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https://wiki.seas.harvard.edu/geos-chem/index.php?title=HEMCO_data_directories&diff=49580
HEMCO data directories
2021-06-25T22:57:47Z
<p>Zitely: Last name corrected</p>
<hr />
<div>On this page we describe the directory tree from which the [[HEMCO|HEMCO emissions component]] can read emissions inventories and other atmospheric data sets.<br />
<br />
== Overview ==<br />
<br />
The [[HEMCO|HEMCO emissions component]] can read several types of emission inventories, as well as other types atmospheric data sets, such as production and loss rates, or concentration data. We have collated all of this data into a comprehensive directory tree structure. Each folder of the HEMCO data directory tree represents a particular emissions inventory or other data set.<br />
<br />
At present, the HEMCO data directory tree resides on the Compute Canada and AWS s3://gcgrid bucket. We have created a package that will let you download this directory tree to your local disk storage space. For more information, please see the [[#Downloading_the_HEMCO_data_directories|''Downloading the HEMCO data directories'']] section below.<br />
<br />
Please see [[Emissions_and_Deposition_Working_Group#Recommended_Default_Emission_Inventories|our list of recommended default emission inventories]], which has been compiled by the [[Emissions and Deposition Working Group]].<br />
<br />
== Downloading the HEMCO data directories ==<br />
<br />
We recommend the following methods for downloading the HEMCO data directories, depending on which GEOS-Chem version you are using:<br />
<br />
{| border=1 cellpadding=5 cellspacing=0<br />
|-bgcolor="#CCCCCC" <br />
!width="175px"|GEOS-Chem versions<br />
!width="350px"|Recommended download method<br />
!width="350px"|Alternate download method<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem 12#12.7.0|12.7.0]] and later<br />
|[[Downloading_data_with_the_GEOS-Chem_dry-run_option|The GEOS-Chem dry-run option]]<br />
|Manual download from either <br />
*[[Downloading_data_from_Compute_Canada|Compute Canada]], or <br />
*[[Downloading_data_from_Amazon_Web_Services_cloud_storage|Amazon Web Services <tt>s3://gcgrid</tt> storage]]<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem 12#12.6.3|12.6.3]] and prior<br />
|[[#The hemco_data_download package|The <tt>hemco_data_download</tt> package]]<br />
|Manual download from either <br />
*[[Downloading_data_from_Compute_Canada|Compute Canada]], or <br />
*[[Downloading_data_from_Amazon_Web_Services_cloud_storage|Amazon Web Services <tt>s3://gcgrid</tt> storage]]<br />
<br />
|}<br />
<br />
--[[User:Bmy|Bob Yantosca]] ([[User talk:Bmy|talk]]) 17:07, 3 December 2020 (UTC)<br />
<br />
== HEMCO data directories corresponding to an emissions option ==<br />
<br />
The sections below describe each of the data directories corresponding to a HEMCO inventory or extension. These are grouped in the order in which they appear in the <tt>HEMCO_Config.rc</tt> version that ships with [[GEOS-Chem 13.0.0]].'' <br />
<br />
In each of the tables below:<br />
<br />
:The '''Inventory''' column contains a link that describes each data set in more detail. Most of these links point to existing pages on the GEOS-Chem wiki.<br />
<br />
:The '''Data file info''' column points to the README files that are stored with each data set. Each README provides a list of the files contained within a given folder, information about the data contained in each file, and (often) a description of how the files were created.<br />
<br />
:The '''Path''' column shows the location of each data set, with respect to <tt>$ROOT</tt>, the top-level HEMCO directory. For example, on the Harvard disk server, <tt>$ROOT</tt> points to the directory <tt>/mnt/gcgrid/data/ExtData/HEMCO/</tt>. <br />
<br />
:The '''Default or optional?''' column contains this description<br />
<br />
:{| border=1 cellspacing=0 cellpadding=5<br />
|-valign="top"<br />
|width="225px" bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
|width="785px"|Denotes that the data set is part of the standard emissions configuration for GEOS-Chem, that is:<br />
*It is used in the GEOS-Chem 1-month and 1-year full-chemistry [http://acmg.seas.harvard.edu/geos/geos_benchmark.html benchmark simulations], or<br />
*It is used in one or more of the [[GEOS-Chem_chemistry_mechanisms#Specialty_simulations|GEOS-Chem specialty simulations]].<br />
<br />
|-valign="top"<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
|Denotes that the data set is not part of the the standard GEOS-Chem emissions configuration. <br />
*But you can still use the data set in your research applications if you wish.<br />
<br />
|}<br />
<br />
:If use GEOS-Chem, then we recommend that you download the data sets that are listed as '''DEFAULT SETTING''', as these form the standard GEOS-Chem emissions configuration. You are free, however, to use any of the data sets listed below. Your choice of data sets will depend on your particular research needs.<br />
<br />
=== Regional inventories ===<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|- bgcolor="#cccccc"<br />
!width="450px"|Inventory<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="150px"|Default or Optional?<br />
<br />
|-valign="top"<br />
|[[CAC_anthropogenic_emissions#Historical_Canadian_emissions|'''APEI''']]<br />
*Canadian emissions<br />
*Data Years: 1989-2014<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/APEI/v2016-11/README README]<br />
|<tt>$ROOT/APEI/v2016-11/</tt><br />
|68 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[EPA/NEI11_North_American_emissions|'''NEI2011_HOURLY''']]<br />
*Hourly CONUS emissions from NEI2011 inventory<br />
*Data Years: 2006-2013<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NEI2011/v2015-03/README README]<br />
|<tt>$ROOT/NEI2011/v2015-03</tt><br />
|248 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[EPA/NEI11_North_American_emissions|'''NEI2011_MONTHLY_MEAN''']]<br />
*Monthly mean CONUS emissions from NEI2011 inventory<br />
*Data Years: 1989-2014<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NEI2011/v2017-02-MM/README README]<br />
|<tt>$ROOT/NEI2011/v2017-02-MM</tt><br />
|248 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[MIX Asian anthropogenic emissions|'''MIX''']]<br />
*Asian anthropogenic emissions<br />
*Data Years: 2008-2010<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MIX/v2015-03/README README]<br />
|<tt>$ROOT/MIX/v2015-03</tt><br />
|623 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[DICE-Africa_anthropogenic_emissions_inventory|'''DICE_Africa''']]<br />
*African emissions inventory<br />
*Data Years: 2013<br />
||[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/DICE_Africa/v2016-10/README README]<br />
|<tt>$ROOT/DICE_Africa/v2016-10</tt> <br />
|202 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|}<br />
<br />
=== Global inventories ===<br />
<br />
The following subdirectories of the HEMCO directory tree contain inventories of anthropogenic and biofuel emissions.<br />
<br />
Please also see list of species included in each of these [[Anthropogenic_emissions#Global_inventories|global inventories]] and [[Anthropogenic_emissions#Regional_inventories|regional inventories]].<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|- bgcolor="#cccccc"<br />
!width="450px"|Inventory<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="150px"|Default or Optional?<br />
<br />
|-valign="top"<br />
|[[CEDS anthropogenic emissions|'''CEDS''']]<br />
*Community Emissions Data System<br />
*Reference: McDuffie et al 2020, ESSD<br />
*Data Years: 1970-2017<br />
||[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CEDS/v2018-04/README README]<br />
|<tt>$ROOT/CEDS/v2020-08</tt> <br />
|73 GB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[CEDS anthropogenic emissions|'''CEDS_byFuelType''']]<br />
*Sectorial CEDS emissions<br />
*Data Years: 1970-2017<br />
*Reference: McDuffie et al 2020, ESSD<br />
||[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CEDS/v2018-04/README README]<br />
|<tt>$ROOT/CEDS/v2020-08</tt> <br />
|73 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[EDGAR v4.3 anthropogenic emissions|'''EDGARv43''']]<br />
*EDGAR global emissions v4.3<br />
*Data Years: 1970-2010<br />
*Used for sectors not included in DICE-Africa inventory<br />
*Turning on this option will also include trash burning emissions of NOx, SOx, CO, NH3, BC and OC from Wiedinmyer et al. (2014) and NMVOC emissions from CEDS<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/EDGARv43/v2016-11/README README]<br />
|<tt>$ROOT/EDGARv43/v2016-11</tt><br />
|6.2 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[http://edgar.jrc.ec.europa.eu/htap_v2/index.php?SECURE=123 '''HTAP''']<br />
*HTAP global anthro+biofuel emissions<br />
*Data Years: 2008-2010<br />
**NOTE: HTAP includes some regional emissions from other inventories. If you select HTAP you might not need to select the other regional inventories in HEMCO. [http://edgar.jrc.ec.europa.eu/htap/EDGAR-HTAP_v1_final_jan2012.pdf See this document] for more information.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/HTAP/v2015-03/README README]<br />
|<tt>$ROOT/HTAP/v2015-03</tt><br />
|4.5 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NH3/v2014-07/README '''GEIA_NH3''']<br />
*GEIA natural source NH3 emissions<br />
*Data Years: 1990<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NH3/v2014-07/README README]<br />
|<tt>$ROOT/NH3/v2014-07</tt><br />
|8.1 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NH3/v2018-04/README '''SEABIRD_NH3''']<br />
*Croft et al NH3 emissions from arctic sea birds<br />
*Data Years: 1990<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NH3/v2018-04/README README]<br />
|<tt>HEMCO/NH3/v2018-04/</tt><br />
|104 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/POET/v2017-03/README '''POET''']<br />
*Anthropogenic EOH inventory<br />
*Data Years: 1985<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/POET/v2017-03/README README]<br />
|<tt>$ROOT/POET/v2017-03/</tt><br />
|38 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[https://onlinelibrary.wiley.com/doi/full/10.1002/2016JD025767 '''TZOMPASOSA_C2H6''']<br />
*Tzompa-Sosa et al [2017] C2H6 emissions (overwrites CEDS to address underestimates)<br />
*Data Years: 2010<br />
||[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/C2H6_2010/v2019-06/README README]<br />
|<tt>$ROOT/C2H6_2010/v2019-06</tt> <br />
|536 KB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/XIAO/v2014-09/README '''XIAO_C3H8''']<br />
*Y. Xiao et al [2008] C3H8 emissions (overwrites CEDS to address underestimates)<br />
*Data Years: 1985<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/XIAO/v2014-09/README README]<br />
|<tt>$ROOT/XIAO/v2014-09</tt><br />
|308 KB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Bromine_chemistry_mechanism#Source code and data files|'''LIANG_BROMOCARB''']]<br />
*Liang et al VSL emissions<br />
*Data Years: 2000<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/BROMINE/v2015-02/README README]<br />
|<tt>$ROOT/BROMINE/v2015-02</tt><br />
|156 KB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Halogen_chemistry_mechanism#Source_code_and_data_files|'''ORDONEZ_IONOCARB''']]<br />
*Ordonez et al Iodine emissions<br />
*Data Years: 1985<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/IODINE/v2017-09/README README]<br />
|<tt>$ROOT/IODINE/v2017-09</tt><br />
|4.4 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Aircraft_emissions#MIT_aviation_emissions_inventory|'''AEIC''']]<br />
*MIT aircraft emissions inventory<br />
*Data Years: 2005<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/AEIC/v2015-01/README README]<br />
|<tt>$ROOT/AEIC/v2015-01</tt><br />
|2.0 GB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/ALD2/v2017-03/README '''DECAYING_PLANTS''']<br />
*ALD2 and EOH emissions from decaying plants<br />
*Data Years: 1985<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/ALD2/v2017-03/README README]<br />
|<tt>$ROOT/ALD2/v2017-03</tt><br />
|8.1 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Mineral_dust_aerosols#Anthropogenic_PM2.5_dust_source_in_GEOS-Chem|'''AFCID''']]<br />
*Anthropogenic PM2.5 dust source<br />
*Data Years: 2015<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/AFCID/v2018-04/README README]<br />
|<tt>$ROOT/AFCID/2018-04</tt><br />
|4.4 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|}<br />
<br />
=== Ship emissions ===<br />
<br />
The following subdirectories of the HEMCO directory tree contain inventories of anthropogenic aircraft and ship emissions.<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|-bgcolor="#cccccc"<br />
!width="450px"|Inventory<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="150px"|Default or Optional?<br />
<br />
|-valign="top"<br />
|[[CEDS anthropogenic emissions|'''CEDS_SHIP''']]<br />
*CEDS ship emissions (summed over all sectors)<br />
*Data Years: 1970-2017<br />
||[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CEDS/v2018-04/README README]<br />
|<tt>$ROOT/CEDS/v2020-08</tt> <br />
|73 GB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[CEDS anthropogenic emissions|'''CEDS_SHIP_byFuelType''']]<br />
*Sectorial CEDS ship emissions<br />
*Data Years: 1970-2017<br />
**NOTE: Incurs additional data I/O overhead<br />
||[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CEDS/v2018-04/README README]<br />
|<tt>$ROOT/CEDS/v2020-08</tt> <br />
|73 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[http://edgar.jrc.ec.europa.eu/htap_v2/index.php?SECURE=123 '''HTAP_SHIP''']<br />
*CO, NO, SO2 ship emissions from the HTAP inventory<br />
*Data Years: 2008-2010<br />
*[http://edgar.jrc.ec.europa.eu/htap/EDGAR-HTAP_v1_final_jan2012.pdf See this document] for more information.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/HTAP/v2015-03/README README]<br />
|<tt>$ROOT/HTAP/v2015-03</tt><br />
|4.5 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[Ship_emissions#ICOADS|'''ICOADS_SHIP''']]<br />
*CO ship emissions from the ICOADS inventory<br />
*Data Years: 2002<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/ICOADS_SHIP/v2014-07/README README]<br />
|<tt>$ROOT/ICOADS_SHIP/v2014-07</tt><br />
|4.2 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[Ship_emissions#ARCTAS|'''ARCTAS_SHIP''']]<br />
*SO2 ship emissions from the ARCTAS inventory<br />
*Data Years: 2008<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/ARCTAS_SHIP/v2014-07/README README]<br />
