Dry deposition

This page describes the current dry deposition scheme used in GEOS-Chem.

Overview

Here is a description of the GEOS-Chem dry deposition scheme from several journal articles:

From Section 4 of Alexander et al [2005]:

Dry deposition velocities for sea-salt aerosols (and sulfate formed in sea-salt aerosols) are computed with the size-dependent scheme of Zhang et al. [2001] integrated over each model size bin and accounting for hygroscopic growth as a function of relative humidity [Gerber, 1985]. Dry deposition velocities for all other species are computed with a standard resistance-in-series scheme based on Wesely [1989] as described by Wang et al. [1998].

From Section 2.4 of Bey et al [2001]:

Dry deposition of oxidants and water soluble species is computed using a resistance-in-series model based on the original formulation of Wesely [1989] with a number of modifications [Wang et al 1998]. The dry deposition velocities are calculated locally using GEOS data for surface values of momentum and sensible heat fluxes, temperature, and solar radiation.

From Section 6 of Wang et al [1998]:

We use a resistance-in-series model [Wesely and Hicks, 1977] to compute dry deposition velocities of O3, NO2, HNO3, PANs and H2O2. The deposition velocity Vi for species i is computed as:

     Vi = 1 / ( Ra + Rb,i + Rc,i )

where Ra is the aerodynamic resistance to transfer to the surface, Rb,i is the boundary resistance, and Rc,i is the canopy surface resistance. Ra and Rb,i are calculated from the GCM meteorological variables [Jacob et al 1993]. Surface resistances Rc,i are based largely on the canopy model of Wesely [1989] with some improvements, including explicit dependence of canopy stomatal resistances on LAI [Gao and Wesely, 1995] and on direct and diffuse PAR within the canopy [Baldocchi et al, 1987]. The same radiative transfer model for direct and diffuse PAR in the canopy is used as in the formulation of isoprene emissions. Surface resistances for deposition to tropical rain forest and tundra are taken from Jacob and Wofsy [1990] and Jacob et al [1992], respectively. The surface resistance for deposition of NO2 is taken to be the same as that of ozone [Erisman & Pul, 1994; Kramm et al, 1995; Eugster and Hesterberg, 1996] and hence lower than specified by Wesely [1989]. Dry deposition of CO and hydrocarbons is negligibly small and not included in the model [Mueller and Brasseur, 1995].

Source code and data

The source code of the various routines are located in drydep_mod.f.

1. Routine DO_DRYDEP is the main driver for the dry deposition. This calls various setup subroutines.
2. Routine DEPVEL (which is called by DO_DRYDEP) computes dry deposition dry deposition velocities in [m/s].
3. Dry deposition frequencies [1/s] for all species are computed in DO_DRYDEP, after the call to DEPVEL.

For more information about the input data files required by the drydep scheme, please see the README file: GEOS_1x1/drydep_200203/README

Full-chemistry simulation

In the NOx-Ox-HC-aerosol "full-chemistry" simulation, dry deposition is handled as follows:

1. The DEPVEL array is passed to routine CALCRATE (in source code file calcrate.f). The dry deposition frequencies of the gas-phase species (NO2, O3, PAN, HNO3, H2O2, PMN, PPN, R4N2, CH2O, N205, etc.) are then entered into the master reaction rate array, RRATE.
2. The RRATE is passed to either the SMVGEAR or KPP solver (whichever you have selected). The dry deposition frequencies are considered as loss rates in the chemical mechanism.
3. Dry deposition of the sulfur aerosol tracers (SO2, SO4, SO4s, MSA, NH3, NH4, NIT, NITs) is applied in sulfate_mod.f. Deposited tracer is removed directly from the main tracer array (STT).
4. Dry deposition of the carbon and/or SOA aerosol tracers (BCPI, BCPO, OCPI, OCPO, etc.) is applied in carbon_mod.f. Deposited tracer is removed directly from the main tracer array (STT).
5. Dry deposition of the mineral dust tracers (DST1, DST2, DST3, DST4) is applied in dust_mod.F. Deposited tracer is removed directly from the main tracer array (STT).
6. Dry deposition of the sea salt aerosol tracers (SALA, SALC) is applied in dust_mod.F. Deposited tracer is removed directly from the main tracer array (STT).

