On this page we provide information about the sulfate aerosol species in GEOS-Chem.
- 1 Overview
- 2 Important updates to the sulfate aerosol simulation
- 3 SO4s and NITs have the same molecular weight as SALC
- 4 Computing PM2.5 concentrations from GEOS-Chem output
- 5 References
- 6 Previous issues that have now been resolved
From Park et al :
The sulfur simulation in GEOS-Chem is based on the Georgia Tech/Goddard Global Ozone Chemistry Aerosol Radiation and Transport (GOCART) model [Chin et al., 2000a], with a number of modifications described below. Our fossil fuel and industrial emission inventory is for 1999-2000 and is obtained by scaling the gridded, seasonally resolved inventory from the Global Emissions Inventory Activity (GEIA) for 1985 [Benkovitz et al., 1996] with updated national emission inventories and fuel use data [Bey et al., 2001a]. The emissions for the United States and Canada are from U.S. EPA , and the emissions for European countries are from European Monitoring and Evaluation Programme (EMEP)/United Nations Economic Commission for Europe (UNECE). Asian sulfur emission in the model is 20 Tg S yr1, which can be compared to year 2000 estimates of 17 Tg S yr1 by Streets et al.  and 25 Tg S yr1 by Intergovernmental Panel on Climate Change (hereinafter IPCC) . Anthropogenic sulfur is emitted as SO2 except for a small fraction as sulfate (5% in Europe and 3% elsewhere) [Chin et al., 2000a].
Other anthropogenic sources of SO2 in the model include gridded monthly aircraft emissions (0.07 Tg S yr1) taken from Chin et al. [2000a] and biofuel use. We use a global biofuel CO emission inventory with 1° x 1° spatial resolution from Yevich and Logan  and apply an emission factor of 0.0015 mol SO2 per mole CO [Andreae and Merlet, 2001]. Seasonal variations in biofuel emissions are specified from the heating degree days approach [Park et al., 2003].
Natural sources of sulfur in the model include DMS from oceanic phytoplankton and SO2 from volcanoes and biomass burning. The oceanic emission of DMS is calculated as the product of local seawater DMS concentration and sea-to-air transfer velocity. The seawater DMS concentrations are gridded monthly averages from Kettle et al. , and the transfer velocity of DMS is computed using an empirical formula from Liss and Merlivat  as a function of the surface (10 m) wind speed. The GEOS surface winds used here assimilate remote sensing data from the Special Sensor Microwave Imager instrument. Volcanic emissions of SO2 from continuously active volcanoes are included from the database of Andres and Kasgnoc . Emissions from sporadically erupting volcanoes show large year-to-year variability and are not included in the model. No major volcanic eruptions occurred in 2001. Biomass burning emissions of SO2 are calculated using a gridded monthly biomass burning inventory of CO constrained from satellite observations in 2001 by Duncan et al.  with an emission factor of 0.0026 mol SO2 per mole CO [Andreae and Merlet, 2001].
The gas-phase sulfur oxidation chemistry in the model includes DMS oxidation by OH to form SO2 and MSA, DMS oxidation by nitrate radicals (NO3) to form SO2, and SO2 oxidation by OH to form sulfate. Reaction rates are from DeMore et al.  and the yields of SO2 and MSA from DMS oxidation are from Chatfield and Crutzen . Aqueous-phase oxidation of SO2 by O3 and H2O2 in clouds to form sulfate is included using kinetic data from Jacob  and assuming a pH of 4.5 for the oxidation by O3. Cloud liquid water content is not available in the GEOS data, and we specify it instead in each cloudy grid box by using a temperature-dependent parameterization [Somerville and Remer, 1984]. The cloud volume fraction in a given grid box is specified as an empirical function of the relative humidity following Sundqvist et al. .
Ammonia emissions in the model are based on annual data for 1990 from the 1° x 1° GEIA inventory of Bouwman et al. . Source categories in that inventory include domesticated animals, fertilizers, human bodies, industry, fossil fuels, oceans, crops, soils, and wild animals. We view the first five as anthropogenic and the last four as natural. Additional emissions from biomass burning and biofuel use are computed using the global inventories of Duncan et al.  and Yevich and Logan , with an emission factor of 1.3 g NH3 per kilogram dry mass burned [Andreae and Merlet, 2001].
Production of total inorganic nitrate (gas-phase nitric acid and aerosol nitrate) in the model is computed from the ozone-NOx-hydrocarbon chemical mechanism.