|<tt>$ROOT/ARCTAS_SHIP/v2014-07</tt><br />
|508 KB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[Ship_emissions#Corbett|'''CORBETT_SHIP''']]<br />
*SO2 ship emissions from Corbett et al inventory<br />
*Data Years: 1985<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CORBETT_SHIP/v2014-07/README README]<br />
|<tt>$ROOT/CORBETT_SHIP/v2014-07</tt><br />
|1.8 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[EPA/NEI11_North_American_emissions|'''NEI2011_SHIP''']]<br />
*Hourly coastal ship emissions from the NEI_2011 inventory<br />
*Data Years: 2006-2013<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NEI2011/v2015-03/README README]<br />
|<tt>$ROOT/NEI2011/v2015-03</tt><br />
|248 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[EPA/NEI11_North_American_emissions|'''NEI2011_SHIP_MONMEAN''']]<br />
*Monthly mean coastal ship emissions from the NEI2011 inventory<br />
*Data Years: 2006-2013<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NEI2011/v2015-03/README README]<br />
|<tt>$ROOT/NEI2011/v2017-02-MM</tt><br />
|248 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|}<br />
<br />
NOTES about ship emissions:<br />
#CEDS ship emissions are the default ship inventory in [[GEOS-Chem 12#12.1.0|GEOS-Chem 12.1.0]] and later versions.<br />
#*Data files for CEDS ship emissions are stored with the other CEDS emission sector files in the HEMCO data path: <tt>$ROOT/CEDS/v2018-04/</tt>. <br />
#If CEDS emissions are turned off above then:<br />
#*ARCTAS should be used over ICOADS, CORBETT, and HTAP for SO2<br />
#*ICOADS should be used for CO and NO.<br />
#The NEI2011 ship emissions data only extends a few km from land. They are therefore coastal emissions inventories and not global emissions inventories.<br />
<br />
=== Future emissions ===<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|-bgcolor="#cccccc"<br />
!width="450px"|Inventory<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="150px"|Default or Optional?<br />
<br />
|-valign="top"<br />
|[[RCP_future_emissions_scenarios#RCP_scenarios_in_GEOS-Chem_v10-01_and_higher_versions|'''RCP_3PD''']]<br />
*Emissions for scenario RCP_3PD<br />
*Data Years: 2005-2100<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/RCP/v2020-07/README README]<br />
|<tt>$ROOT/RCP/v2020-07/RCP_3PD</tt><br />
|91 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[RCP_future_emissions_scenarios#RCP_scenarios_in_GEOS-Chem_v10-01_and_higher_versions|'''RCP_45''']]<br />
*Emissions for scenario RCP_45<br />
*Data Years: 2005-2100<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/RCP/v2020-07/README README]<br />
|<tt>$ROOT/RCP/v2020-07/RCP_45</tt><br />
|93 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[RCP_future_emissions_scenarios#RCP_scenarios_in_GEOS-Chem_v10-01_and_higher_versions|'''RCP_60''']]<br />
*Emissions for scenario RCP_60<br />
*Data Years: 2005-2100<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/RCP/v2020-07/README README]<br />
|<tt>$ROOT/RCP/v2020-07/RCP_60</tt><br />
|92 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[RCP_future_emissions_scenarios#RCP_scenarios_in_GEOS-Chem_v10-01_and_higher_versions|'''RCP_85''']]<br />
*Emissions for scenario RCP_85<br />
*Data Years: 2005-2100<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/RCP/v2020-07/README README]<br />
|<tt>$ROOT/RCP/v2020-07/RCP_85</tt><br />
|93 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|}<br />
<br />
=== Biomass burning emissions (not implemented as extensions) ===<br />
<br />
''NOTE: Some biomass burning inventories are implemented as HEMCO extensions. See the [[#Emissions implemented as HEMCO extensions|Emissions implemented as HEMCO extensions]]'' below for more information.''<br />
<br />
The following subdirectories of the HEMCO directory tree contain inventories of biomass burning emissions.<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|-bgcolor="#cccccc"<br />
!width="450px"|Inventory<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="150px"|Default or Optional?<br />
<br />
|-valign="top"<br />
|[[GFAS_biomass_burning_emissions|'''GFAS''']]<br />
*CAMS Global Fire Assimilation System estimated emissions<br />
*Injection height info is taken from<br />
** ECMWF fire observations<br />
** ECMWF operational weather forecasts.<br />
*Data Years: 2003-2020<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/GFAS/v2018-09/README README]<br />
|<tt>$ROOT/GFAS/v2018-09</tt><br />
|49 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
<br />
|-valign="top"<br />
|[[QFED_biomass_burning_emissions|'''QFED''']]<br />
*Quick Fire Emissions Database (v2.5r1)<br />
*Data Years: 2003-2020<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/QFED/v2018-07/README README]<br />
|<tt>$ROOT/QFED/v2018-07</tt><br />
|247 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|}<br />
<br />
=== Offline grid-independent emissions ===<br />
<br />
Offline grid-independent emissions were generated by running high-resolution (0.25&deg;x0.3125&deg; for GEOS-FP, 0.5&deg;x0.625&deg; for MERRA-2) simulations using the HEMCO standalone and online emissions from the [[#Emissions implemented as HEMCO extensions|HEMCO extensions]].<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|-bgcolor="#cccccc"<br />
!width="450px"|Inventory<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="150px"|Default or Optional?<br />
<br />
|-valign="top"<br />
|[[Mineral_dust_aerosols#Offline_Dust_Emissions|'''OFFLINE_DUST''']]<br />
*Dust emissions archived from HEMCO standalone simulations<br />
*Data Years: 1980-2020<br />
**NOTE: If you use OFFLINE_DUST, you must turn off both DustDead and DustGinoux extensions.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OFFLINE_DUST/v2019-01/README README]<br />
|<tt>$ROOT/OFFLINE_DUST/v2019-01</tt><br />
|18 GB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Grid-independent_emissions#Biogenic_emissions|'''OFFLINE_BIOGENICVOC''']]<br />
*Biogenic VOC emissions generated from HEMCO standalone simulations<br />
*Data Years: 1980-2020<br />
**NOTE: The MEGAN extension should remain on so that it can calculate biogenic emissions for some species not in this inventory.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OFFLINE_BIOVOC/v2019-01/README README]<br />
|<tt>$ROOT/OFFLINE_BIOVOC/v2019-01</tt><br />
|1400 GB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Grid-independent_emissions#Biogenic_emissions|'''OFFLINE_SEASALT''']]<br />
*Sea salt emissions generated from HEMCO standalone simulations<br />
*Data Years: 1980-2020<br />
**NOTE: If you use OFFLINE_SEASALT, turn off the SeaSalt extension.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OFFLINE_SEASALT/v2019-01/README README]<br />
|<tt>$ROOT/OFFLINE_SEASALT/v2019-01</tt><br />
|876 GB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
<br />
|-valign="top"<br />
|[[Grid-independent_emissions#Biogenic_emissions|'''OFFLINE_SOILNOX''']]<br />
*Soil NOx emissions generated from HEMCO standalone simulations<br />
*Data Years: 1980-2020<br />
**NOTE: If you use OFFLINE_SOILNOX, you must turn off the SoilNOx extension.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OFFLINE_SOILNOX/v2019-01/README README]<br />
|<tt>$ROOT/OFFLINE_SOILNOX/v2019-01</tt><br />
|48 GB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|}<br />
<br />
=== Non-emissions data ===<br />
<br />
The following subdirectories of the HEMCO directory tree input data contains non-emissions data sets. Most of these are used as inputs to GEOS-Chem's chemistry modules (i.e. photolysis, stratospheric chemistry, etc.).<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|-bgcolor="#cccccc"<br />
!width="450px"|Inventory<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="150px"|Default or Optional?<br />
<br />
|-valign="top"<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/UVALBEDO/v2016-06/README '''UVALBEDO''']<br />
*Hermann & Celarier [1997] UV surface albedo data <br />
*Data years: 1997 (1985 timestamps)<br />
*Needed for FAST-JX photolysis<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/UVALBEDO/v2019-06/README README]<br />
|<tt>$ROOT/UVALBEDO/v2019-06</tt><br />
|476 KB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Bromine_chemistry_mechanism#Source code and data files|'''CCM_STRAT_Bry''']]<br />
*Stratospheric Bry from the CCM model<br />
*Data years: 2007<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/STRAT/v2015-01/Bry/README README]<br />
|<tt>$ROOT/STRAT/v2015-01/Bry</tt><br />
|385 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Stratospheric chemistry|'''GMI_STRAT_OH''']]<br><br />
*OH concentration (v/v) from the GMI model<br />
*Data years: 2005<br />
|rowspan="2"|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/GMI/v2015-02/README README]<br />
|rowspan="2"|<tt>$ROOT/GMI/v2015-02</tt><br />
|rowspan="2"|16 GB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Stratospheric chemistry|'''GMI_PROD_LOSS''']]<br><br />
*P & L rates from the GMI model<br />
*Data years: 2005<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[UCX chemistry mechanism|'''UCX_PROD_LOSS''']]<br />
*P & L rates from GEOS-Chem simulations with UCX<br />
*Data years: 2013<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/UCX/v2018-02/README README]<br />
|<tt>$ROOT/UCX/v2018-02</tt><br />
|12 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OMOC/v2018-01/README '''OMOC_RATIO''']<br />
*Spatially varying OM/OC ratios for SOA species<br />
*Data years: 2010<br />
**NOTE: OMOC_RATIO is controlled by a switch in <tt>input.geos</tt><br>(default is OFF)<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OMOC/v2018-01/README README]<br />
|<tt>$ROOT/OMOC/v2018-01</tt><br />
|8.6 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[NOx-Ox-HC-aerosol#Monthly_mean_surface_distributions|'''GMD_SFC_CH4''']]<br />
*NOAA GMD monthly mean surface methane distributions<br />
*Data years: 1979-2020<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NOAA_GMD/v2018-01/README]<br />
|<tt>$ROOT/NOAA_GMD/v2018-01</tt><br />
|85 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[NOx-Ox-HC-aerosol#Monthly_mean_surface_distributions|'''CMIP6_SFC_CH4''']]<br />
*CMIP6 monthly mean surface methane distributions<br />
*Data years: 1750-1978<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CMIP6/v2019-12/README]<br />
|<tt>$ROOT/CMIP6/v2019-12</tt><br />
|85 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[Olson land map|'''OLSON_LANDMAP''']]<br />
*Masks for each Olson land type<br />
*Data years: 1985<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OLSON_MAP/v2019-02/README README]<br />
|<tt>$ROOT/OLSON_MAP/v2019-02</tt><br />
|1.9 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Leaf_area_indices_in_GEOS-Chem#Yuan_processed_MODIS_LAI|'''YUAN_MODIS_LAI''']]<br />
*Yuan-processed MODIS XLAI<br>(leaf area index per land type)<br />
*Data years: 2005-2016<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MODIS_XLAI/v2017-07/README README]<br />
|<tt>$ROOT/Yuan_XLAI/v2019-03</tt><br />
|203 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Coupling GEOS-Chem with RRTMG|'''RRTMG''']]<br />
*RRTMG radiative transfer model input data (e.g. surface reflectances etc.)<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/RRTMG/v2018-11/README README]<br />
|<tt>$ROOT/RRTMG/v2018-11</tt><br />
|19 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/SfcFix/v2019-12/README '''SfcVMR''']<br />
*Latitudinally and monthly resolved fixed surface concentrations for long-lived organohalogen species from GMI and UCX (1959-2099)<br />
*Data years: 1750-2014<br />
|<br />
[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/SfcFix/v2019-12/README README]<br />
|<tt>HEMCO/SfcFix/v2019-12</tt><br />
|851 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[https://www.atmos-chem-phys-discuss.net/acp-2019-1043/ '''OCEAN_O3_DRYDEP''']<br />
*Ozone deposition to the ocean<br />
*Data years: 1985<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OCEAN_O3_DRYDEP/v2020-02/README README]<br />
|<tt>HEMCO/OCEAN_O3_DRYDEP/v2020-02</tt><br />
|388 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|}<br />
<br />
=== Emissions implemented as HEMCO extensions ===<br />
<br />
The following subdirectories of the HEMCO directory tree contain input data used by various HEMCO extensions. These HEMCO extensions compute emissions for quantities that depend on meteorological variables (e.g. emissions from lighting, biogenic processes, etc.).<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|-bgcolor="#cccccc"<br />
!width="450px"|HEMCO Extension<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="150px"|Default or Optional?<br />
<br />
|-valign="top"<br />
|'''SeaFlux'''<br />
*Ocean exchange<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/ACET/v2014-07/README README1]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/ALD2/v2017-03/README README2]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/DMS/v2015-07/README README3]<br />
|<tt>$ROOT/ACET/v2014-07</tt><br><tt>$ROOT/ALD2/v2017-03</tt><br><tt>$ROOT/DMS/v2015-07</tt><br />
|5.8 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Ship_emissions#PARANOX_ship_plume_model|'''ParaNOx''']]<br />
*PARANOX ship plume model, computes the aging of emissions in ship exhaust plumes.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/PARANOX/v2015-02/README README]<br />
|<tt>$ROOT/PARANOX/v2015-02</tt><br />
|162 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[Lightning_NOx_emissions|'''LightNOx''']]<br />
*Computes NO from lightning<br />
*May be used instead of OFFLINE_LIGHTNING<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/LIGHTNOX/v2017-09/README README]<br />
|<tt>$ROOT/LIGHTNOX/v2017-09</tt><br />
|32 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING''' <br />
<br />
|-valign="top"<br />
|[[Hudman_et_al_2012_soil_NOx_emissions_algorithm|'''SoilNOx''']]<br />
*Hudman et al [2012] soil NOx emissions algorithm<br />
**NOTE: If you use SoilNOx, turn off OFFLINE_SOILNOX.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/SOILNOX/v2014-07/README README]<br />
|<tt>$ROOT/SOILNOX/v2014-07</tt><br />
|730 MB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING''' <br />
<br />
|-valign="top"<br />
|[[Mineral dust aerosols|'''DustDead''']]<br />
*DEAD dust model (cf. Zender)<br />
**NOTE: If you use DustDead, turn off OFFLINE_DUST.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/DUST_DEAD/v2014-07/README README]<br />
|<tt>$ROOT/DUST_DEAD/2014-07</tt><br />
