-32, B0 = 3.6, A1 = 3.7e-12, B1 = 1.6) | JPL201510andGCv10_ClOplClOplM_eq_Cl2O2.png |
Table 3-1 |
N2O5 = NO2 + NO3 | GP(A0 = 7.40E-04, B0 = 4.4E+00, C0 = -11000., A1 = 5.18E+14, B1 = 7.0E-01, C1 = -11000.) | GP(A0 = 2.4e-30/5.8e-27, B0 = 3., C0 = -10840, A1 = 1.6e-12/5.8e-27, B1 = -0.1, C1 = -10840) | JPL201510andGCv10_N2O5_eq_NO2plNO3.png |
HNO4 = HO2 + NO2 | GP(A0 = 2.e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 2.9e-12 / 2.1e-27, B1 = 1.1, C1 = -10900.) | GP(A0 = 1.9e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 4e-12 / 2.1e-27, B1 = 0.3, C1 = -10900.) | JPL201510andGCv10_HNO4_eq_HO2plNO2.png |
1. Termolecular rates coefficients are evaluated from -0.5km to 11km in the 1976 US Std Atmosphere temperature and pressures |
2. GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1 |
3. GY is short hand for the GEOS-Chem rate form denoted by Y in globchem.dat and corresponding to the JPL termolecular rate defined as k^{ca}_f([M],T) in Section 2.1 |