Important updates to the sulfate aerosol simulation
Notable additions since Park et al :
- Biomass emissions of SO2 and NH3 are now computed by the GFED inventory.
- The most recent version (Oct 2015) is GFED4
- You may still uses the older GFED2 or GFED3 inventories for research purposes.
- Incorporation of new Volcanic SO2 emissions from Aerocom
- Alkalinity computation for Sea salt aerosols
- Updates to regional and global anthropogenic emissions inventories
- Get liquid water content and cloud fraction directly from GEOS-5 met fields for SO2 chemistry (since GEOS-Chem v8-03-02)
- Other minor changes
Also, the following updates have been added (or are in the process of being added) since GEOS-Chem v9-02:
Cloud water pH for sulfate formation
This update was tested in the 1-month benchmark simulation v9-02p and approved on 13 Sep 2013.
Becky Alexander wrote:
- Bulk cloud pH is calculated iteratively using concentrations of sulfate, total nitrate (HNO3 + NO3), total ammonia (NH3 + NH4), SO2, and CO2 = 390 ppmv based on their effective Henry's law constants and the local cloud LWC.
- Over the oceans, the influence of cloud droplet heterogeneity in pH on in-cloud sulfate production rates is accounted for using the Yuen et al. (1996) parameterization. Based on isotopic evidence, this parameterization seems to work well over the oceans using sea salt aerosol as the course mode aerosol component, but tends to overestimate in-cloud sulfate production over land.
The reference for this work is:
- Alexander, B., D.J. Allman, H.M. Amos, T.D. Fairlie, J. Dachs, D.A. Hegg and R.S. Sletten, Isotopic constraints on sulfate aerosol formation pathways in the marine boundary layer of the subtropical northeast Atlantic Ocean, J. Geophys. Res., 117, D06304, doi:10.1029/2011JD016773, 2012.
--Melissa Sulprizio 11:55, 5 September 2013 (EDT)
Update DMS climatology to Lana
Sulfur oxidation by reactive halogens
This update was included in v11-02d (approved 12 Feb 2018).
From Chen et al. (2017):
- Sulfur and reactive bromine (Bry) play important roles in tropospheric chemistry and the global radiation budget. The oxidation of dissolved SO2 (S(IV)) by HOBr increases sulfate aerosol abundance and may also impact the Bry budget, but is generally not included in global climate and chemistry models. In this study, we implement HOBr + S(IV) reactions into the GEOS-Chem global chemical transport model and evaluate the global impacts on both sulfur and Bry budgets. Modeled HOBr mixing ratios on the order of 0.1–1.0 parts per trillion (ppt) lead to HOBr + S(IV) contributing to 8% of global sulfate production and up to 45% over some tropical ocean regions with high HOBr mixing ratios (0.6–0.9 ppt). Inclusion of HOBr + S(IV) in the model leads to a global Bry decrease of 50%, initiated by the decrease in bromide recycling in cloud droplets. Observations of HOBr are necessary to better understand the role of HOBr + S(IV) in tropospheric sulfur and Bry cycles.
Text S2 in this supporting document describes the parameterization of HOBr + S(IV) reactions in GEOS-Chem.
- Chen, Q., J. A. Schmidt, V. Shah, L. Jaeglé, T. Sherwen, and B. Alexander, Sulfate production by reactive bromine: Implications for the global sulfur and reactive bromine budgets, Geophys. Res. Lett., 44, 7069–7078, doi:10.1002/2017GL073812, 2017.
Metal catalyzed oxidation of SO2
This update was included in v11-02e (approved 24 Mar 2018).
Becky Alexander wrote:
- SO2 is oxidized in clouds by transition metals (Fe and Mn). Natural Fe and Mn atmospheric concentrations are scaled to dust, and anthropogenic are scaled to primary anthropogenic sulfate. It is assumed that 1% of natural Mn and Fe is soluble, for anthropogenic it is 10%. The oxidation state of Fe and Mn depends on sunlight. See Alexander et al.  for more details.
- We had discussed having a switch for this in input.geos, so people could easily turn it off if they wanted. The Aerosols WG decided to have it on by default.
- Alexander, B., Park, R.J., Jacob, D.J., and Gong, S., Transition metal catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur budget, J. Geophys. Res., 114, D02309, 2009.
Viral Shah implemented the metal catalyzed in-cloud SO2 oxidation pathway originally described in Alexander et al. (2009) into GEOS-Chem v10-01.