Offline simulations

In general, dry deposition for offline simulations is handled in the relevant module (e.g. RnPbBe_mod.F for the Radon-Lead-Beryllium simulation, etc. The dry deposition frequencies stored in DEPVEL are used to remove dry deposited tracer directly from the main tracer array (STT).

--Bob Y. 15:34, 21 October 2011 (EDT)

OVOCs dry deposition

This update was tested in the 1-month benchmark simulation v9-01-03c and approved on 19 Dec 2011.

According to Karl et al.(2010), I changed the reactivity factor(f0) for all OVOCs from 0 to 1.

Now dry dep is set up as:

Species	H*(moles L-1 atm-1 )	f0	Reference
NO2	0.01	0.1
Ox	0.01	1.0
PAN	3.6	0.1
HNO3	1.0d+14	0.0
H2O2	1.0d+5	1.0
PMN	as PAN
PPN	as PAN
PYPAN	as PAN
ISN2	as HNO3
R4N2	as PAN
CH2O	6.0e+3	change from 0 to 1.0
GLYX	3.6d+5	change from 0 to 1.0
MGLY	3.7d+3	change from 0 to 1.0
GLYC	4.1d+4	change from 0 to 1.0
MPAN,GPAN, GLPAN	as PAN
N2O5	as HNO3
HCOOH	1.67d+5	change from 0 to 1.0
ACTA	1.14d+4	change from 0 to 1.0
ISOPND	1.7d+4	0.0
ISOPNB	1.7d+4	0.0
MVKN+MACRN	1.7d+4	0.0
PROPNN	1.0d+3	0.0	NITROOXYACETONE IN SANDER TABLE
RIP	as H2O2
IEPOX	as H2O2
MAP	8.4d+2	1.0
MVK	4.4d1	change from 0 to 1.0	from R.Sander
MACR	6.5d0	change from 0 to 1.0	from R.Sander
SO2	1.0d+5	0.0

Karl, T., Harley, P., Emmons, L., Thornton, B., Guenther, A., Basu, C., Turnipseed, A., and Jardine, K.: Efficient Atmospheric Cleansing of Oxidized Organic Trace Gases by Vegetation, Science, 330, 816-819, 10.1126/science.1192534, 2010.

Notes: To run with non-local mixing, you don't need to modify globchem.dat with " MVK=DRYDEP+DRYMVK", because drydep here is done out of chemistry step. But you need to modify that for full mixing scheme, which is using chemical solver to calculate drydep.

--Jmao 15:06, 15 December 2011 (EST)

Code updates

Update dry deposition to use local surface pressure

NOTE: This update is currently slated for inclusion into GEOS-Chem v9-01-03.

Lyatt Jaeglé wrote:

The only difference comes from the pressure value (PRESS variable) used in the dry deposition code to calculate the diffusivity of a molecule in air. Pressure comes into play in the mean free path calculation in DIFFG. For some reason the pressure was set at a constant value of 1500hPa (I do not know why this value was chosen in the first place, any ideas?). When I was going over the dry deposition code for sea salt I had replaced this fixed value with local sea level pressure (SLP). I think that it makes sense to use the actual local pressure instead of this fixed value. The overall effect is small.

--Melissa Payer 11:19, 11 January 2012 (EST)