|712 KB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[Mineral dust aerosols|'''DustGinoux''']]<br />
*Ginoux et al dust model<br />
**NOTE: If you use DustDead, turn off OFFLINE_DUST.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/DUST_GINOUX/v2014-07/README README]<br />
|<tt>$ROOT/DUST_GINOUX/2014-07</tt><br />
|36 KB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[Mineral dust aerosols|'''SeaSalt''']]<br />
*Sea salt emissions<br />
**NOTE: If you use SeaSalt, turn off OFFLINE_SEASALT.<br />
|colspan="3"|Does not have an associated data directory<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[MEGAN_v2.1_plus_Guenther_2012_biogenic_emissions|'''MEGAN''']]<br />
*MEGAN v2.1 biogenic emissions<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MEGAN/v2018-05/README README]<br />
|<tt>$ROOT/MEGAN/v2018-05</tt><br />
|12 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[GFED4_biomass_burning_emissions|'''GFED4''']]<br />
*GFED4 biomass burning v4.1, data directory contains dry matter and other inputs<br />
*Data Years: 1988-2019 (monthly-mean)<br />
*Daily & hourly emissions are possible with the use of scale factors.<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/GFED4/v2020-02/README README]<br />
|<tt>$ROOT/GFED4/v2020-02</tt><br />
|296 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|[[FINNv1_biomass_burning_emissions#FINN_v1.5_data|'''FINN''']]<br />
*FINN biomass burning (v1.5)<br />
*Data Years: 2002-2016<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/FINN/v2015-02/README README]<br />
|<tt>$ROOT/FINN/v2015-02</tt><br />
|1.2 GB<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|'''DustAlk'''<br />
*Computes dust alkalinity (for aciduptake simulation only)<br />
|colspan="3"|Does not have an associated data directory.<br />
|bgcolor="#FFFF00"|'''OPTIONAL SETTING'''<br />
<br />
|-valign="top"<br />
|[[Volcanic_SO2_emissions|'''Volcano''']]<br />
*Volcanic SO2 emissions from Aerocom<br />
*Data Years: 1978-2020<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/VOLCANO/v2019-08/README README]<br />
|<tt>$ROOT/VOLCANO/v2019-08</tt><br />
|63 MB<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|-valign="top"<br />
|'''Inorg_Iodine'''<br />
*Inorganic iodine emissions (HOI, I2)<br />
|colspan="3"|Does not have an associated data directory.<br />
|bgcolor="#00FF00"|'''DEFAULT SETTING'''<br />
<br />
|}<br />
<br />
== Other HEMCO data directories ==<br />
<br />
In each of the tables below:<br />
<br />
:The '''Directory''' column contains a description of the directory and its contents.<br />
<br />
:The '''More info''' column points to the README files that are stored with each data set. <br />
<br />
:The '''Path''' column shows the location of each data set, with respect to <tt>$ROOT</tt>, the top-level HEMCO directory. For example, on the Harvard disk server, <tt>$ROOT</tt> points to the directory <tt>/mnt/gcgrid/data/ExtData/HEMCO/</tt>. <br />
<br />
:The '''Used by?''' column lists in which context the data in each directory is used.<br />
<br />
=== HEMCO scale factors, masks, and other data ===<br />
<br />
The following subdirectories of the HEMCO directory tree contain scale factors for various emissions inventories<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|- bgcolor="#cccccc"<br />
!width="325px"|Directory<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="325px"|Used by?<br />
<br />
|-valign="top"<br />
|[[Scale_factors_for_anthropogenic_emissions|'''AnnualScalar''']]<br />
*Directory containing annual scale factors<br />
|[ftp://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/AnnualScalar/v2014-07/README README]<br />
|<tt>$ROOT/AnnualScalar/v2014-07</tt><br />
|3.0 MB<br />
|Only needed for the following inventories:<br />
*HTAP<br />
*MIX<br />
*XIAO_C3H8<br />
<br />
|-valign="top"<br />
|[[EPA/NEI05_North_American_emissions|'''NEI2005''']]<br />
*Directory containing NEI2005 scale factors<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/NEI2005/v2014-09/README README]<br />
|<tt>$ROOT/NEI2005/v2014-09</tt><br />
|8.1 MB<br />
|Only needed for the following inventories:<br />
*NEI2011_HOURLY<br />
*NEI2011_MONMEAN<br />
<br />
|-valign="top"<br />
|'''MASKS'''<br />
*Directory containing mask files for regional emission inventories<br />
|[ftp://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MASKS/v2014-07/README README]<br />
|<tt>$ROOT/MASKS/v2014-07</tt><br />
|148 MB<br />
|Needed for regional emissions inventories<br />
<br />
|-valign="top"<br />
|'''COUNTRY_ID'''<br />
*Directory containing [http://www.nationsonline.org/oneworld/country_code_list.htm ISO ALPHA-3 standard] country codes on an 0.1&deg; x 0.1&deg; grid. <br />
*HEMCO can use these ID's to apply country-level scale factors to any emissions field.<br />
|[ftp://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/COUNTRY_ID/v2015-04/README README]<br />
|<tt>$ROOT/COUNTRY_ID/v2015-04</tt><br />
|15 MB<br />
|Not currently used, but is available for research needs<br />
<br />
|-valign="top"<br />
|'''TIMEZONES'''<br />
*Timezone offsets from UTC, needed to compute emissions that depend on local solar time<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/TIMEZONES/v2015-02/README README]<br />
|<tt>$ROOT/TIMEZONES/v2015-02</tt><br />
|264 KB<br />
|This data will always be read by HEMCO, regardless of simulation type<br />
<br />
|}<br />
<br />
=== GEOS-Chem specialty simulation data ===<br />
<br />
The following subdirectories of the HEMCO directory tree input data (emissions, oxidants, etc.) for use with the [[GEOS-Chem_chemistry_mechanisms#Specialty_simulations|GEOS-Chem specialty simulations (i.e. those that do not use the fullchem mechanism)]]. If you do not regularly use these simulations, you may choose not to download these data directories.<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|- bgcolor="#cccccc"<br />
!width="325px"|Directory<br />
!width="90px"|More info<br />
!width="275px"|Path<br />
!width="75px"|Data size<br />
!width="325px"|Used by?<br />
<br />
|-valign="top"<br />
|'''CH4'''<br />
*Various data<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CH4/v2017-10/README README1]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CH4/v2014-09/README README2]<br />
|<tt>$ROOT/CH4/v2017-10</tt><br><tt>$ROOT/CH4/v2014-09</tt><br />
|6.6 GB<br />
|<br />
*[[CH4 simulation|CH4 and tagCH4 specialty simulations]]<br />
<br />
|-valign="top"<br />
|'''CO2'''<br />
*Various data sources<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CO2/v2015-04/README README1]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CO2/v2015-04/BIO/README README2]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CO2/v2015-04/BIOFUEL/README README3]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CO2/v2015-04/CHEM/README README4]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CO2/v2015-04/FOSSIL/README README5]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CO2/v2015-04/OCEAN/README README6]<br />
|<tt>$ROOT/CO2/v2015-04<br>$ROOT/CO2/v2015-04/BIO/<br>$ROOT/CO2/v2015-04/BIOFUEL/<br>$ROOT/CO2/v2015-04/CHEM/<br>$ROOT/CO2/v2015-04/FOSSIL/<br>$ROOT/CO2/v2015-04/OCEAN/</tt><br />
|1.5 GB<br />
|<br />
*[[CO2 simulation]]<br />
<br />
|-valign="top"<br />
|'''CHLA'''<br />
*Oceanic Chlorophyll-A <br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/CHLA/v2014-07/README README]<br />
|<tt>$ROOT/CHLA/v2014-07</tt><br />
|2.0 MB<br />
|<br />
*[[Mercury|Mercury simulation]]<br />
<br />
|-valign="top"<br />
|'''MERCURY'''<br />
*Various emission inventories & data<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/README README1]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/ARTISANAL/README README2]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/BrOx/README README3]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/Hg2_PARTITION/README README4]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/JVALUES/README README5]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/NATURAL/README README6]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/NEI2005/README README7]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/OCEAN/README README8]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/SOIL/README README9]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/MERCURY/v2014-09/STREETS/README README10]<br />
|<tt>$ROOT/MERCURY/v2014-09<br>$ROOT/MERCURY/v2014-09/ARTISANAL<br>$ROOT/MERCURY/v2014-09/BrOx<br>$ROOT/MERCURY/v2014-09/Hg2_PARTITION<br>$ROOT/MERCURY/v2014-09/JVALUES<br>$ROOT/MERCURY/v2014-09/NATURAL<br>$ROOT/MERCURY/v2014-09/NEI2005<br>$ROOT/MERCURY/v2014-09/OCEAN<br>$ROOT/MERCURY/v2014-09/SOIL<br>$ROOT/MERCURY/v2014-09/STREETS</tt><br />
|3.0 GB<br />
|<br />
*[[Mercury|Mercury simulation]]<br />
<br />
|-valign="top"<br />
|'''O3'''<br />
*Archived O3 fields<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/O3/v2014-09/README README]<br />
|<tt>$ROOT/O3/v2014-09</tt><br />
|130 MB<br />
|<br />
*[[Mercury|Hg and tagHg simulations]]<br />
*[[POPs simulation|POPs simulation]]<br />
<br />
|-valign="top"<br />
|'''OFFLINE_AEROSOL'''<br />
*Archived concentrations and P/L rates<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OFFLINE_AEROSOL/v2014-09/README README]<br />
|<tt>$ROOT/OFFLINE_AEROSOL/v2014-09</tt><br />
|165 MB<br />
|<br />
*[[Aerosol-only simulation]]<br />
<br />
|-valign="top"<br />
|'''OH'''<br />
*Archived OH fields<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OH/v2014-09/v5-07-08/README README1]<br>[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OH/v2014-09/v7-02-03.GMI/README README2]<br />
|<tt>$ROOT/OH/v2014-09<br>$ROOT/OH/v2014-09/v5-07-08<br>$ROOT/OH/v2014-09/v7-02-03.GMI</tt><br />
|95 MB<br />
|<br />
*[[Aerosol-only simulation]]<br />
*[[CH4 simulation|CH4 and tagCH4 simulations]]<br />
*[[Mercury|Hg and tagHg simulations]]<br />
*[[POPs simulation|POPs simulation]]<br />
*[[Tagged CO simulation]]<br />
<br />
|-valign="top"<br />
|'''OXIDANTS'''<br />
*Archived P(H2O2)<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/OXIDANTS/v2014-07/README README]<br />
|<tt>$ROOT/OXIDANTS/v2014-07</tt><br />
|32 MB<br />
|<br />
*[[Aerosol-only simulation]]<br />
<br />
|-valign="top"<br />
|'''POPs'''<br />
*Various data<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/POPs/v2015-08/README README]<br />
|<tt>$$ROOT/POPs/v2015-08</tt><br />
|809 MB<br />
|<br />
*[[POPs simulation]]<br />
<br />
|-valign="top"<br />
|'''TAGGED_CO'''<br />
*Archived P(CO)<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/TAGGED_CO/v2017-04/README README]<br />
|<tt>$ROOT/TAGGED_CO/v2017-04</tt><br />
|79 MB<br />
|<br />
*[[Tagged CO simulation]]<br />
<br />
|-valign="top"<br />
|'''TAGGED O3'''<br />
*Archived P(O3) and L(O3)<br />
|[http://ftp.as.harvard.edu/gcgrid/data/ExtData/HEMCO/TAGGED_O3/v2014-09/README README]<br />
|<tt>$ROOT/TAGGED_O3/v2014-09</tt><br />
|374 MB<br />
|<br />
*[[Tagged O3 simulation]]<br />
<br />
|}<br />
<br />
== Submitting new data for use with HEMCO ==<br />
<br />
If you have a new emissions inventory or other atmospheric data set that you would like to add to the HEMCO data directories, then please contact the [[GEOS-Chem Support Team]]. Data files must be in COARDS-compliant or CF-compliant netCDF format. Please see the following pages for more information:<br />
<br />
#''[[Preparing data files for use with HEMCO|''Preparing data files for use with HEMCO]]''<br />
#''[[Submitting updates for inclusion in GEOS-Chem]]''<br />
<br />
--[[User:Bmy|Bob Yantosca]] ([[User talk:Bmy|talk]]) 22:24, 14 January 2020 (UTC)</div>
Zitely
https://wiki.seas.harvard.edu/geos-chem/index.php?title=Emissions_Working_Group&diff=35524
Emissions Working Group
2018-02-21T23:25:32Z
<p>Zitely: /* Current Projects (please add yours!) */</p>
<hr />
<div><u>The purpose of this Working Group</u> is to provide a forum to discuss current and new developments in GEOS-Chem associated with land-atmosphere and ocean-atmosphere sources, sinks, and fluxes of trace gases and aerosols.<br />
<br />
All users interested in adding/updating the GEOS-Chem emissions inventories are encouraged to subscribe to the emissions email list (click on the link in the [[#Primary Working Group Contacts|contact information section]] below).<br />
<br />
== Contact Information ==<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|-valign="top"<br />
!width="300px" bgcolor="#CCCCCC"|Emissions and Deposition<br>Working Group Co-Chairs<br />
|width="600px"|<br />
*[http://www.atmos.colostate.edu/faculty/fischer.php Emily Fischer]<br />
*[http://www.atmos.pku.edu.cn/acm/contact.html Jintai Lin]<br />
*[http://www.birmingham.ac.uk/staff/profiles/gees/marais-eloise.aspx Elo&iuml;se Marais]<br />
*[http://www.atmoschem.umn.edu Dylan Millet]<br />
<br />
|-valign="top"<br />
!bgcolor="#CCCCCC"|Emissions and Deposition<br>Working Group email list<br />
|<tt>geos-chem-emissions [at] g.harvard.edu</tt><br />
<br />
|-valign="top"<br />
!bgcolor="#CCCCCC"|To subscribe to email list<br />
|Either<br />
*Send an email to <tt>geos-chem-emissions+subscribe [at] g.harvard.edu</tt><br />
Or<br />
*Go to the [https://groups.google.com/a/g.harvard.edu/forum/#!forum/geos-chem-emissions GEOS-Chem Emissions and Deposition Google Group]<br />
*Click on '''Subscribe to this group'''<br />
<br />
|-valign="top"<br />
!bgcolor="#CCCCCC"|To unsubscribe from email list<br />
|Either<br />
*Send an email to <tt>geos-chem-emissions+unsubscribe [at] g.harvard.edu</tt><br />
Or<br />
*Go to the [https://groups.google.com/a/g.harvard.edu/forum/#!forum/geos-chem-emissions GEOS-Chem Emissions and Deposition Google Group]<br />
*Click on the '''My Settings''' button<br />
*Click on '''Leave this group'''<br />
|}<br />
<br />
--[[User:Bmy|Bob Y.]] ([[User talk:Bmy|talk]]) 18:35, 21 August 2015 (UTC)<br />
<br />
== Current Projects (please add yours!) ==<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|- bgcolor="#cccccc"<br />
!width="150px"|User Group <br />
!width="600px"|Description <br />
!width="150px"|Contact Person<br />
!width="100px"|Date Added<br />
|-<br />
|Birmingham, UK<br />
|STEAM3 ship emission inventory<br />
|[mailto:e.a.marais@bham.ac.uk Eloise Marais]<br />
|October 2017<br />
|-<br />
|Birmingham, UK/NCAR<br />
|Inefficient combustion emissions in Africa<br />
|[mailto:e.a.marais@bham.ac.uk Eloise Marais]<br />
|April 2017<br />
|-<br />
|Peking U<br />
|Agricultural ammonia emissions in China<br />