Viral Shah wrote:
- My method largely follows Becky's implementation. The main difference is that instead of using a tracer for primary sulfate to calculate anthropogenic Fe and Mn concentrations, I have added a tracer for anthropogenic Fe (pFe). pFe is emitted along with primary sulfate with an emissions ratio that equals the scaling factor used by Becky to calculate Fe concentrations from primary sulfate. This emission ratio is added as a scaling factor in HEMCO_Config and can be adjusted in the future. For wet and dry deposition, pFe is treated as an aerosol species. Anthropogenic Mn concentrations are calculated by scaling pFe concentrations. Note that Fe and Mn are also present in natural dust, and the GC dust species are used to calculate the natural Fe and Mn concentrations.
Ocean ammonia emission inventory
This update is slated for inclusion in GEOS-Chem v11-02 or later.
Fabien Paulot and others have created a new emission inventory for ammonia from oceans. The reference for this work is
- Paulot, F., D.J. Jacob, M. Johnson, T.G. Bell, A.R. Baker, W.C. Keene, I.D. Lima, S.C. Doney, and C.A. Stock, Global oceanic emission of ammonia: constraints from seawater and atmospheric observations, Global Biogeochemical Cycles, in press, 2015. [ PDF ]
These emissions will be implemented into GEOS-Chem v11-02 via the HEMCO emissions component.
SO4s and NITs have the same molecular weight as SALC
Becky Alexander replied:
The reason for using SALC sea salt's molecular weight for SO4s and NITs is that these tracers are essentially internally mixed with coarse sea salt aerosol (SALC). As coarse sea salt aerosol likely dominates the mass of these aerosols, it is appropriate to use sea salt's MW.
Another explanation is that since SO4s and NITs are internally mixed with sea salt, they should be treated identically to SALC in the code for all processes.
Computing PM2.5 concentrations from GEOS-Chem output
For information on how to compute particulate matter (PM2.5) from GEOS-Chem diagnostic outputs, please see our Particulate matter in GEOS-Chem wiki page.
- Andreae, M. O., and P. Merlet (2001), Emission of trace gases and aerosols from biomass burning, Global Biogeochem. Cycles, 15(4), 95596
- Andres, R. J., and A. D. Kasgnoc, A time-averaged inventory of subaerial volcanic sulfur emissions, J. Geophys. Res., 103(D19), 25,251-25,261, 1998.
- Benkovitz, C. M., M. T. Scholtz, J. Pacyna, L. Tarrason, J. Dignon, E. C. Voldner, P. A. Spiro, J. A. Logan, and T. E. Graedel, Global gridded inventories of anthropogenic emissions of sulfur and nitrogen, J. Geophys. Res., 101(D22), 29,239-29,253, 1996.
- Bey, I., D. J. Jacob, R. M. Yantosca, J. A. Logan, B. Field, A. M. Fiore, Q. Li, H. Liu, L. J. Mickley, and M. Schultz, Global modeling of tropospheric chemistry with assimilated meteorology: Model description and evaluation, J. Geophys. Res., 106, 23,073-23,096, 2001. PDF
- Bouwman, A. F., D. S. Lee, W. A. H. Asman, F. J. Dentener, K. W. VanderHoek, and J. G. J. Olivier, A global high-resolution emission inventory for ammonia, Global Biogeochem. Cycles, 11(4), 561-587, 1997.
- Chatfield, R. B., and P. J. Crutzen, Are there interactions of iodine and sulfur species in marine air photochemistry?, J. Geophys. Res., 95(D13), 22,319-22,341, 1990.
- DeMore, W. B., S. P. Sander, D. M. Golden, R. F. Hampson, M. J. Kurylo, C. J. Howard, A. R. Ravishankara, C. E. Kolb, and M. J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, JPL Publ., 97-4, 1-278., 1997.
- Duncan, B. N., R. V. Martin, A. C. Staudt, R. Yevich, and J. A. Logan, Interannual and seasonal variability of biomass burning emissions constrained by satellite observations, J. Geophys. Res., 108(D2), 4100, doi:10.1029/2002JD002378, 2003. PDF
- Jacob, D. J., Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate,J. Geophys. Res., 91(D9), 9807-9826, 1986.
- Kettle, A. J., et al. A global database of sea surface dimethylsulfide (DMS) measurements and a procedure to predict sea surface DMS as a function of latitude, longitude, and month, Global Biogeochem. Cycles, 13(2), 399-444., 1999.