References

1. Alexander, B., R.J. Park, D.J. Jacob, Q.B. Li, R.M. Yantosca, J. Savarino, C.C.W. Lee, and M.H. Thiemens, Sulfate formation in sea-salt aerosols: Constraints from oxygen isotopes, J. Geophys. Res., 110, D10307, 2005. PDF
2. Baldocchi, D.D., B.B. Hicks, and P. Camara, A canopy stomatal resistance model for gaseous deposition to vegetated surfaces, Atmos. Environ. 21, 91-101, 1987.
3. Brutsaert, W., Evaporation into the Atmosphere, Reidel, 1982.
4. Businger, J.A., et al., Flux-profile relationships in the atmospheric surface layer, J. Atmos. Sci., 28, 181-189, 1971.
5. Bey I., D. J. Jacob, R. M. Yantosca, J. A. Logan, B. Field, A. M. Fiore, Q. Li, H. Liu, L. J. Mickley, and M. Schultz, Global modeling of tropospheric chemistry with assimilated meteorology: Model description and evaluation, J. Geophys. Res., 106, 23,073-23,096, 2001. PDF
6. Duan, B., Fairall, C.W., and Thomson, D.W., Eddy correlation measurements of the dry deposition of particles in wintertime, J. Appl. Met., 27, 642-652, 1988.
7. Dwight, H.B., Tables of integrals and other mathematical data, MacMillan, 1957.
8. Erisman, J.W, and A.V. Pul, Parameterization of surface resistance for the quantification of atmospheric deposition of acidifying pollutants and ozone, Atmos. Environ, 28, 2595-2607, 1994.
9. Eugster, W. and R. Hesterberg, Transfer resistances of NO2 determined from eddy correlation flux measurements over a litter meadow at a rural site on the Swiss plateau, Atmos. Environ, 30, 1247-1254, 1996.
10. Gao, W. and M.L. Wesely, Modeling gaseous dry deposition over regional scales with satellite observations, 1. Model development, Atmos. Environ, '29, 727-737, 1995.
11. Gerber, H. E. (1985), Relative-humidity parameterization of the Navy aerosol model (NAM), NRL Rep. 8956, Natl. Res. Lab., Washington, D. C., 1985.
12. Guenther, A., et al, A global model of natural volatile organic compound emissions, J. Geophys. Res., 100, 8873-8892, 1995.
13. Hicks, B.B., and P.S. Liss, Transfer of SO2 and other reactive gases across the air-sea interface, Tellus, 28, 348-354, 1976.
14. Ibrahim, M., Barrie, L.A., and Fanaki, F., An experimental and theoretical investigation of the dry deposition of particles to snow, pine trees, and artificial collectors, Atmos. Environ., 17, 781-788, 1983.
15. Jacob, D.J., and S.C. Wofsy, Budgets of reactive nitrogen, hydrocarbons, and ozone over the Amazon forest during the wet season, J. Geophys. Res., 95, 16737-16754, 1990.
16. Jacob, D.J., et al, Deposition of ozone to tundra, J. Geophys. Res., 97, 16473-16479, 1992.
17. Jacob, D.J, et al, Summertime photochemistry of the troposphere at high northern latitudes, J. Geophys. Res., 98, 14,797-14,816, 1993.
18. Kramm, G. R. Dlugi, G.J. Dollard, T. Foken, N. Moelders, H. Mueller, W. Seiler, and H. Sievering, On the dry deposition of ozone and reactive nitrogen species, Atmos. Environ, 29, 3208-3231, 1995.
19. Levine, I.N., Physical Chemistry, 3rd ed., McGraw-Hill, New York, 1988.
20. Mueller, J-F, and G. Brasseur, IMAGES, A three-dimensional chemical transport model of the global troposphere, J. Geophys. Res., 100, 16,445-16,490, 1995.
21. Munger, J.W., et al, Atmospheric deposition of reactive nitrogen oxides and ozone in a temperate deciduous forest and a sub-arctic woodland, J. Geophys. Res., in press, 1996.
22. Nilsson, E.D. and Rannik, U. Turbulent aerosol fluxes over the Arctic Ocean: 1. Dry deposition over sea and pack ice, J. Geophys. Res, 106, 32,125-32,137, 2001.
23. Price, H., L. Jaeglé, A. Rice, P. Quay, P.C. Novelli, R. Gammon, Global Budget of Molecular Hydrogen and its Deuterium Content: Constraints from Ground Station, Cruise, and Aircraft Observations, submitted to J. Geophys. Res., 2007
24. Walcek, C.J., R.A. Brost, J.S. Chang, and M.L.Wesely, SO2, sulfate, and HNO3 deposition velocities computed using regional landuse and meteorological data, Atmos. Environ., 20, 949-964, 1986.
25. Wang, Y., D.J. Jacob, and J.A. Logan, Global simulation of tropospheric O3-NOx-hydrocarbon chemistry, 1. Model formulation, J. Geophys. Res., 103, D9,10,713-10,726, 1998. PDF
26. Wesely, M.L, Improved parameterizations for surface resistance to gaseous dry deposition in regional-scale numerical models, Environmental Protection Agency Report EPA/600/3-88/025, Research Triangle Park (NC), 1988.
27. Wesely, M. L., Parameterization of surface resistance to gaseous dry deposition in regional-scale numerical models, Atmos. Environ., 23, 1293-1304, 1989.
28. Wesely, M.L, and B.B. Hicks, Some factors that affect the deposition rates of sulfur dioxide and similar gases on vegetation, J. Air. Pollut. Control Assoc., 27, 1110-1116, 1977.
29. Zhang, L., S. Gong, J. Padro, and L. Barrie, A size-segregated particle dry deposition scheme for an atmospheric aerosol module, Atmos. Environ.,, 35, 549–560, 2001.