|[mailto:zhanglg@pku.edu.cn Lin Zhang]<br />
|Nov 2017<br />
|-<br />
|University of Minnesota<br />
|VOC emissions in India <br />
|[mailto:chali011@umn.edu Sree Chaliyakunnel]<br />
|31 August 2017<br />
|-<br />
|MIT<br />
|Investigating ozone dry deposition to vegetation<br />
|[mailto:samsilva@mit.edu Sam Silva]<br />
|08 May 2017<br />
|-<br />
|CUHK / Boston U<br />
|Linking stomatal resistance to photosynthesis calculation in dry deposition<br />
|[mailto:amostai@cuhk.edu.hk Amos Tai] [mailto:jgeddes@bu.edu Jeffrey Geddes]<br />
|08 May 2017<br />
|-<br />
|U. Wollongong (Aus)<br />
|Top-down constraints on Isoprene emissions in Australia using OMI<br />
|[mailto:jwg366@uowmail.edu.au Jesse Greenslade]<br />
|28 Sep 2017<br />
|-<br />
|U. York (UK)<br />
|Improving the parameterization of oceanic dry deposition of ozone<br />
|[mailto:rp819@york.ac.uk Ryan Pound]<br />
|1 Nov 2017<br />
|-<br />
|Colorado State University (USA)<br />
|Implementation of a newer version of the 2011 U.S. National Emission Inventory and the atmospheric implications of the light alkanes emitted from the U.S. oil and gas industry<br />
|[mailto:zitely@colostate.edu Zitely Tzompa-Sosa]<br />
|21 Feb 2018<br />
|-<br />
|}<br />
<br />
== Top-down Findings Germane to GEOS-Chem Inventories (please add yours!) ==<br />
<br />
Science findings from top-down studies that have implications for inventories used in GEOS-Chem (e.g., an inferred high or low bias or other such issue) can be compiled in [[Inventory Findings|this table]]. Please add any findings, either from your group or from other groups, that you feel the GEOS-Chem community should be aware of in using these inventories.<br />
<br />
--[[User:Dbm|Dbm]] ([[User talk:Dbm|talk]]) 00:57, 1 September 2017 (UTC)<br />
<br />
== Ongoing Developments (please add yours!) ==<br />
<br />
Here is the list of updates that are slated to be added to GEOS-Chem in the next few releases:<br />
<br />
{| border=1 cellspacing=0 cellpadding=5<br />
|- bgcolor="#cccccc"<br />
!width="400"|Update<br />
!width="200"|Authors<br />
!width="400"|Planned release<br />
<br />
|-valign="top"<br />
|[[HEMCO|HEMCO emissions component]]<br />
|Christoph Keller (Harvard)<br />
|<br />
*Implemented into [[GEOS-Chem v10-01]], updated as needed<br />
<br />
|-valign="top"<br />
|[[MEGAN biogenic emissions]]<br />
|Michael Barkley (Leicester)<br />
|<br />
*Updates ongoing<br />
<br />
|-valign="top"<br />
|Australian anthropogenic emissions<br />
|Jenny Fisher (Wollongong)<br />
|<br />
*Updates ongoing<br />
<br />
|}<br />
<br />
--[[User:Bmy|Bob Y.]] 18:55, 14 January 2015 (EST)<br />
<br />
== Recent Updates ==<br />
<br />
We have added the following updates pertaining to emissions and deposition to recent GEOS-Chem versions:<br />
<br />
{| border=1 cellspacing=0 cellpadding=5 <br />
|-bgcolor="#CCCCCC" valign="top"<br />
!width="75px"|Version<br />
!width="75px"|Released<br />
!width="550px"|Description<br />
!width="250px"|Contact<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v11-01|v11-01]]<br />
|Jan 2017<br />
|[[Implementation_of_HEMCO_in_GEOS-Chem#Features_added_in_v11-01j|Update HEMCO to version 2.0.003]]<br />
|Christoph Keller (NASA GSFC)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v11-01|v11-01]]<br />
|Jan 2017<br />
|[[CAC_anthropogenic_emissions#High_resolution_emissions|0.1&deg; x 0.1&deg; CAC emissions]]<br />
|Aaron van Donkelaar (Dalhousie)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v11-01|v11-01]]<br />
|Jan 2017<br />
|[[Implementation_of_RETRO_Anthropogenic_Emissions#RETRO_anthropogenic_propane_emissions_are_too_low|Replace RETRO C3H8 emissions with emissions from Xiao et al. (2008)]]<br />
|Emily Fischer (CSU)<br>Zitely Tzompa (CSU)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v11-01|v11-01]]<br />
|Jan 2017<br />
|[[Mercury#Add_option_for_QFED_.26_FINN_biomass_burning_emissions|Add option for QFED & FINN emissions in the Hg simulations]]<br />
|Jenny Fisher (Wollongong)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v11-01|v11-01]]<br />
|Jan 2017<br />
|[[MEGAN_v2.1_plus_Guenther_2012_biogenic_emissions#CO2_direct_effect_on_isoprene_emissions|CO2 direct effect on isoprene emissions]]<br />
|Amos Tai (CUHK)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v11-01|v11-01]]<br />
|Jan 2017<br />
|[[GFED4_biomass_burning_emissions#Update_to_GFED_4.1|Update biomass burning emissions to GFED4.1]], includes:<br />
*Daily and diurnal factors<br />
|Prasad Kasibhatla (Duke)<br>Christoph Keller (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v10-01|v10-01]]<br />
|Jun 2015<br />
|The [[HEMCO|HEMCO emissions component]] now handles all GEOS-Chem emissions.<br />
|Christoph Keller (Harvard)<br>[[GCST]]<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v10-01|v10-01]]<br />
|Jun 2015<br />
|Daily anthropogenic emissions broken down by sector from the EPA NEI2008 inventory (via [[HEMCO]])<br />
|Katie Travis (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v10-01|v10-01]]<br />
|Jun 2015<br />
|[[Biomass_burning_emissions#FINNv1|FINNv1 biomass burning emissions]] (via [[HEMCO]])<br />
|Jenny Fisher (Wollongong)<br>Min Huang (JPL)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v10-01|v10-01]]<br />
|Jun 2015<br />
|[[MEGAN_v2.1_plus_Guenther_2012_biogenic_emissions|MEGAN v2.1 plus Guenther 2012 biogenic emissions]] (via [[HEMCO]])<br />
|Dylan Millet (Minnesota)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Soil NOx emissions#Updated soil NOx emissions algorithm|New soil NOx emission module]]<br />
|Rynda Hudman Kay (EPA)<br>Neil Moore (formerly of Dalhousie)<br>Bram Maasakkers (Harvard) <br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Mercury#Nested-grid Hg simulation over North America|EPA/NEI05 North American Hg emissions]]<br />
|Yanxu Zhang (U. Washington)<br>Lyatt Jaegl&eacute; (U. Washington) <br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Mercury#Streets future Hg emissions|Hg anthropogenic emissions options for the year 2006 or 2050 following SRES scenarios A1B, A2, B1, and B2 from Streets et al. 2009.]]<br />
|Bess Corbitt (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[EPA/NEI05 North American emissions#Updated NH3 seasonal scaling factors in_v9-02|Updated NH3 seasonal scaling factors over the US]]<br />
|Lin Zhang (PKU)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Anthropogenic emissions#CAC|Updated Canadian NH3 inventory]]<br />
|Wai-Ho Lo (Dalhousie)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Wet_deposition#Bug_in_Henry.27s_constant|Bug in wet deposition Henry's constant]]<br />
|Fabien Paulot (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[GEOS-Chem_v9-02#Bug fixes in_biofuel_mod.F and emfossil.F|Fix diurnal NOx scale factors and fix double counting of biofuels over Mexico, Canada, and Europe]]<br />
|Christoph Keller (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Ship emissions#Bugs in ship emissions and non-local PBL mixing|Correct bugs in ship emissions w/ non-local PBL mixing]]<br />
|Chris Holmes (UC Irvine)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[GEOS-Chem v9-02#Bug fixes in day-of-week computation|Bug fixes in day-of-week computation]]<br />
|[[GEOS-Chem Support Team]]<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Historical and Future Emissions#RCP future emission scenarios|RCP future emission scenarios]]<br />
|Chris Holmes (UC Irvine)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[CH4 simulation#Update CH4 emissions to EDGAR v4.2|EDGAR v4.2 emissions for CH4 simulation]]<br />
|Kevin Wecht (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Scale factors for anthropogenic emissions|Update anthropogenic scale factors through 2010]]<br />
|Aaron van Donkelaar (Dalhoisie)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Biomass burning emissions#Update GFED3 emissions to 2011|Update GFED3 emissions to 2011]]<br />
|Prasad Kasibhatla (Duke)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Aircraft emissions#MIT aviation emissions inventory|AEIC aircraft emissions inventory]]<br />
|Sebastian Eastham (MIT)<br>Steven Barrett (MIT) <br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[Dry deposition#Error in definition of RIP and IEPOX drydep species|Fix molecular weights of RIP and IEPOX used in drydep_mod.F]]<br />
|[[GEOS-Chem Support Team]]<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-02|v9-02]]<br />
|Mar 2014<br />
|[[EPA/NEI05 North American emissions#Bug fix for NEI2005 SO4 emissions in sulfate_mod.F|Bug fix for NEI2005 SO4 emissions in sulfate_mod.F]]<br />
|Jenny Fisher (U. Wollongong)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-03|v9-01-03]]<br />
|Sep 2012<br />
|[[Acetone|Improved acetone simulation]]<br />
|Emily Fischer (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-03|v9-01-03]]<br />
|Sep 2012<br />
|[[Biogenic emissions#Retirement of obsolete GEIA biogenic emissions|Complete shift of biogenic VOC emissions from GEIA to MEGAN; retire GEIA]]<br />
|Dylan Millet<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-03|v9-01-03]]<br />
|Sep 2012<br />
|[[Dry deposition#OVOCs dry deposition|OVOC's dry deposition]]<br />
|Jingqiu Mao (NOAA/GFDL) <br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-03|v9-01-03]]<br />
|Sep 2012<br />
|[[#Available Historical and Future Emissions|Historical emission inventories of SO2, NOx, BC, and POA]]<br />
|Eric Leibensperger (MIT)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-03|v9-01-03]]<br />
|Sep 2012<br />
|[[Ship emissions#PARANOX_ship_plume_model|PARANOX model for evolution of ship exhaust plumes]]<br />
|Geert Vinken (Eindhoven)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-03|v9-01-03]]<br />
|Sep 2012<br />
|Improved [[Wet deposition#Add scavenging by snow|snow scavenging]] and [[Wet deposition#Updates for aerosol scavenging efficiency|washout parameterization]]<br />
|Qiaoqiao Wang (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-03|v9-01-03]]<br />
|Sep 2012<br />
|[[Lightning NOx emissions|Constraining the lightning NOx source with satellite data]]<br />
|Lee Murray (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-03|v9-01-03]]<br />
|Sep 2012<br />
|[[Regridding in GEOS-Chem#Modification of MAP_A2A for use within GEOS-Chem|MAP_A2A algorithm to regrid emissions on the fly]]<br />
|Prasad Kasibhatla (Duke)<br>Matt Cooper (Dalhousie)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-03|v9-01-03]]<br />
|Sep 2012<br />
|[[Scale factors for anthropogenic emissions#Anthropogenic NOx scaling factors from OMI|Anthropogenic NOx scaling factors from OMI]]<br />
|Lok Lamsal (NASA)<br>Matt Cooper (Dalhousie)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-02|v9-01-02]]<br />
|Nov 2011<br />
|[[Mercury#Anthropogenic Emissions|GEIA 2005 Hg emissions]]<br />
|Bess Corbitt (Harvard)<br>Noelle Selin (MIT)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-02|v9-01-02]]<br />
|Nov 2011<br />
|[[EPA/NEI05_North_American_emissions#Biofuel_emissions|Bug fix for biofuel emissions when using EPA/NEI05]]<br />
|[[GEOS-Chem Support Team]]<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-02|v9-01-02]]<br />
|Nov 2011<br />
|[[Biomass burning emissions#GFED3|Update to GFED3 biomass burning]]<br />
|[mailto:psk9@duke.edu Prasad Kasibhatla] (Duke)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-02|v9-01-02]]<br />
|Nov 2011<br />
|[[Implementation of RETRO Anthropogenic Emissions|Anthropogenic VOCs]]<br />
|[mailto:dbm@umn.edu Dylan Millet] (UMN)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-02|v9-01-02]]<br />
|Nov 2011<br />
|[[Anthropogenic_emissions#Streets_2000|Added seasonality to Streets NH3 emissions over Asia]]<br />
|[mailto:jafisher@fas.harvard.edu Jenny Fisher] (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-01|v9-01-01]]<br />
|May 2011<br />
|Updated Hg simulation <br />
||Bess Corbitt (Harvard)<br>Jenny Fisher (Harvard)<br>Helen Amos (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-01|v9-01-01]]<br />
|May 2011<br />
|[[EPA/NEI05_North_American_emissions#Biofuel_emissions|Bug fix for biofuel emissions when using EPA/NEI05]]<br />
|[[GEOS-Chem Support Team]]<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-01|v9-01-01]]<br />
|May 2011<br />
|Bug fixes for [[Ship emissions#Bug for ship emissions in emfossil.f|ship emissions]] and [[Ship emissions#Inconsistent mask file for EMEP ship emissions|EMEP ship emissions mask file]]<br />
|[[GEOS-Chem Support Team]]<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-01|v9-01-01]]<br />
|May 2011<br />
|[http://seas.harvard.edu/~ltmurray/LNOx.v9-01-01.Release.Notes.pdf Updated lightning parameterization and fix for cloud-top-height algorithm]<br />
|L. Murray, Harvard<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-01|v9-01-01]]<br />
|May 2011<br />
|[[Volcanic SO2 emissions from Aerocom#Data for v9-01-01 and newer versions|Updated volcanic SO2 emissions from Aerocom]]<br />
| J. Fisher (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v9-01-01|v9-01-01]]<br />
|May 2011<br />
|[http://acmg.seas.harvard.edu/geos/wiki_docs/deposition/v9-01-01_wetdep.pdf Updated wet scavenging and convective updraft scavenging algorithms] and<br>[[Wet deposition#Allow both washout and rainout when precipitation forms|Allow both washout and rainout when precipitation forms]]<br />
|H. Amos (Harvard)<br>Bess Corbitt (Harvard)<br>Q. Wang (Harvard)<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-03-02|v8-03-02]]<br />
|Sep 2010<br />
|[[CO2_simulation| Updated CO2 Emissions]]<br />
|R. Nassar, Environment Canada<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-03-01|v8-03-01]]<br />
|May 2010<br />
|[[Scale factors for anthropogenic emissions| Extension of annual anthropogenic scale factors to 2006]]<br />
|A. van Donkelaar, Dalhousie<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-03-01|v8-03-01]]<br />
|May 2010<br />
|EMEP emissions extended to 2007 and seasonality extended to SOx, CO, and NH3<br />
|A. van Donkelaar, Dalhousie<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-03-01|v8-03-01]]<br />
|May 2010<br />
|Emissions for Nested NA/EU Simulations [[GEOS-Chem nested grid simulations|Nested Grid]]<br />
|A. van Donkelaar, Dalhousie<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-03-01|v8-03-01]]<br />
|May 2010<br />
|Emissions for Global 1 x 1.25 simulation capability<br />
|L. Lamsal, Dalhousie<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-03-01|v8-03-01]]<br />
|May 2010<br />