- Liss, P. S., and L. Merlivat (1986), Air-sea gas exchange rates: Introduction and synthesis, in The Role of Air-Sea Exchange in Geochemical Cycling, edited by P. Buat-Me´nard, pp. 113-127, D. Reidel, Norwell, Mass, 1986.
- Park, R. J., D. J. Jacob, B. D. Field, R. M. Yantosca, and M. Chin, Natural and transboundary pollution influences on sulfate-nitrate-ammonium aerosols in the United States: implications for policy, J. Geophys. Res., 109, D15204, 10.1029/2003JD004473, 2004. PDF
- Yevich, R., and J. A. Logan, An assessment of biofuel use and burning of agricultural waste in the developing world, Global Biogeochem. Cycles, 17(4), 1095, doi:10.1029/2002GB001952, 2003. PDF
- Somerville, R. C. J., and L. A. Remer, Cloud optical thickness feedbacks in the CO2 climate problem, J. Geophys. Res., 89(D6), 9668-9672, 1984.
- Streets, D. G., et al. An inventory of gaseous and primary aerosol emissions in Asia in the year 2000, J. Geophys. Res., 108(D21), 8809, doi:10.1029/2002JD003093, 2003.
--Bob Y. 14:36, 23 February 2010 (EST)
Previous issues that have now been resolved
The following bugs and/or technical issues in the sulfate aerosol module have since been resolved:
Fix error in production of SO4s, NITs in SEASALT_CHEM routine
This fix was included in v11-02a and approved on 12 May 2017.
Prasad Kasibhatla reported an issue in the production of SO4 and NITs in routine SEASALT_CHEM (in GeosCore/sulfate_mod.F) due to a unit conversion error.
Prasad Kasibhatla wrote:
The problem is that in going from v/v to equivalents and back to v/v in rather than doing it the straightforward way as you say, 2 molecular weights are used each time. The way the conversion is done is: Before calculating the production of SO4s or NITs
equivalents = v/v * (mol wt of SO2 or HNO3) / (mol wt of air) * mass of air in grid / (mol wt of SO2 or HNO3) * (2 for SO2 or 1 for HNO3 )
and then in calculating the production of SO4s or NITs
v/v = equivalents * (mol wt of SO4s or NITs) * (mol wt of air) / (mol wt of SO4s or NITs) / mass of air in grid / (2 for SO2 or 1 for HNO3)
So the problem is the difference in the terms highlighted in RED, which correspond to the
TCVVfactors that have been used in GEOS-Chem unit conversions. Btw, I think this affects SO4 too because uptake of SO2 on fine mode seasalt is considered to produces SO4 (and not SO4s). And also, uptake of HNO3 on fine mode seasalt is not accounted for either as a loss of HNO3 or a gain of NIT or NITs.
Bob Yantosca replied:
Older GEOS-Chem versions used the
TCVVfactor (MW of air / MW of species) in the equations. In GEOS-Chem v11-01, we removed all instances of
TCVVand replaced them with direct coding (e.g.
AIRMW / MW_SO2, etc.
Further complicating matters is that the equations in routine SEASALT_CHEM uses hardwired molecular weights (e.g. 0.064 kg/mole, 0.096 kg/mole) as well.
This bug appears to have arisen due to two factors:
- Changing the molecular weight of SO4s and NITs species to 31.4 g/mole (in v11-01e), as per Becky Alexander's recommendation:The reason to use the molecular weight of sea salt for NITs and SO4s is that these tracers are internally mixed with sea salt aerosol, so their deposition fluxes should be identical to course-mode sea salt aerosol.
