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Table 1A - Bimolecular Ox

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
No quantitative updates

Table 1A - Bimolecular O1D

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
CH3Cl + O1D not active
CH3CCl3 + O1D not active
O1D + HCFC22 = O + HCFC22 + ClO + Cl 1e-10 1.02e-10
JPL201510andGCv10_O1DplHCFC22_eq_OplHCFC22plClOplCl.png
O1D + HCFC142b 2.20E-10 2.00E-10
JPL201510andGCv10_O1DplHCFC142b.png
O1D + CFC113 2.00E-10 2.32E-10
JPL201510andGCv10_O1DplCFC113.png
O1D + CFC114 1.30E-10 1.3E-10*exp(-25/T)
JPL201510andGCv10_O1DplCFC114.png
O1D + CFC115 5.0E-11 5.4E-11*exp(-30/T)
JPL201510andGCv10_O1DplCFC115.png

Table 1A - Bimolecular Singlet O2

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
No quantitative updates

Table 1B - Bimolecular HOx

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
No quantitative updates

Table 1C - Bimolecular NOx

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
No quantitative updates

Table 1D - Bimolecular Organic

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
MACR + O3 = OH + HO2 + HCOOH + CO + MGLY + CH2O 1.40E-15*exp(-2100/T) 1.5e-15*exp(-2110/T)
JPL201510andGCv10_MACRplO3_eq_OHplHO2plHCOOHplCOplMGLYplCH2O.png
MVK + O3 = OH + HO2 + HCOOH + CO + ALD2 + MGLY + CH2O 8.50E-16*exp(-1520/T) 8.5e-16*exp(-1520/T)
JPL201510andGCv10_MVKplO3_eq_OHplHO2plHCOOHplCOplALD2plMGLYplCH2O.png
MACR + OH = MAO3 + MRO2\ 8.0E-12*exp(380/T) 9.6e-12*exp(360./T)
JPL201510andGCv10_MACRplOH_eq_MAO3plMRO2.png
MVK + OH = VRO2\ 2.6e-12*exp(610/T) 2.7e-12*exp(580./T)
JPL201510andGCv10_MVKplOH_eq_VRO2.png
ISOP + OH = RIO2 3.1e-11*exp(350/T) 3.0e-11*exp(360./T)
JPL201510andGCv10_ISOPplOH_eq_RIO2.png
MACR + NO3 = MAN2 2.30e-15 3.4e-15
JPL201510andGCv10_MACRplNO3_eq_MAN2.png
ISOP + NO3 = INO2 3.3E-12*exp(-450/T) 3.5e-12*exp(-450/T)
JPL201510andGCv10_ISOPplNO3_eq_INO2.png

Table 1F - Bimolecular ClOx

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
Non CFC/HCFC ClOx needs review. (volunteer by putting your name here)


OH + HCFC22 = Cl + H2O 1.05E-12*exp(-1600./T) 9.2e-13*exp(-1560./T)
JPL201510andGCv10_OHplHCFC22_eq_ClplH2O.png
OH + HCFC123 = Cl + H2O 6.30E-13*exp(-850./T) 7.4e-13*exp(-900./T)
JPL201510andGCv10_OHplHCFC123_eq_ClplH2O.png

Table 1G - Bimolecular BrOx

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
Needs review. (volunteer by putting your name here)

Table 1H - Bimolecular IOx

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
Needs review. (volunteer by putting your name here)

Table 1I - Bimolecular SOx

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
Needs review. (volunteer by putting your name here)

Table 2-1 - Termolecular

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison
HO2 + NO2 + M = HNO4 GP(A0 = 2.e-31, B0 = 3.4, A1 = 2.9e-12, B1 = 1.1) GP(A0 = 1.9e-31, B0 = 3.4, A1 = 4e-12, B1 = 0.3)
JPL201510andGCv10_HO2plNO2plM_eq_HNO4.png
NO2 + NO3 + M = N2O5 GP(A0 = 2.00E-30, B0 = 4.4E+00, A1 = 1.40E-12, B1 = 7.0E-01) GP(A0 = 2.4e-30, B0 = 3., A1 = 1.6e-12, B1 = -0.1)
JPL201510andGCv10_NO2plNO3plM_eq_N2O5.png
OH + CO + M = H + CO2 GY(A0 = 5.9e-33, B0 = 1.4e0, A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = -0.6e0, A3 = 2.1e09, B3 = -6.1e0) GY(A0 = 5.9e-33, B0 = 1., A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = 0., A3 = 2.1e09, B3 = -6.1e0)
JPL201510andGCv10_OHplCOplM_eq_HplCO2.png
OH + PRPE + M = PO2 GP(A0 = 8.00E-27, B0 = 3.5E+00, A1 = 3.00E-11, B1 = 1.0E+00) GP(A0 = 4.6e-27, B0 = 4., A1 = 2.6e-11, B1 = 1.3)
JPL201510andGCv10_OHplPRPEplM_eq_PO2.png
ClO + ClO + M = Cl2O2 GP(1.60E-32, 4.5E+00 , 3.00E-12, 2.0E+00) GP(A0 = 1.9e-32, B0 = 3.6, A1 = 3.7e-12, B1 = 1.6)
JPL201510andGCv10_ClOplClOplM_eq_Cl2O2.png
  1. Termolecular rates coefficients are evaluated from -0.5km to 11km in the 1976 US Std Atmosphere temperature and pressures
  2. GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1
  3. GY is short hand for the GEOS-Chem rate form denoted by Y in globchem.dat and corresponding to the JPL termolecular rate defined as k^{ca}_f([M],T) in Section 2.1

Table 3-1

GEOS-Chem Reaction v10 (JPL 10-6) JPL 15-10 Comparison


N2O5 = NO2 + NO3 GP(A0 = 7.40E-04, B0 = 4.4E+00, C0 = -11000., A1 = 5.18E+14, B1 = 7.0E-01, C1 = -11000.) GP(A0 = 2.4e-30/5.8e-27, B0 = 3., C0 = -10840, A1 = 1.6e-12/5.8e-27, B1 = -0.1, C1 = -10840)
JPL201510andGCv10_N2O5_eq_NO2plNO3.png
HNO4 = HO2 + NO2 GP(A0 = 2.e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 2.9e-12 / 2.1e-27, B1 = 1.1, C1 = -10900.) GP(A0 = 1.9e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 4e-12 / 2.1e-27, B1 = 0.3, C1 = -10900.)
JPL201510andGCv10_HNO4_eq_HO2plNO2.png
  1. GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1
  2. GY is short hand for the GEOS-Chem rate form denoted by Y in globchem.dat and corresponding to the JPL termolecular rate defined as k^{ca}_f([M],T) in Section 2.1