|[[Secondary organic aerosols#Speciated biogenic emissions from MEGAN|Speciated biogenic emissions from MEGAN v2.1 now used in SOA code]]<br />
|H. Pye, Caltech<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-02-04|v8-02-04]]<br />
|Feb 2010<br />
|[[EPA/NEI05 North American emissions|EPA/NEI2005 regional emissions inventory for North America]]<br />
|P. Le Sager (formerly Harvard),<br>A. van Donkelaar (Dalhousie)<br />
<br />
|-valign="top"align="center"<br />
|[[GEOS-Chem v8-02-04|v8-02-04]]<br />
|Feb 2010<br />
|[[MEGAN biogenic emissions#MEGAN in GEOS-Chem v8-02-04 and later versions|MEGAN v2.1 biogenic emissions]]<br />
|Mike Barkley, Edinburgh<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-02-04|v8-02-04]]<br />
|Feb 2010<br />
|[[Volcanic SO2 emissions from Aerocom|Updated inventory of volcanic SO2 emissions from AeroCom]]<br />
|Jenny Fisher, Harvard<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-02-03|v8-02-03]]<br />
|Oct 2009<br />
|[[Ship emissions#ICOADS|ICOADS ship emissions]]<br />
|Chulkyu Lee, Dalhousie<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-02-03|v8-02-03]]<br />
|Oct 2009<br />
|[[Lightning NOx emissions#Updated OTD.2FLIS local redistribution for GEOS-5|Updated OTD/LIS redistribution factors for GEOS-5]]<br />
|Lee Murray, Harvard<br />
<br />
|-valign="top"<br />
|[[GEOS-Chem v8-02-02|v8-02-02]]<br />
|Jun 2009 <br />
|[[#Error in the Bond BC/OC emissons|BOND inventory for BC and OC with monthly variations]]<br />
|Eric Leibensperger, Harvard<br />
<br />
|}<br />
<br />
--[[User:Melissa Payer|Melissa Sulprizio]] 10:43, 17 January 2014 (EST)<br />
<br />
== Recommended Default Emission Inventories ==<br />
<br />
Emission inventories for standard full chemistry runs. Entries in BLACK are the recommended default emission inventories, <span style="color:red">entries in RED are alternate options</span>, and <span style="color:green">entries in GREEN are inventories slated for inclusion in GEOS-Chem in the future</span>. Regional inventories overwrite global inventories for particular locations (indicated in the table).<br />
<br />
Year(s) show years for which the inventory is provided. In many cases annual scale factors are applied to extend the inventory to the past or present.<br />
<br />
Please see our [[HEMCO data directories]] wiki page for information about how to download data files for each of the currently-available inventories.<br />
<br />
{| border=1 cellspacing=0 cellpadding=5 <br />
|-bgcolor="#CCCCCC" valign="top"<br />
!width="90px"|Region<br />
!width="120px"|HEMCO ExtName<br />
!width="260px"|Description<br />
!width="140px"|Resolution<br />
!width="90px"|Year(s)<br />
!width="250px"|Species<br />
!width="280px"|References & Notes<br />
|-<br />
|-bgcolor="#CCFFFF" valign="top" align="left"<br />
!colspan="7"|Anthropogenic (Fossil, Biofuel and Process) Emission Inventories<br />
|-<br />
|Global<br />
|EDGAR<br />
|EDGAR v4.2 anthropogenic + biofuel<br />
|0.1&deg; x 0.1&deg;, monthly<br />
|1970-2008<br />
|NO<sub>x</sub>, SO<sub>2</sub>, SO<sub>4</sub>, CO, NH<sub>3</sub><br />
|http://edgar.jrc.ec.europa.eu/overview.php?v=42<br />
|-<br />
|Global<br />
|BOND<br />
|BOND biofuel + anthropogenic BC + OC emissions<br />
|1&deg; x 1&deg;, monthly<br />
|2000<br />
|BC and OC<br />
|Bond et al. (2007)<br />
|-<br />
|Global<br />
|RETRO<br />
|RETRO anthropogenic + biofuel<br />
|0.5&deg; x 0.5&deg;, monthly<br />
|2000<br />
|NMVOCs except C<sub>2</sub>H<sub>6</sub> and C<sub>3</sub>H<sub>8</sub><br />
|ftp://ftp.retro.enes.org/pub/emissions/aggregated/anthro/0.5x0.5/2000/<br />
|-<br />
|Global<br />
|XIAO<br />
|Fossil fuel + biofuel C<sub>2</sub>H<sub>6</sub> and C<sub>3</sub>H<sub>8</sub><br />
|1&deg; x 1&deg;, annual<br />
|1985<br />
|C<sub>2</sub>H<sub>6</sub> and C<sub>3</sub>H<sub>8</sub><br />
|Xiao et al. (2008)<br />
|-<br />
|<span style="color:green">Global</span><br />
|<span style="color:green">TZOMPA</span><br />
|<span style="color:green">Fossil fuel + biofuel C<sub>2</sub>H<sub>6</sub></span><br />
|<span style="color:green">2&deg; x 2.5&deg;, annual</span><br />
|<span style="color:green">2010</span><br />
|<span style="color:green">C<sub>2</sub>H<sub>6</sub></span><br />
|<span style="color:green">Tzompa-Sosa et al. (2017)</span><br />
|-<br />
|<span style="color:green">Global</span><br />
|<span style="color:green">TRASH</span><br />
|<span style="color:green">Trash burning (not in other inventories)</span><br />
|<span style="color:green">0.1&deg; x 0.1&deg;, annual</span><br />
|<span style="color:green">2010</span><br />
|<span style="color:green">NO<sub>x</sub>, SO<sub>2</sub>, SO<sub>4</sub>, CO, NH<sub>3</sub>, BC, OC, NMVOCs</span><br />
|<span style="color:green">Wiedinmyer et al. (2014)</span><br />
|-<br />
|Global<br />
|SHIP<br />
|ICOADS ship emissions<br />
|1&deg; x 1&deg;, monthly<br />
|2002<br />
|NO<sub>x</sub>, SO<sub>2</sub>, CO<br />
|Wang et al. (2008).<br />
|-<br />
|Global<br />
|AEIC<br />
|Aircraft emissions<br />
|1&deg; x 1&deg;, annual<br />
|2005<br />
|NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, BC, OC<br />
|Stettler et al. (2011)<br />
|-<br />
|Global<br />
|ParaNOx<br />
|Ship plume O<sub>3</sub> and HNO<sub>3</sub> formation<br />
|N.A.<br />
|N.A.<br />
|O<sub>3</sub>, HNO<sub>3</sub><br />
|Vinken et al. (2011) with updates from Holmes et al. (2014)<br />
|-<br />
|<span style="color:red">Global</span><br />
|<span style="color:red">RCP_3PD, RCP_45, RCP_60, RCP_85</span><br />
|<span style="color:red">RCP scenarios 3PD, 4.5, 6.0, 8.5</span><br />
|<span style="color:red">0.5&deg; x 0.5&deg;, annual</span><br />
|<span style="color:red">2005, 2010-2100 in 10 year increments</span><br />
|<span style="color:red">NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, BC, OC, NH3</span><br />
|http://tntcat.iiasa.ac.at:8787/RcpDb/dsd?Action=htmlpage&page=welcome<br />
|-<br />
|<span style="color:red">Global</span><br />
|<span style="color:red">HTAP</span><br />
|<span style="color:red">HTAP v2 inventory</span><br />
|<span style="color:red">0.1&deg; x 0.1&deg;, annual</span><br />
|<span style="color:red">2008, 2010</span><br />
|<span style="color:red">NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, BC, OC, NH<sub>3</sub></span><br />
|http://edgar.jrc.ec.europa.eu/htap_v2/index.php?SECURE=123<br />
|-<br />
|Asia<br />
|MIX<br />
|MIX v1.1 emission inventory for Asia<br />
|0.25&deg; x 0.25&deg;, monthly<br />
|2008, 2010<br />
|NO<sub>x</sub>, SO<sub>2</sub>, CO, BC, OC, NMVOCs, NH<sub>3</sub><br />
|Li et al. (2017)<br />
|-<br />
|<span style="color:red">Asia</span><br />
|<span style="color:red">STREETS</span><br />
|<span style="color:red">Streets regional inventory for China and SE Asia</span><br />
|<span style="color:red">1&deg; x 1&deg;, monthly</span><br />
|<span style="color:red">2000, 2006</span><br />
|<span style="color:red">NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, BC, OC, NH<sub>3</sub></span><br />
|<span style="color:red">Zhang et al. (2009). NH<sub>3</sub> only available for 2000.</span><br />
|-<br />
|<span style="color:green">China</span><br />
|<span style="color:green">MEIC</span><br />
|<span style="color:green">MEIC inventory for China</span><br />
|<span style="color:green">0.25&deg; x 0.25&deg;, monthly</span><br />
|<span style="color:green">2008, 2010</span><br />
|<span style="color:green">NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, NH<sub>3</sub></span><br />
|<span style="color:green">http://www.meicmodel.org/</span>. <br />
|-<br />
|<span style="color:green">Africa</span><br />
|<span style="color:green">DICE-Africa</span><br />
|<span style="color:green">Non-industrial anthropogenic emissions for Africa</span><br />
|<span style="color:green">0.1&deg; x 0.1&deg;, annual</span><br />
|<span style="color:green">2006, 2013</span><br />
|<span style="color:green">NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, NH<sub>3</sub>, BC, OC</span><br />
|<span style="color:green">Marais and Wiedinmyer (2016)</span><br />
|-<br />
|US<br />
|NEI2011<br />
|US EPA NEI-2011 emission inventory<br />
|0.1&deg; x 0.1&deg;, monthly & hourly<br />
|2011<br />
|NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, NH<sub>3</sub>, BC, OC<br />
|https://www.epa.gov/air-emissions-inventories/2011-national-emissions-inventory-nei-data<br />
|-<br />
|Canada<br />
|CAC<br />
|CAC inventory for Canada<br />
|0.1&deg; x 0.1&deg;, annual<br />
|2005<br />
|NO<sub>x</sub>, SO<sub>2</sub>, CO, NH<sub>3</sub><br />
|http://carexcanada.uvic.ca//emp/wp-content/uploads/2014/06/EC_Emission_Inventory_Guidebook.pdf<br />
|-<br />
|Mexico<br />
|BRAVO<br />
|BRAVO inventory for Mexico<br />
|1&deg; x 1&deg;, annual<br />
|1999<br />
|NO<sub>x</sub>, SO<sub>2</sub>, CO<br />
|Kuhns et al. (2003)<br />
|-<br />
|Europe<br />
|EMEP<br />
|EMEP inventory for Europe<br />
|1&deg; x 1&deg;, monthly<br />
|1980,1985-2000<br />
|NO<sub>x</sub>, SO<sub>2</sub>, CO<br />
|Auvray and Bey (2005) <br />
|-<br />
|-bgcolor="#CCFFFF" valign="top" align="left"<br />
!colspan="7"|Biomass Burning (Open Fires) Emission Inventories<br />
|-<br />
|Global<br />
|GFED4<br />
|GFED4 biomass burning inventory<br />
|0.25&deg; x 0.25&deg;, monthly, daily, every 3 hours<br />
|1997-2014<br />
|NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, NH<sub>3</sub>, BC, OC<br />
|http://www.globalfiredata.org, Giglio et al. (2013)<br />
|-<br />
|<span style="color:red">Global</span><br />
|<span style="color:red">QFED2</span><br />
|<span style="color:red">QFED2 biomass burning emissions</span><br />
|<span style="color:red">0.1&deg; x 0.1&deg;, daily</span><br />
|<span style="color:red">2000-2014</span><br />
|<span style="color:red">NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, NH<sub>3</sub>, BC, OC</span><br />
|<span style="color:red">Darmenov and da Silva (2015)</span><br />
|-<br />
|<span style="color:red">Global</span><br />
|<span style="color:red">FINN</span><br />
|<span style="color:red">FINN v1.5 biomass burning emissions</span><br />
|<span style="color:red">0.25&deg; x 0.25&deg;, monthly, daily</span><br />
|<span style="color:red">2002-2014</span><br />
|<span style="color:red">NO<sub>x</sub>, SO<sub>2</sub>, CO, NMVOCs, NH<sub>3</sub>, BC, OC</span><br />
|<span style="color:red">Wiedinmyer et al. (2016)</span><br />
|-<br />
|<span style="color:red">Global</span><br />
|<span style="color:red">BOND</span><br />
|<span style="color:red">BOND biomass burning BC + OC emissions</span><br />
|<span style="color:red">1&deg; x 1&deg;, monthly</span><br />
|<span style="color:red">2000</span><br />
|<span style="color:red">BC, OC</span><br />
|<span style="color:red">Bond et al. (2007)</span><br />
|-<br />
|-bgcolor="#CCFFFF" valign="top" align="left"<br />
!colspan="7"|Terrestrial Biogenic Emission Inventories (online calculation)<br />
|-<br />
|Global<br />
|MEGAN<br />
|MEGAN v2.1 biogenic emissions<br />
|Horizontal and temporal resolution of the model<br />
|Year of model<br />
|ISOP, monoterpenes, sesquiterpenes, MOH, ACET, ETOH, CH<sub>2</sub>O, ALD2, HCOOH, C<sub>2</sub>H<sub>4</sub>, TOLU, PRPE <br />
|Guenther et al. (2012)<br />
|-<br />
|Global<br />
|SeaFlux<br />
|Air-sea exchange fluxes<br />
|Horizontal and temporal resolution of the model<br />
|Year of model<br />
|DMS, ACET<br />
|Lana et al. (2011)<br />
|-<br />
|Global<br />
|SeaFlux<br />
|Air-sea exchange fluxes<br />
|Horizontal and emission resolution of the model<br />
|Year of model<br />
|SALA, SALC<br />
|Jaegl&eacute; et al. (2011)<br />
|-<br />
|-bgcolor="#CCFFFF" valign="top" align="left"<br />
!colspan="7"|Other Natural/Semi-Natural Emission Inventories (online calculation)<br />
|-<br />
|Global<br />
|SoilNOx<br />
|Emission of NO<sub>x</sub> from soils and fertiliser use<br />
|Horizontal and temporal resolution of the model<br />
|Year of model<br />
|NO<br />
|Hudman et al. (2012)<br />
|-<br />
|Global<br />
|LightNOx<br />
|NO<sub>x</sub> from lightning<br />
|Horizontal and temporal resolution of the model<br />
|Year of model<br />
|NO<br />
|Murray et al. (2012)<br />
|-<br />
|Global<br />
|VOLCANO<br />
|Volcanic SO<sub>2</sub> emissions<br />
|1&deg; x 1&deg;, monthly<br />
|1979-2009<br />
|SO<sub>2</sub><br />
|Fisher et al. (2011)<br />
|-<br />
|Global<br />
|LIANG_BROMOCARB<br />
|Very short-lived bromocarbon emissions<br />
|2&deg; x 2.5&deg;, annual<br />
|2000<br />
|CHBr<sub>3</sub>, CH<sub>2</sub>Br<sub>2</sub><br />
|Liang et al. (2010)<br />
|-<br />
|Global<br />
|DustDead<br />
|DEAD Dust emissions scheme<br />
|2&deg; x 2.5&deg;, 4&deg; x 5&deg;, model time resolution<br />
|Year of model<br />
|DST1-4<br />
|Zender et al. (2003)<br />
|-<br />
|<span style="color:red">Global</span><br />
|<span style="color:red">DustGinoux</span><br />
|<span style="color:red">Ginoux dust emissions scheme</span><br />
|<span style="color:red">4&deg; x 5&deg;, model time resolution</span><br />
|<span style="color:red">Year of model</span><br />
|<span style="color:red">DST1-4</span><br />
|<span style="color:red">Ginoux et al. (2001)</span><br />
|-<br />
|<span style="color:green">Global</span><br />
|<span style="color:green">MASAGE</span><br />
|<span style="color:green">MASAGE non-agricultural NH<sub>3</sub> emissions</span><br />
|<span style="color:green">0.5&deg; x 0.5&deg;, monthly?</span><br />
|<span style="color:green">2005-2008</span><br />
|<span style="color:green">NH<sub>3</sub></span><br />
|<span style="color:green">Paulot et al. (2013)</span><br />
|-<br />
|<span style="color:green">Arctic</span><br />
|<span style="color:green">none yet</span><br />
|<span style="color:green">Arctic seabird emissions of NH<sub>3</sub></span><br />
|<span style="color:green">0.1&deg; x 0.1&deg;, monthly?</span><br />
|<span style="color:green">2011</span><br />
|<span style="color:green">NH<sub>3</sub></span><br />
|<span style="color:green">Croft et al. (2016)</span><br />
|-<br />
|}<br />
<br />
--[[User:Emarais|Emarais]] ([[User talk:Emarais|talk]]) 22:36, 7 September 2017 (UTC)<br />
<br />
=== References ===<br />
<br />
*Auvray and Bey, Long-range transport to Europe: Seasonal variations and implications for the European ozone budget, J. Geophys. Res., doi:10.1029/2004JD005503, 2005. <br />
*Bond et al., Historical emissions of black and organic carbon aerosol from energy-related combustion, 1850–2000, Global Biogeochem. Cy., doi:10.1029/2006GB002840, 2007.<br />