############################################################# #### Production of NITs, computed at end of SEASALT_CHEM #### #### Other terms have been omitted for clarity #### ############################################################# In v9-02: !SO4F produced converted from [eq/timestep] to [v/v/timestep] PSO4F = SO4F * 0.096 * TCVV(IDTSO4S) / & AD(I,J,L) / 2.0d0 Correct, because the MW of SO4s = 96 g/mole. In v10-01: !SO4F produced converted from [eq/timestep] to [v/v/timestep] PSO4F = SO4F * 0.096 * TCVV(IDTSO4S) / & AD(I,J,L) / 2.0e+0_fp Correct, because the MW of SO4s = 96 g/mole. In v11-01: !SO4F produced converted from [eq/timestep] to [v/v/timestep] PSO4F = SO4F * 0.096 * ( AIRMW / MW_SO4S ) / & AD(I,J,L) / 2.0e+0_fp Incorrect, because the MW of SO4s = 31.4 g/mole, not 96 g/mole. ############################################################# #### Production of NITs, computed at end of SEASALT_CHEM #### #### Other terms have been omitted for clarity #### ############################################################# In v9-02: ! NITS produced converted from [eq/timestep] to [v/v/timestep] PNITs(I,J,L) = HNO3_SSC * 0.063 * TCVV(IDTNITS) / AD(I,J,L) Correct, because the MW of NITs = 63 g/mole. In v10-01: ! NITS produced converted from [eq/timestep] to [v/v/timestep] PNITs(I,J,L) = HNO3_SSC * 0.063 * TCVV(IDTNITS) / AD(I,J,L) Correct, because the MW of NITs = 63 g/mole. In v11-01: ! NITS produced converted from [eq/timestep] to [v/v/timestep] PNITs(I,J,L) = HNO3_SSC * 0.063 * ( AIRMW / MW_NITS ) / AD(I,J,L) Incorrect, because the MW of NITs = 31.4 g/mole, not 63 g/mole.
Becky Alexander had also written:However, for this particular unit conversion going from molar equivalents to v/v, the calculation should use the molecular weight of HNO3 for mass balance. I see in the wiki that the unit conversion used to use
TCVV(HNO3). In v10 it uses
TCVV(NITS). I don't know when this change happened, but it should not have (though the difference is minor, only 1 g/mole). However, for v11, it is definitely a factor of 2 off if you use the molecular weight of seasalt to convert NITS from molar equivalents to v/v. This should be fixed in v11. This unit conversion should use
Therefore, to fix this bug, one could do the following:
0.096 * ( AIRMW / MW_SO4 )in the equation for
0.063 * ( AIRMW / MW_NIT )in the equation for
But an even better solution (and the one we will follow) is to rewrite the various equations to remove all references to hardwired molecular weights, as shown below:
SO2_eq = ( ( 2.0_fp * SO2_cd * AD(I,J,L) ) / AIRMW ) * 1000.0_fp HNO3_eq = ( ( HNO3_vv * AD(I,J,L) ) / AIRMW ) * 1000.0_fp SO2_ss = ( SO2_chem * AIRMW / AD(I,J,L) ) / 2000.0_fp PSO4E = ( SO4E * AIRMW / AD(I,J,L) ) / 2000.0_fp PSO4F = ( SO4F * AIRMW / AD(I,J,L) ) / 2000.0_fp HNO3_ss = ( HNO3_SSC * AIRMW / AD(I,J,L) ) / 1000.0_fp and HNO3_ss = ( TITR_HNO3 * AIRMW / AD(I,J,L) ) / 1000.0_fp PNITS(I,J,L) = ( HNO3_SSC * AIRMW / AD(I,J,L) ) / 1000.0_fp
Furthermore, we can take this opportunity to remove the hardwired molecular weights for SO4 and HNO3 by rewriting these equations as well:
C_FLUX_A = ( 2.0_fp * F_SO2_A * AD(I,J,L) / AIRMW ) * 1000.0_fp C_FLUX_C = ( 2.0_fp * F_SO2_C * AD(I,J,L) / AIRMW ) * 1000.0_fp N_FLUX_A = ( F_HNO3_A * AD(I,J,L) / AIRMW ) * 1000.0_fp N_FLUX_C = ( F_HNO3_C * AD(I,J,L) / AIRMW ) * 1000.0_fp
Fix bug in CHEM_NIT routine
This fix was included in v11-02a and approved on 12 May 2017.
Prasad Kasibhatla wrote:
I am wondering if there is a small bug in CHEM_NIT. I think the nitrate uptake on fine sea salt (the line displayed in GREEN)
! Fraction of box (I,J,L) underneath the PBL top [unitless] F_UNDER_TOP = GET_FRAC_UNDER_PBLTOP( I, J, L ) ! Only apply drydep to boxes w/in the PBL IF ( F_UNDER_TOP > 0e+0_fp ) THEN !=========================================================== ! NITs chemistry !=========================================================== ! NIT prod from HNO3 uptake on fine sea-salt [v/v/timestep] NITs = NIT0s + PNITs(I,J,L) ! Store final concentration in Spc [v/v] Spc(I,J,L,id_NITs) = NITs ENDIF
should be done throughout the troposphere and not just in the PBL. The PBL check seems to be a legacy from when dry dep was done in CHEM_NIT. I am guessing that even if this is a bug, it is a very small bug because
PNITsshould be quite small outside the marine PBL.