Difference between revisions of "Chemistry Working Group"

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(HO2 + CH2O)
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=== HO2 + CH2O ===
 
=== HO2 + CH2O ===
 
Scheme does not contain the HO2 + CH2O --> Adduct reaction (MJE Leeds)
 
Scheme does not contain the HO2 + CH2O --> Adduct reaction (MJE Leeds)
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Hermans, I., et al. (2005), Kinetics of alpha-hydroxy-alkylperoxyl radicals in oxidation
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processes. HO2 center dot-initiated oxidation of ketones/aldehydes near the tropopause,
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Journal of Physical Chemistry A, 109(19), 4303-4311.
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According to this paper, this reaction is significant when Temperature is below 220K.
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--[[User:Jmao|J Mao.]] 15:00, 10 Aug 2009 (EDT)
  
 
== Documentation ==
 
== Documentation ==

Revision as of 19:09, 10 August 2009

Oxidants and Chemistry Working Group

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Current GEOS-Chem Chemistry Issues (please add yours!)

HO2 + CH2O

Scheme does not contain the HO2 + CH2O --> Adduct reaction (MJE Leeds)

Hermans, I., et al. (2005), Kinetics of alpha-hydroxy-alkylperoxyl radicals in oxidation processes. HO2 center dot-initiated oxidation of ketones/aldehydes near the tropopause, Journal of Physical Chemistry A, 109(19), 4303-4311.

According to this paper, this reaction is significant when Temperature is below 220K.

--J Mao. 15:00, 10 Aug 2009 (EDT)

Documentation

One typo was found by Dylan Millet for reaction 230(MAO3+NO=1.0NO2+4.0CH2O+1.0HO2) in this documentation. The reaction rate should be 6.7E-12exp(340/T) instead of 6.7E-12exp(-340/T). This reaction rate was correct in globchem.dat.

--J Mao. 16:26, 21 July 2009 (EDT)