--Bob Y. 15:24, 19 February 2010 (EST)

Known issues

Aerosol dry deposition velocities over snow and ice surfaces

This update was tested in the 1-month benchmark simulation v9-01-02i and approved on 15 Aug 2011.

Modeled aerosol dry deposition velocities over snow and ice surfaces in the Arctic are much higher than estimated from measured values (e.g., Ibrahim et al. [1983]; Duan et al. [1988]; Nilsson and Rannik [2001]). In GEOS-Chem v9-01-02 we have imposed a dry deposition velocity of 0.03 cm/s for all aerosols over snow and ice surfaces.

This update affects the following aerosol tracers: SO4s, NITs, DST1, DST2, DST3, DST4, SALA, SALC.

--Jenny Fisher 11:08, 20 January 2011 (EST)
--Bob Y. 10:26, 16 August 2011 (EDT)

Dependency between dry deposition and soil NOx emissions

In GEOS-Chem there is a code dependency between the dry deposition routines soil NOx emissions routines. This is purely historical baggage that goes back to the days of the old 9-layer Harvard-GISS CTM (from which these routines were taken).

The dry deposition routine DEPVEL (in drydep_mod.f) computes a quantity called CANOPYNOX, which is the bulk surface resistance of the canopy to NOx deposition. This is computed in the following lines of code:

C** Get the bulk surface resistance of the canopy, RSURFC, from the network
C** of resistances in parallel and in series (Fig. 1 of Wesely [1989])
               DTMP1=1.D0/RIXX
               DTMP2=1.D0/RLUXX
               DTMP3=1.D0/(RAC(LDT)+RGSX)
               DTMP4=1.D0/(RDC+RCLX)
               RSURFC(K,LDT) = 1.D0/(DTMP1 + DTMP2 + DTMP3 + DTMP4)
C  Save the within canopy depvel of NOx, used in calculating the 
C  canopy reduction factor for soil emissions.
               ! Remove hardwire for CANOPYNOX (bmy, 1/24/03)
               IF ( K == DRYDNO2 ) THEN
                  CANOPYNOX(IJLOOP,LDT)=DTMP1+DTMP2+DTMP3+DTMP4
               ENDIF

However, the CANOPYNOX variable is not defined within drydep_mod.f, but is found instead within the soil NOx emissions code header file commsoil.h:

     REAL*8 CANOPYNOX(MAXIJ,NTYPE) !track NOx within canopy dry dep.

and is then also used within the soil NOx emissions function SOILCRF, as follows:

     IF ((XLAI(IREF,JREF,K).GT.0.D0).AND.
    &    (CANOPYNOX(IJLOOP,K).GT.0.D0))THEN

        VFNEW=VFNEW*SQRT(WINDSQR/9.D0*7.D0/XLAI(IREF,JREF,K))*
    *        (SOILEXC(2)/SOILEXC(NN))
        SOILCRF=CANOPYNOX(IJLOOP,K)/(CANOPYNOX(IJLOOP,K)
    *        +VFNEW)
     ELSE
    
        SOILCRF=0.D0
     END IF

This is not necessarily a problem as long as dry deposition is always turned on whenever you are doing a full-chemistry simulation that requires soil NOx emissions. In the driver routine main.f, dry deposition is always done before emissions. However, this is bad coding style and a potential source of error. (This also must be corrected for the GEOS-Chem column code, in which all inputs must come thru the argument list.)

In the new soil NOx emissions code being developed by Rynda Hudman (much of which is based on the GEOS-Chem column code being developed by Bob Yantosca and Philippe Le Sager), there is a new module called canopy_nox_mod.f. This module computes the CANOPYNOX quantity independently of routine DEPVEL in drydep_mod.f, which allows for a totally clean separation between dry deposition routines and emissions routines.

At present, the new canopy_nox_mod.f is not available in the standard mainline GEOS-Chem code. It is slated to be incorporated with the soil NOx emissions update.

--Bob Y. 13:51, 18 February 2010 (EST)