*Croft et al., Contribution of Arctic seabird-colony ammonia to atmospheric particles and cloud-albedo radiative effect, Nature Communications, doi:10.1038/ncomms13444, 2016.<br />
*Darmenov and da Silva, The Quick Fire Emissions Dataset (QFED): Documentation of versions 2.1, 2.2 and 2.4, R. D. Koster (Ed.), Vol. 38, USA, 2015.<br />
*Fisher et al., Sources, distribution, and acidity of sulfate–ammonium aerosol in the Arctic in winter–spring, Atmos. Environ., doi:10.1016/j.atmosenv.2011.08.030, 2011.<br />
*Giglio et al., Analysis of daily, monthly, and annual burned area using the fourth-generation global fire emissions database (GFED4), J. Geophys. Res., doi:10.1002/jgrg.20042, 2013.<br />
*Ginoux et al., Sources and distributions of dust aerosols simulated with the GOCART model, J. Geophys. Res., doi:10.1029/2000JD000053, 2001.<br />
*Guenther et al., The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions, Geosci. Model Dev., doi:10.5194/gmd-5-1471-2012, 2012.<br />
*Holmes et al., The climate impact of ship NO<sub>x</sub> emissions: an improved estimate accounting for plume chemistry, Atmos. Chem. Phys., doi:10.5194/acp-14-6801-2014, 2014.<br />
*Hudman et al., Steps towards a mechanistic model of global soil nitric oxide emissions: implementation and space based-constraints, Atmos. Chem. Phys., doi:10.5194/acp-12-7779-2012, 2012.<br />
*Jaegl&eacute; et al., Global distribution of sea salt aerosols: new constraints from in situ and remote sensing observations, Atmos. Chem. Phys., doi:10.5194/acp-11-3137-2011, 2011.<br />
*Kuhns et al., Big Bend Regional Aerosol and Visibility Observational (BRAVO) Study Emissions Inventory, DRI, Las Vegas, NV, 2003.<br />
*Lana et al., An updated climatology of surface dimethlysulfide concentrations and emission fluxes in the global ocean, Global Biogeochem. Cy., doi:10.1029/2010GB003850, 2011.<br />
*Li et al., MIX: a mosaic Asian anthropogenic emission inventory under the international collaboration framework of the MICS-Asia and HTAP, Atmos. Chem. Phys., doi:10.5194/acp-17-935-2017, 2017.<br />
*Liang et al., Finding the missing stratospheric Br<sub>y</sub>: a global modeling study of CHBr<sub>3</sub> and CH<sub>2</sub>Br<sub>2</sub>, Atmos. Chem. Phys., doi:10.5194/acp-10-2269-2010, 2010.<br />
*Marais and Wiedinmyer, Air Quality Impact of Diffuse and Inefficient Combustion Emissions in Africa (DICE-Africa), Environ. Sci. Technol., doi:10.1021/acs.est.6b02602, 2016.<br />
*Murray et al., Optimized regional and interannual variability of lightning in a global chemical transport model constrained by LIS/OTD satellite data, J. Geophys. Res., doi:10.1029/2012JD017934, 2012.<br />
*Paulot et al., Ammonia emissions in the United States, European Union, and China derived by high-resolution inversion of ammonium wet deposition data: Interpretation with a new agricultural emissions inventory (MASAGE_NH3), J. Geophys. Res., doi:10.1002/2013JD021130, 2014.<br />
*Stettler et al., Air quality and public health impacts of UK airports. Part I: Emissions, Atmos. Environ., doi:10.1016/j.atmosenv.2011.07.012, 2011.<br />
*Tzompa-Sosa et al., in prep, 2017.<br />
*Vinken et al., Accounting for non-linear chemistry of ship plumes in the GEOS-Chem global chemistry transport model, Atmos. Chem. Phys., doi:10.5194/acp-11-11707-2011, 2011.<br />
*Wang et al., Improving Spatial Representation of Global Ship Emissions Inventories, doi:10.1021/es0700799, 2008.<br />
*Wiedinmyer et al., The Fire INventory from NCAR (FINN): a high resolution global model to estimate the emissions from open burning, Geosci. Model Dev., doi:10.5194/gmd-4-625-2011, 2011.<br />
*Wiedinmyer et al., Global Emissions of Trace Gases, Particulate Matter, and Hazardous Air Pollutants from Open Burning of Domestic Waste, Environ. Sci. Technol., doi:10.1021/es502250z, 2014.<br />
*Xiao et al., Global budget of ethane and regional constraints on U.S. sources, J. Geophys. Res., doi:10.1029/2007JD009415, 2008.<br />
*Zhang et al., Asian emissions in 2006 for the NASA INTEX-B mission, Atmos. Chem. Phys., doi:10.5194/acp-9-5131-2009, 2009.<br />
<br />
== Discussions ==<br />
<br />
#[[Scale factors for anthropogenic emissions]]<br />
#[[Carbon_Gases_and_Organics_Working_Group#GEIA_anthropogenic_scaling_factors | GEIA Anthropogenic Scaling Factors]]<br />
#[[MEGAN_v2.1_biogenic_emissions|Biogenic Parameter Input Sources]]<br />
#[[Historical and Future Emissions|Historical and Future Emissions wiki page]]</div>
Zitely
https://wiki.seas.harvard.edu/geos-chem/index.php?title=Updating_standard_chemistry_with_JPL_10-6&diff=26183
Updating standard chemistry with JPL 10-6
2016-03-09T18:21:38Z
<p>Zitely: /* Reactions */ Added a reference for the rate constant of reaction 178.</p>
<hr />
<div>This page is intended to incorporate the latest version of [http://jpldataeval.jpl.nasa.gov/pdf/JPL%2010-6%20Final%2015June2011.pdf JPL chemical kinetics] (June 15, 2011) into GC standard chemistry. <br />
<br />
<span style="color:green">'''''This update was included in [[GEOS-Chem v9-02 benchmark history#v9-02f|GEOS-Chem v9-02f]] (accepted 07 Feb 2013).'''''</span><br />
<br />
==Standard Chemistry==<br />
===For Consideration===<br />
<br />
<span style="color:green">'''''This update was tested in the 1-month benchmark simulation [[GEOS-Chem_v9-02_benchmark_history#v9-02f|v9-02f]] and approved on 07 Feb 2013.'''''</span><br />
<br />
Below is a list of reactions that are being updated based on the JPL 10-6 document. Note that the temperature sensitivity value, E/R, is entered following JPL format, so the sign is opposite of the GEOS-Chem format. The updates will be tested in the benchmark before they are recommended by the working group.<br />
<br />
{| border="1" cellspacing="0" cellpadding="5"<br />
|-bgcolor="#cccccc"<br />
!width="250pt"|'''Reaction'''<br />
!width="210pt"|'''A'''<br />
!width="100pt"|'''E/R'''<br />
!'''Description'''<br />
|-<br />
| HO2 + HO2 -> H2O2 + O2 || 3.0e–13 || -460 || Updated rate<br />
|-<br />
| HO2 + HO2 + M -> H2O2 + O2 || 2.1e-33 || -920 || Updated rate<br />
|-<br />
| HO2 + HO2-H2O -> products || 5.4e–11 || 410 || Not directly used; this is a reaction that explains the water enhancement used in calcrate.f<br />
|-<br />
| HO2 + NO -> NO2 + OH || 3.3e-12 || -270 || Update rate<br />
|-<br />
| ISOP + NO3 -> products || 3.3e-12 || 450 || Updated rate, assuming products do not change<br />
|-<br />
| ISOP + OH -> products || 3.1e-11 || -350 || Updated rate, assuming products do not change<br />
|-<br />
| ISOP + O3 -> products || 1e-14 || 1970 || Updated rate, assuming products do not change<br />
|-<br />
| ALD2 + OH -> products || 4.63e-12 || -350 || Updated rate, assuming products do not change<br />
|-<br />
| C2H6 + OH -> products || 7.66e-12 || 1020 || Updated rate, assuming products do not change<br />
|-<br />
| DMS + OH -> products || 1.2e-11 || 280 || Updated rate, assuming products do not change<br />
|-<br />
| DMS + OH + O2 -> products || 8.20E-39 and 1.05E-05 || -5376 and -3644 || Updated rate, assuming products do not change (E/R values in comment are plus, but to be consistent with JPL tables, I entered them here as negative. This reaction also had an update to the parametrization. Was: 1 + A * [O2] exp(-(E/R)T); Now: 1 + A * [O2]/[M] * exp(-(E/R)/T) where [O2]/[M] = 0.2095.<br />
|-<br />
| DMS + NO3 -> products || 1.9e-13 || -530 || Updated rate, assuming products do not change<br />
|-<br />
| O3 + hv -> OH + HO2 || j<sub>O3</sub> * 1.2e-10 / k<sup>1</sup><sub>O1D</sub> || 0 || This reaction was added to account for the reaction of O1D with H2, which was previously not explicitly included. k<sup>1</sup><sub>O1D</sub> is the pseudo-first order rate of O1D reaction with H2, H2O, O2, and N2. Because H2 was previously left out of k<sup>1</sup><sub>O1D</sub>, ozone photolysis was producing extra OH and the radical budget was mostly conserved.<br />
|-<br />
| O3 + hv -> OH + OH || j<sub>O3</sub> * 1.63e-10 * exp(60/T) / k<sup>1</sup><sub>O1D</sub> || 0 || The addition of H2 to k<sup>1</sup><sub>O1D</sub> reduces this reaction rate.<br />
|-<br />
| O1D -> products || k<sup>1</sup><sub>O1D</sub> || 0 || This reaction is included in stead-state photolysis of O3, and is not added to the mechanism. This entry has been added to the table as a place to describe k<sup>1</sup><sub>O1D</sub> = 1.2e-10 * [H2] + 1.63e-10 * exp(60/T) * [H2O] + 2.15e-11 * exp(110/T) * [N2] + 3.30e-11 * exp(55/T) * [O2]<br />
|-<br />
| EOH + OH -> products || 3.35e-12 || n/a || Updated rate, assuming products do not change<br />
|-<br />
| ACTA + OH -> products || 3.15e-14 || 920 || Updated rate, assuming products do not change<br />
|-<br />
|}<br />
<br />
<br />
'''--Barron Henderson 2011/07/12''' <br />
<br />
<br />
'''Mat Evans comments:''' <br />
:Great work Jingqiu. We should updating all of these for a GC update. We should also think about changing the safety value (if any of the input parameters <= 0) in the ARSL1K routine to be 1e-30 rather than 1e-3<br />
<br />
:O1D+H2: Yep we should put this into the O1D steady state. This should be easy<br />
<br />
:Didn't the DMS + NO3 and the DMS + OH reaction rates change? The DMS scheme in the model is fairly old. We might want to see if anybody is looking at this....<br />
<br />
:I'll contact Stan Sander and ask why the NO2+OH rate constant wasn't updated to the science paper version?<br />
<br />
==Evaluation==<br />
{| border="1" cellspacing="0" cellpadding="5"<br />
|-bgcolor="#cccccc"<br />
!width="100pt" |'''Reaction'''<br />
!width="200pt" |'''old'''<br />
!width="400pt" |'''new'''<br />
!width="200pt" |'''compare'''<br />
|-<br />
| HO2+HO2 || K1=3.50E-13 exp(430/T); K2=1.70E-33 [M]exp(1000/T); K = (K1 + K2)*(1+1.4E-21*[H2O]*EXP(2200/T) || K1=3.00E-13 exp(460/T); K2=2.10E-33 [M]exp(920/T); K = (K1 + K2)*(1+1.4E-21*[H2O]*EXP(2200/T))||[[Image:HO2_HO2.png|thumb|center|100px|]]water enhancement factor is not shown here as it doesn't change from JPL06 to JPL11<br />
|-<br />
| HO2+NO ||3.50E-12 exp(250/T)||3.3e-12 exp(270/T)||[[Image:HO2_NO.png|thumb|center|100px]]<br />
|-<br />
| ISOP+OH ||2.7E-11exp(390/T)||3.1E-11exp(350/T)||[[Image:ISOP_OH.png|thumb|center|100px]]<br />
|-<br />
| ISOP+NO3 ||3.15E-12 exp(-450/T) ||3.3E-12exp(-450/T)||[[Image:ISOP_NO3.png|thumb|center|100px]]<br />
|-<br />
| ISOP+O3 ||1.05E-14 exp(-2000/T) ||1.0E-14exp(-1970/T)||[[Image:ISOP_O3.png|thumb|center|100px]]<br />
|-<br />
| ALD2+OH ||4.4 E-12exp(365/T) ||4.63E-12exp(350/T)||[[Image:ALD2_OH.png|thumb|center|100px]]<br />
|-<br />
| C2H6+OH ||8.7E-12 exp(-1070/T) ||7.66E-12exp(-1020/T)||[[Image:C2H6_OH.png|thumb|center|100px]]<br />
|-<br />
| EOH+OH ||6.90E-12exp(-230/T) ||3.35e-12||[[Image:EOH_OH.png|thumb|center|100px]]<br />
|-<br />
| ACTA+OH ||4.20E-14exp(855/T) ||3.15e-14exp(920/T)||[[Image:ACTA_OH.png|thumb|center|100px]]<br />
|-<br />
| O1D+H2 || N/A || ([O1D]*[H2]+[O1D]*[H2O]) / ([O1D]*[H2]+[O1D]*[H2O]+[O1D][N2]+[O1D][O2])||[[Image:O1D_H2.png|thumb|center|100px]]Here I assume 0.1% RH and 500ppb H2.<br />
|-<br />
| DMS+OH ||1.1E-11exp(-240/T) ||1.2E-11exp(-280/T)||[[Image:DMS_OH.png|thumb|center|100px]]<br />
|-<br />
| DMS+OH+O2 ||K1=1.0E-39exp(5820/T); K2=5.0E-30exp(6280/T); K=K1*[O2]/(1.0+K2*[O2])||K1=8.2E-39exp(5376/T); K2=1.05E-5exp(3644/T); K=K1*[O2]/(1.0+K2*0.2095)||[[Image:DMS_OH_O2.png|thumb|center|100px]]<br />
|-<br />
| DMS+NO3||1.90E-13 exp(500/T) ||1.90E-13 exp(530/T)||[[Image:DMS_NO3.png|thumb|center|100px]]<br />
|}<br />
Notes:<br />
1. '''DMS+OH+O2 is quite different in JPL11.'''<br />
<br />
2. '''The changes in HO2+HO2 and HO2+NO might be responsible for the increase of ozone.'''<br />
<br />
--[[User:Jmao|Jmao]] 17:40, 14 July 2011 (EDT)<br />
<br />
==current standard chemistry==<br />
===Species===<br />
{| border="1" cellspacing="0" cellpadding="5"<br />
|-bgcolor="#cccccc"<br />
! width="100pt" |'''Species'''<br />
! width="200pt" |'''Formula'''<br />
! width="400pt" |'''Note'''<br />
|-<br />
|A3O2 ||CH3CH2CH2OO ||primary RO2 from C3H8<br />
|-<br />
|ACET ||CH3C(O)CH3 ||acetone<br />
|-<br />
|ACTA ||CH3C(O)OH ||acetic acid<br />
|-<br />
|ALD2 ||CH3CHO ||acetaldehyde<br />
|-<br />
|ALK4 ||RH ||≥C4 alkanes<br />
|-<br />
|ATO2 ||CH3C(O)CH2O2 ||RO2 from acetone<br />
|-<br />
|B3O2 ||CH3CH(OO)CH3 ||secondary RO2 from C3H8<br />
|-<br />
|C2H6 ||C2H6 ||ethane<br />
|-<br />
|C3H8 ||C3H8 ||propane<br />
|-<br />
|CH2O ||CH2O ||formaldehyde<br />
|-<br />
|CH4 ||CH4 ||methane<br />
|-<br />
|CO ||CO ||carbon monoxide<br />
|-<br />
|CO2 ||CO2 ||carbon dioxide<br />
|-<br />
|DRYDEP || ||generic entry for dry dep<br />
|-<br />
|EMISSION|| ||generic entry to do emissions<br />
|-<br />
|EOH ||C2H5OH ||ethanol<br />
|-<br />
|ETO2 ||CH3CH2OO ||ethylperoxy radical<br />
|-<br />
|ETP ||CH3CH2OOH ||ethylhydroperoxide<br />
|-<br />
|GLYC ||HOCH2CHO ||glycoaldehyde (hydroxyacetaldehyde)<br />
|-<br />
|GLYX ||CHOCHO ||glyoxal<br />
|-<br />
|H2 ||H2 ||hydrogen atom<br />
|-<br />
|H2O ||H2O ||water vapor<br />
|-<br />
|H2O2 ||H2O2 ||hydrogen peroxide<br />
|-<br />
|HAC ||HOCH2C(O)CH3 ||hydroxyacetone<br />
|-<br />
|HCOOH ||HCOOH ||formic acid<br />
|-<br />
|HNO2 ||HONO ||nitrous acid<br />
|-<br />
|HNO3 ||HNO3 ||nitric acid<br />
|-<br />
|HNO4 ||HNO4 ||pernitric acid<br />
|-<br />
|HO2 ||HO2 ||hydroperoxyl radical<br />
|-<br />
|IALD ||HOCH2C(CH3)=CHCHO ||hydroxy carbonyl alkenes from isoprene<br />
|-<br />
|IAP ||HOCH2C(CH3)(OOH)CH(OH)CHO ||peroxide from IAO2<br />
|-<br />
|INO2 ||O2NOCH2C(OO)(CH3)CH=CH2 ||RO2 from ISOP+NO3<br />
|-<br />
|INPN ||O2NOCH2C(OOH)(CH3)CH=CH2 ||peroxide from INO2<br />
|-<br />
|ISN2 ||CH2=C(CH3)CH(ONO2)CH2OH ||isoprene nitrtate<br />
|-<br />
|ISNO3 ||RONO2 ||stable organic nitrate<br />
|-<br />
|ISNP ||HOCH2C(OOH)(CH3)CH(ONO2)CH2OH ||peroxide from ISOPNBO2 and ISOPNDO2<br />
|-<br />
|ISOP ||CH2=C(CH3)CH=CH2 ||isoprene<br />
|-<br />
|KO2 ||RO2 from >3 ketones ||RO2 from >3 ketones<br />
|-<br />
|M || ||for three body reactions<br />
|-<br />
|MACR ||CH2=C(CH3)CHO ||methacrolein<br />
|-<br />
|MAN2 ||HOCH2C(ONO2)(CH3)CHO ||RO2 from MACR+NO3<br />
|-<br />
|MAO3 ||CH2=C(CH3)C(O)OO ||peroxyacyl from MVK and MACR<br />
|-<br />
|MAOP ||CH2=C(CH3)C(O)OOH ||peroxide from MAO3<br />
|-<br />
|MAP ||CH3C(O)OOH ||peroxyacetic acid<br />
|-<br />
|MCO3 ||CH3C(O)OO ||peroxyacetyl radical<br />
|-<br />
|MEK ||RC(O)R ||>3 ketones<br />
|-<br />
|MGLY ||CH3COCHO ||methylglyoxyal<br />
|-<br />
|MNO3 ||CH3ONO2 ||methylnitrate<br />
|-<br />
|MO2 ||CH3O2 ||methylperoxy radical<br />
|-<br />
|MOH ||CH3OH ||methanol<br />
|-<br />
|MP ||CH3OOH ||methylhydroperoxide<br />
|-<br />
