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Table 1A - Bimolecular Ox

GEOS-Chem Reaction	v10 (JPL 10-6)	JPL 15-10	Comparison
No quantitative updates

Table 1A - Bimolecular O1D

GEOS-Chem Reaction	v10 (JPL 10-6)	JPL 15-10	Comparison
CH3Cl + O1D	not active
CH3CCl3 + O1D	not active
O1D + HCFC22 = O + HCFC22 + ClO + Cl	1e-10	1.02e-10	JPL201510andGCv10_O1DplHCFC22_eq_OplHCFC22plClOplCl.png
O1D + HCFC142b	2.20E-10	2.00E-10	JPL201510andGCv10_O1DplHCFC142b.png
O1D + CFC113	2.00E-10	2.32E-10	JPL201510andGCv10_O1DplCFC113.png
O1D + CFC114	1.30E-10	1.3E-10*exp(-25/T)	JPL201510andGCv10_O1DplCFC114.png
O1D + CFC115	5.0E-11	5.4E-11*exp(-30/T)	JPL201510andGCv10_O1DplCFC115.png

Table 1A - Bimolecular Singlet O2

GEOS-Chem Reaction	v10 (JPL 10-6)	JPL 15-10	Comparison
No quantitative updates

Table 1B - Bimolecular HOx

GEOS-Chem Reaction	v10 (JPL 10-6)	JPL 15-10	Comparison
No quantitative updates

Table 1C - Bimolecular NOx

GEOS-Chem Reaction	v10 (JPL 10-6)	JPL 15-10	Comparison
No quantitative updates

Table 1D - Bimolecular Organic

GEOS-Chem Reaction	v10 (JPL 10-6)	JPL 15-10	Comparison
MACR + O3 = OH + HO2 + HCOOH + CO + MGLY + CH2O	1.40E-15*exp(-2100/T)	1.5e-15*exp(-2110/T)	JPL201510andGCv10_MACRplO3_eq_OHplHO2plHCOOHplCOplMGLYplCH2O.png
MVK + O3 = OH + HO2 + HCOOH + CO + ALD2 + MGLY + CH2O	8.50E-16*exp(-1520/T)	8.5e-16*exp(-1520/T)	JPL201510andGCv10_MVKplO3_eq_OHplHO2plHCOOHplCOplALD2plMGLYplCH2O.png
MACR + OH = MAO3 + MRO2\	8.0E-12*exp(380/T)	9.6e-12*exp(360./T)	JPL201510andGCv10_MACRplOH_eq_MAO3plMRO2.png
MVK + OH = VRO2\	2.6e-12*exp(610/T)	2.7e-12*exp(580./T)	JPL201510andGCv10_MVKplOH_eq_VRO2.png
ISOP + OH = RIO2	3.1e-11*exp(350/T)	3.0e-11*exp(360./T)	JPL201510andGCv10_ISOPplOH_eq_RIO2.png
MACR + NO3 = MAN2	2.30e-15	3.4e-15	JPL201510andGCv10_MACRplNO3_eq_MAN2.png
ISOP + NO3 = INO2	3.3E-12*exp(-450/T)	3.5e-12*exp(-450/T)	JPL201510andGCv10_ISOPplNO3_eq_INO2.png

Table 1F - Bimolecular ClOx

GEOS-Chem Reaction	v10 (JPL 10-6)	JPL 15-10	Comparison
Non CFC/HCFC ClOx needs review. (volunteer by putting your name here)
OH + HCFC22 = Cl + H2O	1.05E-12*exp(-1600./T)	9.2e-13*exp(-1560./T)	JPL201510andGCv10_OHplHCFC22_eq_ClplH2O.png
OH + HCFC123 = Cl + H2O	6.30E-13*exp(-850./T)	7.4e-13*exp(-900./T)	JPL201510andGCv10_OHplHCFC123_eq_ClplH2O.png

Table 1G - Bimolecular BrOx Needs review. (volunteer by putting your name here) Table 1H - Bimolecular IOx Needs review. (volunteer by putting your name here) Table 1I - Bimolecular SOx Needs review. (volunteer by putting your name here) Table 2-1 - Termolecular GEOS-Chem Reactionv10 (JPL 10-6)JPL 15-10Comparison HO2 + NO2 + M = HNO4GP(A0 = 2.e-31, B0 = 3.4, A1 = 2.9e-12, B1 = 1.1)GP(A0 = 1.9e-31, B0 = 3.4, A1 = 4e-12, B1 = 0.3)

JPL201510andGCv10_HO2plNO2plM_eq_HNO4.png

NO2 + NO3 + M = N2O5GP(A0 = 2.00E-30, B0 = 4.4E+00, A1 = 1.40E-12, B1 = 7.0E-01)GP(A0 = 2.4e-30, B0 = 3., A1 = 1.6e-12, B1 = -0.1)

JPL201510andGCv10_NO2plNO3plM_eq_N2O5.png

OH + CO + M = H + CO2GY(A0 = 5.9e-33, B0 = 1.4e0, A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = -0.6e0, A3 = 2.1e09, B3 = -6.1e0)GY(A0 = 5.9e-33, B0 = 1., A1 = 1.1e-12, B1 = -1.3e0, A2 = 1.5e-13, B2 = 0., A3 = 2.1e09, B3 = -6.1e0)

JPL201510andGCv10_OHplCOplM_eq_HplCO2.png

OH + PRPE + M = PO2GP(A0 = 8.00E-27, B0 = 3.5E+00, A1 = 3.00E-11, B1 = 1.0E+00)GP(A0 = 4.6e-27, B0 = 4., A1 = 2.6e-11, B1 = 1.3)

JPL201510andGCv10_OHplPRPEplM_eq_PO2.png

ClO + ClO + M = Cl2O2GP(1.60E-32, 4.5E+00 , 3.00E-12, 2.0E+00)GP(A0 = 1.9e-32, B0 = 3.6, A1 = 3.7e-12, B1 = 1.6)

JPL201510andGCv10_ClOplClOplM_eq_Cl2O2.png

Table 3-1 N2O5 = NO2 + NO3GP(A0 = 7.40E-04, B0 = 4.4E+00, C0 = -11000., A1 = 5.18E+14, B1 = 7.0E-01, C1 = -11000.)GP(A0 = 2.4e-30/5.8e-27, B0 = 3., C0 = -10840, A1 = 1.6e-12/5.8e-27, B1 = -0.1, C1 = -10840)

JPL201510andGCv10_N2O5_eq_NO2plNO3.png

HNO4 = HO2 + NO2GP(A0 = 2.e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 2.9e-12 / 2.1e-27, B1 = 1.1, C1 = -10900.)GP(A0 = 1.9e-31 / 2.1e-27, B0 = 3.4, C0 = -10900., A1 = 4e-12 / 2.1e-27, B1 = 0.3, C1 = -10900.)

JPL201510andGCv10_HNO4_eq_HO2plNO2.png

1. Termolecular rates coefficients are evaluated from -0.5km to 11km in the 1976 US Std Atmosphere temperature and pressures 2. GP is short hand for the GEOS-Chem rate form denoted by P in globchem.dat and corresponding to the JPL termolecular rate defined as k_f([M],T) in Section 2.1 3. GY is short hand for the GEOS-Chem rate form denoted by Y in globchem.dat and corresponding to the JPL termolecular rate defined as k^{ca}_f([M],T) in Section 2.1

--Bob Y. (talk) 19:54, 19 May 2015 (UTC)