|MRO2 ||HOCH2C(OO)(CH3)CHO ||RO2 from MACR+OH<br />
|-<br />
|MRP ||HOCH2C(OOH)(CH3)CHO ||peroxide from MRO2<br />
|-<br />
|MVK ||CH2=CHC(O)CH3 ||methylvinylketone<br />
|-<br />
|N2 ||N2 ||nitrogen<br />
|-<br />
|N2O ||N2O ||nitrous oxide<br />
|-<br />
|N2O5 ||N2O5 ||dinitrogen pentoxide<br />
|-<br />
|NH2 ||NH2 ||ammonia radical<br />
|-<br />
|NH3 ||NH3 ||ammonia<br />
|-<br />
|NO ||NO ||nitric oxide<br />
|-<br />
|NO2 ||NO2 ||nitrogen dioxide<br />
|-<br />
|NO3 ||NO3 ||nitrate radical<br />
|-<br />
|O ||O ||oxygen atom (3P)<br />
|-<br />
|O1D ||O1D ||oxygen atom (1D)<br />
|-<br />
|O2 ||O2 ||molecular oxygen<br />
|-<br />
|O2CH2OH||O2CH2OH ||produced by CH2O+HO2<br />
|-<br />
|O3 ||O3 ||ozone<br />
|-<br />
|OH ||OH ||hydroxyl radical<br />
|-<br />
|PAN ||CH3C(O)OONO2 ||peroxyacetylnitrate<br />
|-<br />
|PMN ||CH2=C(CH3)C(O)OONO2 ||peroxymethacryloyl nitrate (MPAN)<br />
|-<br />
|PO2 ||HOCH2CH(OO)CH3 ||RO2 from isoprene<br />
|-<br />
|PP ||HOCH2CH(OOH)CH3 ||peroxide from PO2<br />
|-<br />
|PPN ||CH3CH2C(O)OONO2 ||peroxypropionylnitrate<br />
|-<br />
|PRN1 ||O2NOCH2CH(OO)CH3 ||RO2 from propene + NO3<br />
|-<br />
|PRPE ||C3H6 ||≥C3 alkenes<br />
|-<br />
|PRPN ||O2NOCH2CH(OOH)CH3 ||peroxide from PRN1<br />
|-<br />
|R4N1 ||RO2 from R4N2 ||RO2 from R4N2<br />
|-<br />
|R4N2 ||RO2NO ||≥C4 alkylnitrates<br />
|-<br />
|R4O2 ||RO2 from ALK4 ||RO2 from ALK4<br />
|-<br />
|R4P ||CH3CH2CH2CH2OOH ||peroxide from R4O2<br />
|-<br />
|RA3P ||CH3CH2CH2OOH ||peroxide from A3O2<br />
|-<br />
|RB3P ||CH3CH(OOH)CH3 ||peroxide from B3O2<br />
|-<br />
|RCHO ||CH3CH2CHO ||>C2 aldehydes<br />
|-<br />
|RCO3 ||CH3CH2C(O)OO ||peroxypropionyl radical<br />
|-<br />
|RCOOH ||C2H5C(O)OH ||>C2 organic acids<br />
|-<br />
|RIO1 ||HOCH2C(OO)(CH3)CH=CHOH ||RO2 from isoprene oxidation products<br />
|-<br />
|RIO2 ||HOCH2C(OO)(CH3)CH=CH2 ||RO2 from isoprene<br />
|-<br />
|RIP ||HOCH2C(OOH)(CH3)CH=CH2 ||peroxide from RIO2<br />
|-<br />
|ROH ||C3H7OH ||>C2 alcohols<br />
|-<br />
|RP ||CH3CH2C(O)OOH ||peroxide from RCO3<br />
|-<br />
|VRO2 ||HOCH2CH(OO)C(O)CH3 ||RO2 from MVK+OH<br />
|-<br />
|VRP ||HOCH2CH(OOH)C(O)CH3 ||peroxide from VRO2<br />
|-<br />
|DMS ||(CH3)2S ||dimethylsulfide<br />
|-<br />
|SO2 ||SO2 ||sulfur dioxide<br />
|-<br />
|SO4 ||SO4 ||sulfate radical<br />
|-<br />
|MSA ||CH4SO3 ||methanesulfonic acid<br />
|}<br />
<br />
===Reactions===<br />
{| border="1" cellspacing="0" cellpadding="5"<br />
|-bgcolor="#cccccc"<br />
! width="100pt" |'''No'''<br />
! width="400pt" |'''Reaction'''<br />
! width="400pt" |'''Rate Constant'''<br />
! width="400pt" |'''Reference'''<br />
! width="400pt" |'''Note'''<br />
|-<br />
|1 ||NO + O3 = NO2 + O2 ||3.00E-12 exp(-1500/T) ||JPL06 ||<br />
|-<br />
|2 ||O3+OH = HO2+O2 ||1.70E-12 exp(-940/T)||JPL06 ||<br />
|-<br />
|3 ||O3+HO2 = OH+2O2 ||1.00E-14 exp(-490/T)||JPL06 ||<br />
|-<br />
|4 ||O3+NO2 = O2+NO3 ||1.20E-13 exp(-2450/T)||JPL06 ||<br />
|-<br />
|5 ||O3+MO2 = CH2O+HO2+2O2 ||2.90E-16 exp(-1000/T)||JPL06 ||<br />
|-<br />
|6 ||OH+OH = H2O+O3 ||1.8E-12 ||JPL06 ||JMAO<br />
|-<br />
|7 ||OH+OH+M = H2O2 ||LPL: 6.9E-31(300/T); HPL: 2.60E-11; Fc:0.6||JPL06 ||JMAO<br />
|-<br />
|8 ||OH+HO2 = H2O + O2 ||4.80E-11 exp (250/T)||JPL06 ||JMAO<br />
|-<br />
|9 ||OH+H2O2 = H2O + HO2 ||1.8E-12 ||JPL06 ||JMAO<br />
|-<br />
|10 ||HO2+NO = OH + NO2 ||3.50E-12 exp(250/T)||JPL06 ||<br />
|-<br />
|11 ||HO2+HO2 = H2O2 HO2+HO2+M=H2O2 ||K1=3.50E-13 exp(430/T); K2=1.70E-33 [M]exp(1000/T); K = (K1 + K2)*(1+1.4E-21*[H2O]*EXP(2200/T)||JPL06 ||JMAO<br />
|-<br />
|12 ||OH+H2 = H2O + HO2||2.80E-12 exp(-1800/T) ||JPL06 ||JMAO<br />
|-<br />
|13 ||CO+OH = HOCO ||LPL: 5.9E-33(300/T)^1.4; HPL:1.1E-12(300/T)^-1.3; Fc:0.6 ||JPL06 ||JMAO(in calcrate.f) Ignore the intermediate species HOCO and use two 3-body reactions<br />
|-<br />
| ||HOCO + O2= HO2 + CO2||2.00E-12||JPL06 ||<br />
|-<br />
| ||CO+OH=HO2+CO2 (different formula)||LPL: 1.5E-13(300/T)^-0.6; HPL:2.10E9(300/T)^-6.1; Fc:0.6||JPL06 ||<br />
|-<br />
|14 ||OH+ CH4 = MO2+H2O||2.45E-12exp(–1775/T) ||JPL06 ||JMAO:could also be 2.8E-14T^0.667 exp(–1575/T)<br />
|-<br />
|15 ||MO2+NO =CH2O+HO2+NO2 ||2.80E-12 exp(300/T) ||JPL06 ||<br />
|-<br />
|16 ||MO2+HO2 = MP+O2||4.1E-13 exp(750/T) ||JPL06 ||JMAO<br />
|-<br />
|17 ||MO2+HO2 = CH2O + O2||N/A||JPL06(P1-59,D35) ||JMAO:Not recommended in JPL06 <br />
|-<br />
|18 ||MO2+MO2 =MOH+CH2O+O2||K1=9.5E-14 exp(390/T); K2=2.62E+1 exp(-1130/T); K=K1 / (1+K2)||Tyndall 2001||<br />
|-<br />
|19 ||MO2+MO2 = 2CH2O + 2HO2||K1=9.5E-14 exp(390/T); K2=4.00E-02exp(1130/T); K=K1 / (1+K2)||Tyndall 2001||<br />
|-<br />
|20 ||MP+OH = MO2+H2O ||2.66E-12 exp(200/T)||JPL06 ||<br />
|-<br />
|21 ||MP+OH = CH2O+OH+H2O ||1.14E-12 exp(200/T)||JPL06 ||<br />
|-<br />
|22 ||CH2O+OH = HCO +H2O ||5.5E-12 exp(125/T) ||JPL06 ||JMAO(use the first rate)<br />
|-<br />
| ||HCO + O2 = CO + HO2 ||5.2E-12 ||JPL06||<br />
|-<br />
|23 ||OH + NO2 + M = HONO2 ||LPL: 1.80E-30(300/T)^3; HPL:2.80E-11(300/T)^0; Fc:0.6||JPL06 ||JMAO: Ignore the HOONO channel for now.<br />
|-<br />
| ||OH + NO2 + M=HOONO ||LPL:9.10E-32(300/T)^3.9 ; HPL:4.20E-11(300/T)^0.5; Fc:0.6||JPL06 ||<br />
|-<br />
|24 ||HNO3+OH = H2O+NO3 ||K0=2.41E-14 exp(460/T); K2=2.69E-17exp(2199/T); K3=6.51E-34exp(1335/T); K = K0 + K3[M] / (1 + K3[M]/K2)||JPL06 ||<br />
|-<br />
|25 ||NO+OH+M = HNO2+M ||LPL: 7.00E-31(300/T)^2.6; HPL: 3.60E-11(300/T)^0.1; Fc: 0.6||JPL06 ||<br />
|-<br />
|26 ||HNO2+OH = H2O+NO2 ||1.80E-11 exp(-390/T)||JPL06 ||<br />
|-<br />
|27 ||HO2+NO2+M = HNO4+M ||LPL: 2.0E-31(300/T)^3.4; HPL:2.9E-12(300/T)^1.1; Fc= 0.6||JPL06 ||JMAO<br />
|-<br />
|28 ||HNO4+M = HO2+NO2 ||LPL: 9.52E-5(300/T)^3.4* exp(-10900/T); HPL:1.38E+15*(300/T)^1.1*exp(-10900/T); Fc=0.6 ||JPL06||JMAO:K=forward rxn/Keq; Keq=2.1E-27exp(10900/T); <br />
|-<br />
|29 ||HNO4+OH = H2O+NO2+O2 ||1.30E-12 exp(380/T)||JPL06 ||<br />
|-<br />
|30 ||NO+NO3=2NO2 ||1.50E-11 exp(170/T)||JPL06 ||<br />
|-<br />
|31 ||HO2+NO3 = OH+NO2+O2 ||3.50E-12||JPL06 ||<br />
|-<br />
|32 ||OH+NO3 = HO2+NO2 ||2.20E-11||JPL06 ||<br />
|-<br />
|33 ||NO2+NO3+M = N2O5+M ||LPL: 2.0E-30(300/T)^4.4; HPL:1.4E-12(300/T)^0.7; Fc=0.6||JPL06 ||<br />
|-<br />
|34 ||N2O5+M = NO2+NO3 ||LPL: 7.4E-4(300/T)^4.4* exp(-11000/T); HPL:5.18E+14*(300/T)^0.7*exp(-11000/T); Fc=0.6 ||JPL06 ||JMAO :K=forwardrxn/ Keq; Keq = 2.70E-27exp(11000/T); <br />
|-<br />
|35 ||HCOOH+OH =H2O+CO2+HO2 ||4.00E-13||JPL06 ||<br />
|-<br />
|36 ||MOH+OH = HO2+CH2O ||2.9E-12 exp(-345/T)||JPL06 ||<br />
|-<br />
|37 ||NO2+NO3 = NO+NO2+O2 ||4.50E-14 exp(-1260/T)||JPL06 ||<br />
|-<br />
|38 ||NO3+CH2O = HNO3+HO2+CO||5.80E-16||JPL06 ||<br />
|-<br />
|39 ||ALD2 + OH=H2O + 0.95 MCO3 + 0.05 CH2O + 0.05 CO + 0.05 HO2 ||4.4 E-12exp(365/T) ||IUPAC06 ||DBM (cannot find this reaction from JPL06)<br />
|-<br />
|40 ||ALD2+NO3 = HNO3+MCO3 ||1.40E-12 exp(-1900/T) ||JPL06 ||JMAO<br />
|-<br />
|41 ||MCO3+NO2+M = PAN ||LPL: 9.70E-29(300/T)^5.6; HPL:9.3E-12(300/T)^1.5; Fc: 0.6 ||JPL06 ||JMAO<br />
|-<br />
|42 ||PAN = MCO3+NO2 ||9.30E-29 exp(14000/T) ||IUPAC06 ||equilibrium with the one above<br />
|-<br />
|43 ||MCO3+NO = MO2+NO2+CO2 ||8.10E-12 exp(270/T) ||JPL06 ||<br />
|-<br />
|44 ||C2H6+OH = ETO2+H2O ||8.7E-12 exp(-1070/T)||JPL06 ||<br />
|-<br />
|45 ||ETO2+NO =ALD2+NO2+HO2 ||2.60E-12 exp(365/T) ||JPL06 ||JMAO<br />
|-<br />
|46 ||C3H8+OH = B3O2 ||K1=7.60e-12 exp(-585/T); K2=5.87*(300/T)^0.64exp(-816/T); K=K1 / (1+K2) ||IUPAC06||JMAO<br />
|-<br />
| ||C3H8+OH = A3O2 ||K1=7.60E-12 exp(-585/T); K2= 0.17*(300/T)^-0.64exp(816/T); K=K1 / (1+K2) ||IUPAC06||JMAO<br />
|-<br />
|47 ||A3O2+NO = NO2 + HO2 + RCHO ||2.90E-12 exp(350/T) ||IUPAC06 ||JMAO<br />
|-<br />
|48 ||PO2+NO = NO2+HO2+CH2O+ALD2 ||2.70E-12 exp(350/T) ||Tyndall 2001 JGR||<br />
|-<br />
|49 ||ALK4+OH = R4O2 ||9.10E-12 exp(-405/T)||IUPAC06||<br />
|-<br />
|50 ||R4O2+NO = NO2 +0.32ACET + 0.19MEK +0.18MO2 + 0.27HO2 +0.32ALD2 + 0.13RCHO +0.50A3O2 + 0.18B3O2 + 0.32ETO2 || K* (1-YN) where YN isreturned from fyrno3.f; K=2.7E-12 exp(350/T) (Xcarbn=4.50E00) ||Atkinson 97||A3O2 is 0.05 in the input file(Palmer)<br />
|-<br />
|51 ||R4O2+NO = R4N2 ||K* YN where YN is returned from fyrno3.f; K=2.7E-12 exp(350/T) (Xcarbn=4.50E00)|| Atkinson97||<br />
|-<br />
|52 ||ATO2+NO = 0.96NO2 + 0.960CH2O +0.960MCO3 + 0.04R4N2 ||2.80E-12 exp(300/T) ||Tyndall||<br />
|-<br />
|53 ||KO2+NO = 0.93NO2+ 0.93ALD2 +0.93MCO3 + 0.07R4N2 ||2.70E-12 exp(350/T) ||Tyndall ETO2+NO ||JMAO: there was a typo in last version, no yield of NO. (Bryan Duncan).<br />
|-<br />
|54 ||RIO2 + NO = 0.90NO2 + 0.90HO2 + 0.34IALD + 0.34MVK + 0.22MACR + 0.56CH2O ||2.7E-12 exp(350/T)||MCM3.1 ||DBM(MCM 3.1), this reaction was recently modified to turn off the other channel.<br />
|-<br />
|56 ||IAO2+NO = 0.92HO2 + 0.61CO + 0.17H2 + 0.33HAC + 0.24GLYC + 0.53MGLY + 0.92NO2 + 0.35CH2O + 0.08HNO3 ||2.7E-12 exp(350/T) ||Tyndall ETO2+NO||<br />
|-<br />
|57 ||ISN1+NO = 1.9NO2+0.95GLYC+0.95HAC +0.05HNO3+0.05NO2+0.05HO2||2.7E-12 exp(350/T) ||Tyndall ETO2+NO; Paulson&Seinfeld 1992 HO2 term(Palmer, JMAO)||<br />
|-<br />
|58 ||VRO2+NO = NO2+0.28HO2+0.28CH2O+0.72MCO3+0.72GLYC+0.28MGLY ||K* (1-YN) where YN is returned from fyrno3.f; K=2.7E-12 exp(350/T) (Xcarbn=4.00E00) ||Atkinson 97 ||<br />
|-<br />
|59 ||VRO2+NO = HNO3 ||K* YN where YN is returned from fyrno3.f ;K=2.7E-12 exp(350/T) (Xcarbn=4.00E00) ||Atkinson 97||<br />
|-<br />
|60 ||MRO2 + NO = NO2 + HAC + CH2O + HO2||K* (1-YN) where YN is returned from fyrno3.f K=2.7E-12 exp(350/T) (Xcarbn=4.00E00)||DBM(MCM 3.1)||<br />
|-<br />
|61 ||MRO2+NO = HNO3 ||K* YN where YN is returned from fyrno3.f; K=2.7E-12 exp(350/T) (Xcarbn=4.00E00) ||Atkinson 97||<br />
|-<br />
|62 ||MVN2+NO = 1.90NO2 +0.30HO2+0.30CH2O+0.60MCO3+0.60GLYC+0.30MGLY+0.10HNO3 ||2.7E-12 exp(350/T) || ||<br />
|-<br />
|63 ||MAN2+NO = 2NO2+CH2O+MGLY ||2.7E-12 exp(350/T) ||Tyndall ETO2+NO || ||<br />
|-<br />
|64 ||B3O2+NO = NO2+HO2+ACET ||2.7E-12 exp(350/T) || || ||<br />
|-<br />
|65 ||INO2+NO = 1.10NO2+0.80HO2+0.85HNO3+0.05NO2+0.10MACR+0.15CH2O+0.05MVK ||2.7E-12 exp(350/T) ||Tyndall ETO2+NO ||<br />
|-<br />
|66 ||PRN1+NO = 2NO2+CH2O+ALD2 ||2.7E-12 exp(350/T) ||Tyndall ETO2+NO ||<br />
|-<br />
|67 ||ALK4+NO3 = HNO3 + R4O2 ||2.8E-12 exp(-3280/T) ||IUPAC02 ||<br />
|-<br />
|68 ||R4N2+OH = R4N1+H2O ||1.6E-12 ||IUPAC06 ||JMAO: use the one from HO + 1-C4H9ONO2 → products<br />
|-<br />
|69 ||ACTA+OH = MO2+CO2++H2O ||4.20E-14 exp(855/T) ||IUPAC06 ||JMAO<br />
|-<br />
|70 ||OH+RCHO= RCO3+H2O ||6.0E-12exp(410/T) ||IUPAC06 ||JMAO: use the one from HO + CH3CH2CH2CHO → products<br />
|-<br />
|71 ||RCO3+NO2 = PPN ||LPL: 9.00E-28(300/T)^8.9; HPL:7.70E-12(300/T)^0.2; Fc: 0.6 ||JPL06 ||<br />
|-<br />
|72 ||PPN = RCO3+NO2 ||9e-29*exp(14000/T) ||JPL06 ||<br />
|-<br />
|73 ||MAO3+NO2 = PMN ||LPL: 9.00E-28(300/T)^8.9; HPL:7.70E-12(300/T)^0.2; Fc: 0.6 ||JPL06 ||<br />
|-<br />
|74 ||PMN = MAO3+NO2 ||9e-29*exp(14000/T) ||JPL06 ||same as PPN<br />
|-<br />
|75 ||GLCO3+NO2 = GLPAN ||LPL: 9.00E-28(300/T)^8.9; HPL:7.70E-12(300/T)^0.2; Fc: 0.6||JPL06 ||same as PPN<br />
|-<br />
|76 ||GLPAN = GLCO3+NO2 ||9e-29*exp(14000/T) ||JPL02 PPN||<br />
|-<br />
|77 ||GCO3+NO2 = GPAN ||LPL: 9.00E-28(300/T)^8.9; HPL:7.70E-12(300/T)^0.2; Fc: 0.6 ||JPL02 Same as PPN ||<br />
|-<br />
|78 ||GPAN = GCO3+NO2N ||9e-29*exp(14000/T) ||JPL02 PPN ||<br />
|-<br />
|79 ||RCO3+NO = NO2+ETO2 ||6.70E-12 exp(340/T) ||IUPAC06 C2H5CO3+NO ||<br />
|-<br />
|80 ||GCO3+NO = NO2+HO2 +CH2O ||6.70E-12 exp(340/T) ||IUPAC06 C2H5CO3+NO ||<br />
|-<br />
|81 ||GLCO3+NO = NO2+HO2+CO ||6.70E-12 exp(340/T) ||IUPAC06 C2H5CO3+NO<br />
|-<br />
|82 ||RCHO+NO3 = HNO3 +RCO3 ||6.5E-15 ||IUPAC06 || use the one from NO3+C2H5CHO → HNO3 + C2H5CO<br />
|-<br />
|83 ||ACET+OH = ATO2 + H2O ||1.33E-13+ 3.82E-11 exp(-2000/T) ||JPL 06 ||JMAO:Implemented as 2 reactions <br />
|-<br />
|84 ||A3O2+MO2 = HO2 +0.75CH2O+0.75RCHO+0.25MOH + 0.25ROH ||5.92E-13 ||Tyndall RateMO2+MO2 Atkinson97RO2+RO2 ||K(RO2+MO2) = 2*sqrt(k(MO2+MO2)*k(RO2+RO2))<br />
|-<br />
|85 ||PO2+MO2 = HO2 + 0.5ALD2+1.25CH2O +0.16HAC + 0.09RCHO +0.25MOH + 0.25ROH ||5.92E-13 ||Tyndall RateMO2+MO2 Atkinson97RO2+RO2 ||<br />
|-<br />
|86 ||R4O2+HO2 = R4P ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|87 ||R4N1+HO2 = R4N2 ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|88 ||ATO2+HO2 = MCO3 + MO2 ||8.60E-13 exp(700/T) || ||<br />
|-<br />
|89 ||KO2+HO2 = MO2 + MGLY ||7.40E-13 exp(700/T) ||Tyndall ||Tyndall forms CH3C(O)CH2OOH ,this must then split and go to MCO3+MO2, the products in chem..dat ??<br />
|-<br />
|90 ||RIO2+HO2 = RIP ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|91 ||RIO1+HO2 = RIP ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|92 ||IAO2 + HO2 = IAP ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|93 ||ISN1+HO2 = ISNP ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|94 ||VRO2+HO2 = VRP ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|95 ||MRO2+HO2 = MRP ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|96 ||MVN2 + HO2 = ISNP ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|97 ||MAN2 + HO2 = ISNP ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|98 ||B3O2+HO2 = RB3P ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|99 ||INO2 + HO2 = INPN ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|100 ||PRN1 + HO2 = PRPN ||7.40E-13 exp(700/T) ||Tyndall ||<br />
|-<br />
|101 ||MEK+OH = KO2+H2O ||1.3 E-12exp(-25/T) ||IUPAC06 ||JMAO<br />
|-<br />
|102 ||MO2+ETO2 = 0.75CH2O+0.75ALD2+HO2+0.25MOH+0.25EOH ||3.00E-13 ||Horowitz 98, Atkinson 92& 94 ||<br />
|-<br />
|103 ||MEK+NO3 = HNO3+ KO2 ||8.00E-16 ||Lurmann et al. 1986 ||<br />
|-<br />
|104 ||R4O2+MO2 = 0.16ACET+0.10MEK+0.09MO2+0.14HO2+0.16ALD2 +0.07RCHO+0.03A3O2 +0.09B3O2+0.16ETO2+0.25MEK+0.75CH2O+0.25MOH+0.25ROH+0.50HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) ||<br />
|-<br />
|105 ||R4N1+MO2 = NO2+0.20CH2O+0.38ALD2 + 0.29RCHO+0.15R4O2+ 0.25RCHO+0.75CH2O+0.25MOH+0.25ROH+0.50HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) ||<br />
|-<br />
|106 ||ATO2+MO2 = 0.30HO2+0.30CH20+0.30MCO3+0.20HAC+0.20CH2O+0.50MGLY+0.50MOH ||7.5E-13 exp(500/T) ||Tyndall,2001 || ||<br />
|-<br />
|107 ||KO2+MO2 = 0.5ALD2 +0.50MCO3+0.25MEK+0.75CH2O+0.25MOH+0.25ROH+0.5HO2 ||8.37E-14 || || ||<br />
|-<br />
|108 ||RIO2+MO2 = 0.42HO2 +0.35CH2O+0.2MVK +0.14MACR + 0.07RIO1 +0.06IALD+0.25MEK+0.75CH2O+0.25MOH+0.25ROH + 0.5HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) ||HO2 term is 0.43 in input file, need to be changed back to 0.42(Palmer, JMAO)<br />
|-<br />
|109 ||RIO1+MO2 = 0.50IALD+0.50HO2+0.38CH2O+0.25MEK+0.75CH2O+0.25MOH+0.25ROH+ 0.5HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) || ||<br />
|-<br />
|110 ||IAO2+MO2 = 0.50HO2 + 0.33CO + 0.09H2 + 0.18HAC + 0.13GLYC + 0.29MGLY + 0.25MEK + 0.95CH2O + 0.25MOH + 0.25ROH + 0.5HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) || ||<br />
|-<br />
|111 ||ISN1+MO2 = NO2+0.50GLYC+0.50HAC+0.25RCHO+0.75CH2O+0.25MOH+ 0.25ROH+0.50HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below)|| || <br />
|-<br />
|112 ||VRO2+MO2 = 0.14HO2 + 0.14CH2O + 0.36MCO3 + 0.36GLYC + 0.14MGLY + 0.25MEK + 0.75CH2O + 0.25MOH + 0.25ROH + 0.50HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below)|| || <br />
|-<br />
|113 ||MRO2 + MO2 = HAC + 0.85CH2O + 1.15HO2 + 0.15CO ||8.37E-14 ||DBM(MCM 3.1) || ||<br />
|-<br />
|114 ||MVN2+MO2 = NO2+0.50CH2O+0.25MCO3 +0.25MGLY+0.25HO2+0.25RCHO+0.75CH2O+0.25MOH+0.25ROH+0.50HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) || ||<br />
|-<br />
|115 ||MAN2+MO2= NO2+0.50CH2O+0.50MGLY+0.25RCHO+0.75CH2O+0.25MOH+0.25ROH+0.50HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) || ||<br />
|-<br />
|116 ||B3O2+MO2 = 0.50HO2+0.50ACET+0.25ACET +0.75CH2O+0.25MOH+0.25ROH+0.50HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) || ||<br />
|-<br />
|117 ||INO2+MO2 = 0.55NO2 + 0.40HO2 + 0.425HNO3 + 0.025NO2 + 0.05MACR + 0.08CH2O + 0.03MVK + 0.25RCHO + 0.75CH2O + 0.25MOH + 0.25ROH + 0.05HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) ||NISOPO2(in MCM), HO2 term is 0.5 in the input file, need to be fixed. (Palmer, JMAO)<br />
|-<br />
|118 ||PRN1+MO2 = NO2+0.50CH2O+ 0.50ALD2+0.25RCHO+0.75CH2O+0.25MOH+0.25ROH+0.50HO2 ||8.37E-14 ||Tyndall MO2+MO2 Atkinson97 RO2+RO2 (See note 11 below) || ||<br />
|-<br />
|119 ||EOH+OH = HO2+ALD2 ||6.90E-12 exp(-230/T) ||JPL02 || ||<br />
|-<br />
|120 ||ROH+OH = HO2+RCHO ||4.6E-12 exp(70/T) ||IUPAC06 ||not in JPL06||<br />
|-<br />
|121 ||ETO2+ETO2 = 2ALD2 +2HO2 ||4.10E-14 ||JPL06 || ||<br />
|-<br />
|122 ||ETO2+ETO2 = EOH + ALD2 ||2.70E-14 ||JPL06 || ||<br />
|-<br />
|123 ||HO2+ETO2 = ETP ||7.40E-13 exp(700/T) ||Tyndall (see note 4) || ||<br />
|-<br />
|124 ||A3O2+HO2 = RA3P ||7.40E-13 exp(700/T) ||Tyndall || ||<br />
|-<br />
|125 ||PO2+HO2 = PP ||7.40E-13 exp(700/T) ||Tyndall || ||<br />
|-<br />
|126 ||MCO3 + HO2 = 0.15 ACTA + 0.15 O3 + 0.44 OH + 0.44 MO2 + 0.41 MAP ||5.2e-13exp(980/T) ||IUPAC(Feb2009) ||DBM<br />
|-<br />
|128 ||RCO3+HO2=0.3RCOOH+0.3O3+ 0.7RP ||4.30E-13 exp(1040/T) || || ||<br />
|-<br />
|129 ||GCO3 + HO2 = 0.71GP + 0.29O3 + 0.29CH2O ||4.30E-13 exp(1040/T) ||DBM(MCM 3.1) || || <br />
|- <br />
|130 ||MAO3+HO2=0.3RCOOH+0.3O3 + 0.7MAOP ||4.30E-13 exp(1040/T) || || ||<br />
|-<br />
|131 ||GLCO3+HO2=0.3RCOOH+0.3O3+0.7GLP ||4.30E-13 exp(1040/T) || || ||<br />
|-<br />
|132 ||PRPE+OH+M = PO2 ||LPL: 8.00E-27(300/T)^3.5;HPL:3.00E-11(300/T); Fc: 0.5 ||IUPAC06 ||JMAO<br />
|-<br />
|133 ||PRPE+O3 = 0.535CH2O+0.500ALD2+0.420CO+0.300HO2+0.135OH+0.065H2+0.305MO2 ||5.50E-15 exp(-1880/T) ||IUPAC06 ||JMAO<br />
|-<br />
|134 ||GLYX+OH = HO2+2CO ||1.1E-11 ||IUPAC06 ||Already updated<br />
|-<br />
|135 ||MGLY+OH = MCO3+CO ||1.50E-11 ||IUPAC06 ||JMAO<br />
|-<br />
|136 ||GLYX+NO3 = HNO3 + HO2+ 2CO ||K1=1.40E-12exp(-1860/T); K=K1*([O2]+3.5D18)/(2*[O2]+3.5D18); ||Atkinson92&94, (ALD2) ||<br />
|-<br />
|137 ||MGLY+NO3 = HNO3 + CO +MCO3 ||1.40E-12 exp(-1860/T) ||Atkinson92&94, (ALD2)/IUPAC06 ||<br />
|-<br />
|138 ||ISOP+OH = RIO2 ||2.70E-11 exp(390/T) ||IUPAC06 ||<br />
|-<br />
|139 ||MVK+OH = VRO2 ||2.6e-12exp(610/T) ||IUPAC06 ||JMAO<br />
|-<br />
|140 ||MACR + OH = 0.57MAO3 + 0.43MRO2 ||8.0E-12exp(380/T) ||IUPAC06 ||JMAO,DBM(MCM3.1)<br />
|-<br />
|141 ||HAC+OH = MGLY+HO2 ||3E-12 ||Atkinson 92,94/IUPAC06||<br />
|-<br />
|142 ||MCO3+A3O2 = MO2+RCHO+HO2 ||1.68E-12 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See Note 12 <br />
|-<br />
|143 ||MCO3+PO2 = MO2 +ALD2+CH2O+HO2 ||1.68E-12 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See Note 12 <br />
|-<br />
|144 ||MCO3+A3O2 = ACTA +RCHO ||1.87E-13 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See Note 12 <br />
|-<br />
|145 ||MCO3+PO2 = ACTA + 0.35RCHO+0.65HAC ||1.87E-13 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See Note 12 <br />
|-<br />
|146 ||ISOP+O3 = 0.387MACR + 0.159MVK + 0.100O3 + 0.270OH + 0.070PRPE + 0.900CH2O + 0.060HO2 + 0.150CO2 + 0.050CO ||1.05E-14 exp(-2000/T) ||Paulson &Seinfeld, 92 Aschmann &Atkinson, 94 ||<br />
|-<br />
|147 ||MVK+O3 = 0.82MGLY+ 0.80CH2O+0.20O2+0.05CO+0.06HO2+ 0.04ALD2 ||8.5 E-16exp(-1520/T) ||IUPAC06 ||0.20O2->0.20O3(Palmer, JMAO, according to Paulson & Seinfeld 92) Note 12 <br />
|-<br />
|148 ||MACR+O3 = 0.800MGLY +0.700CH2O+0.200O3+0.200CO+0.275HO2+0.215OH+0.160CO2 ||1.4 E-15exp(-2100/T) ||IUPAC06 ||JMAO<br />
|-<br />
|149 ||ISOP+NO3 = INO2 ||3.15E-12 exp(-450/T) ||IUPAC06 ||JMAO<br />
|-<br />
|150 ||MVK+NO3 = MVN2 ||REMOVED (<6E-16,IUPAC06) ||IUPAC06 ||JMAO<br />
|-<br />
|151 ||MACR+NO3 = MAN2 ||2.3E-15 ||IUPAC06 ||JMAO<br />
|-<br />
|152 ||MACR+NO3 = MAO3+HNO3 ||1.1E-15 ||IUPAC06 ||JMAO:IUPAC06 total rate is 3.4E-15, so use the ratio from Lurmann et al.,1986<br />
|-<br />
|153 ||RCO3+MO2 = CH2O+HO2+ETO2 ||1.68E-12 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See note 12|| <br />
|-<br />
|154 ||GCO3+MO2 = 2CH2O +2HO2 ||1.68E-12 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See note 12 <br />
|-<br />
|155 ||MAO3+MO2 = CH2O+HO2+CH2O+MCO3 ||1.68E-12 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See note 12 <br />
|-<br />
|156 ||GLCO3+MO2 = CH2O +2HO2+CO ||1.68E-12 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See note 12 <br />
|-<br />
|157 ||RCO3+MO2 = RCOOH +CH2O ||1.87E-13 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See note 12 <br />
|-<br />
|158 ||GCO3+MO2 = RCOOH + CH2O ||1.87E-13 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See note 12 <br />
|-<br />
|159 ||MAO3+MO2 = RCOOH + CH2O ||1.87E-13 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See note 12 <br />
|-<br />
|160 ||GLCO3+MO2 = RCOOH + CH2O ||1.87E-13 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See note 12 <br />
|-<br />
|161 ||INPN+OH = INO2 ||3.80E-12 exp(200/T) ||DeMore,reported in Horowitz as MP+OH ||<br />
|-<br />
|162 ||PRPN+OH = PRN1 ||3.80E-12 exp(200/T) ||JPL97,MP+OH ||<br />
|-<br />
|163 ||ETP+OH = 0.50OH+ 0.50ETO2+0.50ALD2 ||3.80E-12 exp(200/T) ||JPL97,MP+OH ||<br />
|-<br />
|164 ||RA3P+OH = 0.50OH + 0.50A3O2+0.50RCHO ||3.80E-12 exp(200/T) ||JPL97,MP+OH ||<br />
|-<br />
|165 ||RB3P + OH = 0.5OH + 0.5B3O2 + 0.5ACET ||3.80E-12 exp(200/T) ||JPL97,MP+OH;DBM,lumping from MCM3.1 ||<br />
|-<br />
|166 ||R4P+OH = 0.50OH+0.50R4O2 + 0.50RCHO ||3.80E-12 exp(200/T) ||JPL97,MP+OH ||<br />
|-<br />
|167 ||RP+OH = 0.50OH+0.50RCO3+0.50ALD2 ||3.80E-12 exp(200/T) ||JPL97,MP+OH ||<br />
|-<br />
|168 ||PP + OH = PO2 ||3.80E-12 exp(200/T) ||JPL97,MP+OH;DBM(MCM 3.1)<br />
|- <br />
|169 ||GP + OH = GCO3 ||3.80E-12 exp(200/T) ||DBM(MCM 3.1) ||<br />
|-<br />
|170 ||GLP+OH = 0.50OH+0.50GLCO3+0.50CO ||3.80E-12 exp(200/T) ||JPL97,MP+OH ||<br />
|-<br />
|171 ||RIP + OH = 0.509IALD + 0.509OH + 0.491RIO2 ||3.80E-12 exp(200/T) ||JPL97,MP+OH;DBM,lumping from MCM3.1 ||<br />
|-<br />
|172 ||IAP + OH = IAO2 ||3.80E-12 exp(200/T) ||JPL97,MP+OH; DBM (MCM3.1) ||<br />
|-<br />
|173 ||ISNP+OH = 0.50OH+0.50RCHO+0.50NO2+0.50ISN1 ||3.80E-12 exp(200/T) ||JPL97,MP+OH ||<br />
|-<br />
|174 ||VRP+OH = 0.50OH+0.50RCHO+0.50VRO2 ||3.80E-12 exp(200/T) ||JPL97,MP+OH ||<br />
|-<br />
|175 ||MRP + OH = MRO2 ||3.80E-12 exp(200/T) ||JPL97,MP+OH;DBM(MCM 3.1) ||<br />
|-<br />
|176 ||MAOP + OH = MAO3 ||3.80E-12 exp(200/T) ||JPL97,MP+OH;DBM(MCM 3.1) || <br />
|-<br />
|177 ||OH+MAP = 0.50OH+0.50CH2O + 0.50MCO3 ||3.80E-12 exp(200/T) ||JPL97,MP+OH ||<br />
|-<br />
|178 ||C2H6+NO3 = ETO2+HNO3 ||1.40E-18 ||Atkinson et al. 2004 (See note 13 below) ||<br />
|-<br />
|179 ||MNO3+OH =CH2O+NOMNO32 ||8.0E-13exp(-1000/T) ||JPL06 ||JMAO, The product is NO2 in the input file instead of NOMNO32.<br />
|-<br />
|180 ||IALD+OH = 0.44IAO2 +0.41MAO3+0.15HO2 ||3.70E-11 ||Paulson &Seinfeld, 92 ||<br />
|-<br />
|181 ||IALD+O3 = 0.60MGLY + 0.10OH + 0.12CH2O + 0.28GLYC + 0.30O3 + 0.40CO + 0.20H2 + 0.20HAC + 0.20HCOOH ||6.16E-15 exp(-1814/T) ||Paulson &Seinfeld, 92 ||MCO3+NO,MCO3,HO2,RCO3,GCO3,MAO3,GLCO3 rates are used for other radicals.<br />
|-<br />
|182 ||MCO3+MCO3 = 2MO2 ||2.50E-12 exp(500/T) ||Tyndall; See note 6. ||RCO3+HO2 same as MCO3+HO2, RCO3+NO same as MCO3+NO, RCO3+MCO3 same asMCO3+MCO3<br />
|-<br />
|183 ||MCO3+MO2 = CH2O+MO2+HO2 ||1.80E-12 exp(500/T) ||Tyndall ||<br />
|-<br />
|184 ||MCO3+MO2 = ACTA +CH2O ||2.00E-13 exp(500/T) ||Tyndall ||<br />
|-<br />
|185 ||R4O2+MCO3 = MO2 +0.32ACET + 0.19MEK + 0.18MO2 + 0.27HO2 + 0.32ALD2 + 0.13RCHO + 0.05A3O2 + 0.18B3O2 + 0.32ETO2 ||1.68E-12 exp(500/T) || ||T dep & B.R.Tyndall K298Villenave 98 See note 12 <br />
|-<br />
|186 ||ATO2+MCO3 = MO2 +0.8HO2+0.2CH2O+0.2MCO3+0.8MGLY ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|187 ||KO2+MCO3 = MO2 +ALD2+MCO3 ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|188 ||RIO2+MCO3 = MO2+0.864HO2+0.690CH2O +0.402MVK+0.288MACR+0.136RIO1+0.127IALD ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|189 ||RIO1+MCO3 = MO2 +IALD+HO2+0.75CH2O ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|190 ||IAO2+MCO3 = MO2 + HO2 + 0.65CO + 0.18H2 + 0.36HAC + 0.26GLYC + 0.58MGLY + 0.4CH2O ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|191 ||ISN1+MCO3 = MO2+NO2+GLYC+HAC ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|192 ||VRO2+MCO3 = MO2+0.28HO2+0.28CH2O+0.72MCO3+0.72GLYC+0.28MGLY ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|193 ||MRO2+MCO3 = MO2+HO2+0.17MGLY+0.83HAC+0.83CO+0.17CH2O ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|194 ||B3O2+MCO3 = MO2+HO2+ACET ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|195 ||R4N1+MCO3 = MO2+NO2+0.39CH2O+0.75ALD2+0.57RCHO+0.30R4O2 ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|196 ||MVN2+MCO3 = MO2 +NO2+CH2O+0.5MCO3+0.5MGLY+0.5HO2 ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|197 ||MAN2+MCO3 = MO2 +NO2+CH2O+MGLY ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|198 ||INO2+MCO3 = MO2 +0.10NO2 + 0.80HO2 +0.85HNO3 + 0.05NO2 +0.10MACR + 0.15CH2O +0.05MVK ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|199 ||PRN1+MCO3 = MO2 +NO2+CH2O+ALD2 ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|-<br />
|200 ||R4O2+MCO3 = MEK +ACTA ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|201 ||ATO2+MCO3 = MEK +ACTA ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|202 ||KO2+MCO3 = MEK + ACTA ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|203 ||RIO2+MCO3 = MEK +ACTA ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|204 ||RIO1+MCO3 = MEK +ACTA ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|205 ||IAO2+MCO3 = MEK+ ACTA ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|206 ||VRO2+MCO3 = MEK +ACTA ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|207 ||MRO2+MCO3 = MEK +ACTA ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|208 ||R4N1+MCO3 = RCHO +ACTA + NO2 ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|209 ||ISN1+MCO3 = RCHO +ACTA + NO2 ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|210 ||MVN2+MCO3 = RCHO +ACTA + NO2 ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|211 ||MAN2+MCO3 = RCHO +ACTA + NO2 ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|212 ||INO2+MCO3 = RCHO +ACTA + NO2 ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|213 ||PRN1 + MCO3 = RCHO +ACTA + NO2 ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|214 ||B3O2+MCO3 = ACET +ACTA ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|215 ||MCO3+ETO2 = MO2+ALD2+HO2 ||1.68E-12 exp(500/T) ||Ibid. ||<br />
|- <br />
|216 ||MCO3+ETO2 = ACTA +ALD2 ||1.87E-13 exp(500/T) ||Ibid. ||<br />
|- <br />
|217 ||RCO3+MCO3 = MO2 + ETO2 ||2.50E-12 exp(500/T) ||Tyndall,MCO3+MCO3 ||<br />
|- <br />
|218 ||GCO3+MCO3 = MO2 + HO2+ CH2O ||2.50E-12 exp(500/T) ||Tyndall,MCO3+MCO3 ||<br />
|- <br />
|219 ||MAO3+MCO3 = MO2 + CH2O + MCO3 ||2.50E-12 exp(500/T) ||Tyndall,MCO3+MCO3 || <br />
|- <br />
|220 ||GLCO3+MCO3 = MO2+ HO2+ CO ||2.50E-12 exp(500/T) ||Tyndall,MCO3+MCO3 ||<br />
|- <br />
|221 ||NO3+NO3 = 2NO2 + O2 ||8.50E-13 exp(-2450/T) ||JPL 06 ||<br />
|-<br />
|222 ||HO2 = 0.50H2O2 ||gamma=2E-1 ||Jacob, 2000 ||<br />
|- <br />
|223 ||NO2 = 0.50HNO3 +0.50HNO2 ||gamma=1E-4 ||Jacob, 2000 ||<br />
|- <br />
|224 ||NO3 = HNO3 ||gamma=1E-3 ||Jacob, 2000 ||<br />
|- <br />
|225 ||N2O5 = 2HNO3 ||gamma=fct(aerosol type, rh,temp) || Evans et al., 2005 ||<br />
|-<br />
|226 ||DMS+OH = SO2+MO2+CH2O ||1.1E-11exp(-240/T) ||JPL06 ||JMAO<br />
|-<br />
|227 ||DMS+OH+O2 = 0.75SO2+0.25MSA+MO2 ||K1=1.0E-39exp(5820/T); K2=5.0E-30exp(6280/T); K=K1*[O2]/(1.0+K2*[O2])||JPL06 ||MJE<br />
|-<br />
|228 ||DMS+NO3 = SO2+HNO3 +MO2+CH2O ||1.90E-13 exp(500/T) ||JPL2003 ||<br />
|-<br />
|229 ||SO2+OH+M = SO4+HO2 ||LPL: 3.30E-31(300/T)^4.3; HPL:1.60E-12; Fc: 0.6 ||JPL06 ||JMAO<br />
|-<br />
|230 ||MAO3 + NO=MCO3 + CH2O + NO2 ||6.7E-12exp(340/T) ||IUPAC2006 ||Palmer, May, JMAO:This reaction doesn't exist in the manual but is in the input The rate is from IUPAC2006 (or 2003), using the rate of CH3CH2C(O)O2+NO=C2H5C(O)O+NO2.<br />
|-<br />
|231 ||RIO1+NO = NO2 + IALD + HO2 + 0.75 CH2O ||K* (1-YN) where YN is returned from fyrno3.f; K=2.7E-12 exp(350/T) (Xcarbn=5.00E00) ||Atkinson 97 ||<br />
|-<br />
|232 ||RIO1+NO=HNO3 ||K* YN where YN is returned from fyrno3.f ;K=2.7E-12 exp(350/T) (Xcarbn=5.00E00) ||Atkinson 97 ||<br />
|-<br />
|233 ||PMN + OH = NO2 + 0.590HAC + 2.0HO2 + 2.230CH2O||3.20E-11 || ||<br />
|-<br />
|234 ||PMN + O3 = NO2 + 0.60CH2O + HO2||8.2E-18 || ||<br />
|-<br />
|235 ||GLYC+OH =0.8GCO3+0.4CO+0.2H2+0.2HO2 ||1.0E-11 || || <br />
|-<br />
|236 ||PRPE+NO3=PRN1 ||4.59E-13 exp(-1156/T) || || <br />
|}<br />
Note 10.RO2 primary+MO2: following madronich & calvert: K(RO2+MO2) = 2*sqrt(k(MO2+MO2)*k(RO2+RO2)).<br />
<br />
Note 11.RO2 secondary+MO2: same calculation as in note 10, but with the updated MO2+MO2 rate.<br />
<br />
Note 12:k 298 = 1e-11cm3 molec-1. Use T dep. From MCO3+MO2 according to Tyndall, and apply branching ratio from Tyndall. Keeping rate constant at 298K equal to 1E-11,means that A factor is 1.87E-12. Branching ratio from Tyndall sends 90% to the radical branch(A = 0.9*1.87E-12 = 1.68E-12), and 10% to molecular branch (A = 0.1* 1.87E-12 =1.87E-13).<br />
<br />
Note 13. Atkinson et al. (2004) gives k298 = <1x10^-17, which encompasses 1.4x10^-18.<br />
<br />
--[[User:Jmao|Jmao]] 21:52, 30 June 2011 (EDT)</div>
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